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16820 SMOKEY POINT BLVD_004207_2026
INSPECTION REPORT titN G 7'O Permit No.0 `12� Lot#: , "-L Q ~ Address: < Z Contractor: •-IP�F o 93, ,SO Owner: 1 I N O Date: APPROVAL ❑ PARTIAL APPROVAL ❑ VIOLATION ❑ CORRECTION REQUESTED ❑ Corrections listed below MUST BE MADE before work can be approved. ❑ Please contact inspector. ❑ Was not able to perform inspection. ❑ CALL 435-0674 FOR RE-INSPECTION -24 hour notice required. �1 I f I Inspector: Date l 'b TYP OF INSPECTION REQUESTED ❑ Under-floor ❑ Framing ❑ Gas Piping ❑ Footing ❑ Drywall, Nailing ❑ Consultation ❑ Foundation ❑ Shear Nailing ❑ Groundwork ❑ Mechanical ❑ Grid ❑ Struct. Slab ❑ Wood Stove ❑ Rough-in ❑ Final ❑ Masonry ❑ Drainage ❑ Insulation T ❑ Other: ��C�-Y INSPECTION REPORT N G To Permit No.:LV -�-/,Z`? Lot#: Address:f �� OZ Contractor: -3 93, Owner: `". 2ZL) V FII N G Date: ❑ APPROVAL ❑ PARTIAL APPROVAL ❑ VIOLATION CORRECTION REQUESTED ❑ Corrections listed below MUST BE MADE before work can be approved. ❑ Please contact inspector. ❑ Was not able to perform inspection. ❑ C L 43 -0674 FOR RE-INSPECTION -24 hour notice required. t P7 7 Inspector. ' Date: 12 97 TAPE OF INSPECTION REQUESTED ❑ Under-floor ❑ Framing ❑ Gas Piping ❑ Footing ❑ Drywall, Nailing ❑ Consultation ❑ Foundation ❑ Shear Nailing ❑ Groundwork ❑ Mechanical ❑ Grid >�Final truct. S{ab ❑ Wood Stove ❑ Rough-in ❑ Masonry ❑ Drainage O Insulation ❑ Other: 44 �" INSPECTION REPORT 4ti1N G rO Permit No. Lot #: Address: Ac g,90 Z Contractor: G,SO Owner: � IN Date: APPROVAL ❑ PARTIAL APPROVAL ❑ IOLATION ❑ CORRECTION REQUESTED ❑ Corrections listed below MUST BE MADE before work can be approved. ❑ Please contact inspector. ❑ Was not able to perform inspection. ❑ CALL 435-0674 FOR RE-INSPECTION - 24 hour notice required. Inspector: 41_4,�144LDate: TYPE OF INSPECTION REQUESTED ❑ Under-floor ❑ Framing ❑ Gas Piping ❑ Footing ❑ Drywall, Nailing ❑ Consultation ❑ Foundation ❑ Shear Nailing ❑ Groundwork Mechanical ❑ Grid ❑ Struct. Slab �Lj ood Stove ❑ Rough-in ❑ Final ❑ Masonry ❑ Drainage ❑ Insulation 0 Other: INSPECTION REPORT /(1) y1N G TO Permit No.: Lot#: veb Address: Z Contractor: `9 O Owner: I N G� Date: //- 13 —00 APPROVAL ❑ PARTIAL APPROVAL ❑ IOLATION ❑ CORRECTION REQUESTED ❑ Corrections listed below MUST BE MADE before work can be approved. ❑ Please contact inspector. ❑ Was not able to perform inspection. ❑ CALL 435-0674 FOR RE-INSPECTION - 24 hour atice required. )V 8 Inspector: INNDate: YPE OF INSPECTION REQUESTED ❑ Under-floor N ❑ Framing ❑ Gas Piping ElFooting Drywall, Nailing ❑ Consultation ❑ Foundation ❑ Shear Nailing ❑ Groundwork ❑ Mechanical ❑ Grid ❑ Struct. Slab ❑ Wood Stove ❑ Rough-in ❑ Final ❑ Masonry ❑ Drainage ❑ Insulation ❑ Other: INSPECTION REPORT l' k() 4y1N Gr0�p 0 Permit No.: Lot #: Q' Address: 1I`2?268w� Z Contractor: Owner: 407— SHIN G� Date: ,161—3/—0 i� ❑ APPROVAL RTIAL APPROVAL ElVIOLATION >u'CRRECTION REQUESTED ❑ Corrections listed below MUST BE MADE before work can be approved. ❑ Please contact inspector. ❑ Was not able to perform inspection. ❑ CALL 435-0674 FOR RE-INSPECTION - 24 hour notice required. - - _UC_ s i -- Inspector: Date: TYPE OF INSPECTION REQUESTED ❑ Under-floor ��Framing ❑ Gas Piping ❑ Footing ❑ Drywall, Nailing ❑ Consultation ❑ Foundation ❑ Shear Nailing ❑ Groundwork ❑ Mechanical ❑ Grid ❑ Struct. Slab ❑ Wood Stove ❑ Rough-in ❑ Final ❑ Masonry ❑ Drainage insulation ❑ Other: INSPECTION REPORT C-tjN ! Permit No.: '� Lot#:Address:Contractor: � 0,OHO Owner: I N Date: 9—2 PPROVAL ❑ PARTIAL APPROVAL ❑ VIOLATION ❑ CORRECTION REQUESTED ❑ Corrections listed below MUST BE MADE before work can be approved. ❑ Please contact inspector. ❑ Was not able to perform inspection. ❑ CALL 435-0674 FOR RE-INSPECTION -24 hour n T required. I r C��k"?�//)I Inspector: Date: 6/0 TYPE OF INSPECTION REQUESTED ❑ Under-floor ❑ Framing ❑ Gas Piping ❑ Footing Drywall, Nailing ❑ Consultation ❑ Foundation Z) Shear Nailing ❑ Groundwork ❑ Mechanical ❑ Grid ❑ Struct. Slab ❑ Wood Stove ❑ Rough-in ❑ Final ❑ Masonry Drainage ❑ Insulation ❑ Other: � 1 -� INSPECTION REPORT ¢y1N GTO Permit No. — eX 7Lot #: ��- Address: 109c;�C ^�©ram VQ Z Contractor: !P�v 93, �O Owner:fy� �I N O Date: ❑ APPROVAL PARTIAL APPROVAL ❑ VIOLATION ❑ CORRECTION REQUESTED ❑ Corrections listed below MUST BE MADE before work can be approved. ❑ Please contact inspector. ❑ Was not able to perform inspection. ❑ CALL 435-0674 FOR RE-INSPECTION -24 hour notice required. x?/ o 6A/J cc_ par Inspector: Date: / Od PE OF INSPECTION REQUESTED ❑ Under-floor ❑ Framing ❑ Gas Piping ❑ Footing ❑ Drywall, Nailing ❑ Consultation ❑ Foundation ❑ Shear Nailing ❑ Groundwork ❑ Mechanical ❑ Grid ❑ Struct. Slab ❑ Wood Stove ❑ Rough-in ❑ Final ❑ Masonry ❑ Drainage �<Insulation 0 Other: C I T Y QF A RL I hiCTC" CONE;TRUCT I ON F:)1ERM I T d F:,E RM I T V40- 00-4a,07 Owner: NORTHWEST VETERENARY CLINIC 16820 SMOKET POINT BL.VD ARLINGTON 9a Value of Work: $105,6 0.010 TEM 31,60 629 4571 Describe Work: TENNANT IMPROVEMENT Proposed Use: VETENATR CL.I.N1O Legal Description. .lob Address: 1E,820 ShOKET POINT DLVD Contractor' s Name Type Address License# BERG CONSTRUCTION GEC! 4209 126T4., ST KL�NBEC*140!J TOTALS Fee Per-Iri•t I:-ee 021.75 Haan Fee �654. 14 C� / State fee $4.50 SIGNATURE; ' TOTAL FEE. _ ,. .... . .. . $1,690.S9 I !-HEREBY CERI 1 Y T!Att T i HAVE REAL AND EXAMIi ED 'T #IS APPL ICATION AND PAYMENTS......... . . .. ... .. $664. 14 KNOW THE SAME TO RE T,RUE AND C OR— RECT ALL PROVISIONS OF LAWS AND TOTAL DUE....... ........ .. 11,026.25 ORDINANC�:S GOVERNING THIS TYPE OF WORK WILL BE COMPLIED WITH WHETHER RECEIPT # SPECIFIE !EREil I O-5' BUILDI. I L Li DD (,gs1 - 1 0 0 0 c j � wJ «� �/A :� NORTHWEST VETERINARY CLINIC June 24 , 2000 City of Arlington 238 N Olympic Ave Arlington, Wa 98223 To whom it may concern: Shaun McGarry is hereby authorized as our agent to act on our behalf in matters concerning permit applications, plan submission, building design, and other matters dealing with our current construction project at Smokey Point Plaza, 16820 Smokey Point Blvd, Arlington, Wa. �incer y, Daniel Haskins, DVM Vice President Northwest Veterinary Clinic of Stanwood 8500 Cedarhome Drive • Stanwood WA 98292 134 West Avenue • Arlington WA 98223 360-629-4571 360-435-3011 t M: :., i; �' - I I i i 1 ., � � -. '' . � - March 1, 2001 Greg Holt 657 W Field Rd Camano Island, WA 98292 Dear Mr. Holt, I just wanted to thank you for your cooperation in sending the necessary certifications to close the file. I apologize for any inconvenience this has caused you. Sincerely, Barbara Noble Building Inspector �� \ 1 f� 02/28/2001 13:01 3603876822 EZ PLUMBING INC PAGE 01 I ENDORSED AS PROVIDED BY LAW AS MEDICAL GAS PIPING INSTALLER ENDORSEMENT# EXP. DATE M001 HOLT*GM022RS 08/02/2001 EFFECTIVE DATE 12/28/1998 HOLT, GREGORY M 657 W FIELD RD CAMANO ISLAND W �� 292 5igttuturn �"' Issued by DEPA Tm C1F ABUR FIND 1NDUSTICES t i M V AU =-L '2t ttt_L ' 1 I 02/28/2001 13: 01 3603876822 EZ PLUMBING INC PAGE 02 o > PH j Q Gre M. Holt Q n � O 0-4 tp tA rri tY `� F M �, 1 r • • r* ELt� "W7 C3l \ Ate ; 4m+ m j tv01 r d O O 03. -atLq rr � y O � x r a - - n]o - moo' � I do• r•� 141 '`"' r.,r r� CAS � s� I MM Wo ^. �. ? , r., 6- sue _ I I 02/26/2001 21: 22 3603876822 EZ PLUMBING INC PAGE 01 E.Z. PLUMBING, INC. 657 W. FIELD ROAD GREG HOL7 387-6941 CAMANO ISLAND,WA 98292 4&*%7v— s'441-01 K)dle fey o arm as- r.► �,o 4�fs 7:txr q&roIo..r, /c)U, Ve reOr'M;c GQ - 3/L7 Aa"a A r y s'7?o r -2) 141 , .=2-Aee./040 , o*4r.C4eo-V C,Wot" e 96kl .2e4s -t5` A s; 3) oea Ldd R1v&)Aca 4) en000a o77-o/ joz-i�e 4t oodcCp, ?) --r c.,)yslrom dloo.acc�^o ,-6 „j'au!ce cg�a,S, va7*7-zJ*lP70A�s aecArw 44kr q7'.�,~07OV1,9 ',o re. ,J"L//"e /1+fr olorreGl'e . I ■ ■■ h ■■■ ■ ■51• ■ 5• • 7K JW I _ Y � I� bit ■ * art .R ■ r�� d •. L■ �� Fes■ y J. 16V 7' ��"•V ■ �. -■ 0 :- `-1� YS Qom■ _ •1 5. � ?� A = 61HGMAN usoRATORIES, Inc. P.O. DOX 159 SARAHVVILLE.OHIO 43779 Shell ' MATERIAL SAFETY DATA SHFET MSDS NUMBER / 5.592-8 PAGE 1 17367 44•651 24 HOUR :EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE SHELL: 713-473-9461 CHEMTREC: 800-424-9300 SHELL: 713-241-4819 BE SAFE READ OUR PRODUCT ACUTE HEALTH FIRE REACIWI7Y S,AFETVINFORMATION (EAST • 0 SLIGHT • I MODERATE • 3 ...AND 2 3 0 HAZARD RATING ' PASS R ON NION 7 EXTREME A ►�OhK..va�m uM *For acute and chronic health effects refer to the discussion In Section III SECTION J :NAME PRODUCT ISOPROPYL ALCOHOL, 70'6 REENTERED FEBRUARY 1994 C NAME ' IPA. ISOPROPANOL. 2-PROPANDL A LC O H O L 7 0 ---• WAB 20025 CHEMICAL ' ALCOHOL WAB 20030 FAMILY SHELL CODE 31122 WAB 20032 -------------------------------------------------------------------------------R.►BaM-----..------ SECTION II-A PRODUCT/INGREDIENT -------------------------------------------------- COMPOSITION CAS NUMBER PERCENT ------------------------------ --------------------------- - ---- -------- P ISOPROPYL ALCOHOL. 70% MIXTURE 100 1 ISOPROPYL ALCOHOL 67-63-0 70 2 WATER 7732-18-5 30 ---------------------------------------------------------------------------------------------------- SECTION II-B ACUTE TOXICITY DATA ------------------------------------------------------------------------------------------------- NO. ACUTE ORAL LOBO ACUTE DERMAL LOBO ACUTE INHALATION LC50 ------------------------------------------------------------------------------------------•--------- 1 5840 MG/KG (RAT) 13000 MG/KG (RABBIT) ..12000 PPM (RAT) B HRS --------------------------------------------- - SECTION III HEALTH INFORMATION THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REOUIREMENTS UNDER THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). RECEIVED EYE CONTACT MODERATELY IRRITATING TO THE EYES. �.7 JAN 4 2001 SKIN CONTACT MILDLY IRRITATING TO THE SKIN. CITY OF ARLINGTON INHALATION MAY CAUSE MILD IRRITATION TO THE NOSE. THROAT AND RESPIRATORY TRACT AND MAY RESULT IN CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. INGESTION IRRITATING TO THE GASTROINTESTINAL TRACT. CAUSING ABDOMINAL PAIN AND VOMITING. SOMETIMES BLOODY. INGESTION MAY CAUSE CNS DEPRESSION. LOW BLOOD PRESSURE. RAPID HEART BEAT AND LIVER DAMAGE. SIGNS AND SYMPTOMS , IRRITATION AS NOTED ABOVE. ELRLY TD MODERATE CNS (CENTRAL NERVOUS SYSTEM) DEPRESSION MAY BE EVIDENCED BY GIDDINESS. HEADACHE. DIZZINESS AND NAUSEA; IN EXTREME CASES, UNCONCIOUSNESS. RESPIRATORY DEPRESSION AND DEATH MAY OCCUR. LIVER DAMAGE MAY BE EVIDENCED BY LOSS OF APPETITE, 9�11111I Provided as a "Value Added Service" THE BUTLER COMPANY jJ,.. by The Butler Company 5000 BRADENTON AVE DUBLIN, OH 43017 PRODUCT NAME: ISOPROPYL ALCOHOL, 70% MSOS 5.592-8 PAGE 3 JAUNDICE (YELLOWISH SKIN COLOR) AND SOMETIMES PAIN IN THE UPPER ABDOMEN ON THE RIGHT SIDE. AVATED MEDICAL CONDITIONS 1',..cXISTING EYE. SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. IMPAIRED LIVER FUNCTION FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. SEE SECTION V1 FOR ADDITIONAL HEALTH INFORMATION. SECTION IV OCCUPATIONAL EXPOSURE LIMITS -------------------------•--------•-------.••--•---•-----------•-----------------------------------. OSHA ACGIH OTHER 40. PEL/TWA PEL/CEILING TLV/TWA TLV/STEL 1 400 PPM 400 PPM 500 PPM $DO PPM• CDR COMPONENT 1. 50% ODOR RECOGNITION THRESHOLD IS 7.5 PPM. ODSHA PEL/STEL. ----------------------------------------------------------------------------•.....------............ SECTION V EMERGENCY AND FIRST AID PROCEDURES ---------------------------------------------------------------------------------------............. !YE CONTACT IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE HOLDING EYELIDS OPEN. 3ET MEDICAL ATTENTION. SKIN CONTACT FLUSH SKIN WITH WATER. IF IRRITATION OCCURS. GET MEDICAL ATTENTION. INHALATION REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GET MEDICAL ATTENTION. INGESTION DO NOT GIVE LIQUIDS 1F VICTIM IS UNCONSCIOUS OR VERY DROWSY. OTHERWISE. GIVE NO MORE THAN 2 •• ?' ASSES OF WATER AND INDUCE VOMITING BY GIVING 3OCC (2 TABLESPOONS) SYRUP OF IPECAC.- IF IPECAC IS �. AILABLE. GIVE 2 GLASSES OF WATER AND INDUCE VOMITING BY TOUCHING FINGER TO BACK OF VICTIM'S .: ,AT. KEEP VICTIMS HEAD BELOW HIPS WHILE VOMITING. GET MEDICAL ATTENTION. VOTE TO PHYSICIAN •IF VICTIM 15 A CHILD. GIVE NO MORE THAN 1 GLASS OF WATER AND 15CC (1 TABLESPOON) SYRUP OF IPECAC. IF SYMPTOMS SUCH AS LOSS OF GAG REFLEX. CONVULSIONS OR UNCONSCIOUSNESS OCCUR BEFORE EMESIS. GASTRIC :AVAGE SHOULD BE CONSIDERED FOLLOWING INTUBATION WITH A CUFFED ENDOTRACHEAL TUBE. ---------------------------•-••------------•--•------------------------------r------------•--------- SECTION VI SUPPLEMENTAL HEALTH INFORMATION ----------------------------•----------------------------------------------------------------------- IPA: IN RESPONSE TO A TSCA TEST RULE, SEVERAL STUDIES OF IPA HAVE NOW BEEN COMPLETED. THE STUDIES AND THEIR RESULTS ARE AS FOLLOWS 1) BOTH MUTAGENICITY STUDIES. THE MOUSE MICRONUCLEUS AND CHO ASSAYS, WERE NEGATIVE. 2) RAT AND RABBIT ORAL TERATOGENICITY AND DEVELOPMENTAL TOXICOLOGY: A) THERE WAS NO EVIDENCE THAT IPA CAUSED TERATOGENICITY IN RATS OR RABBITS. B) DEVELOPMENTAL TOXICITY WAS SEEN IN RATS AT 1200 MG/KG (EVIDENCED.BY DECREASED BODY WEIGHT•*) WHILE NO DEVELOPMENTAL TOXICITY WAS SEEN IN THE RABBIT STUDY. FOR RATS, THE NOAEL WAS 400 MG/KG; FOR RABBITS, 480 MG/KG. THIS WORK ALSO IDENTIFIED PREGNANT RABBITS TO BE APPROXIMATELY EIGHT TIMES MORE SENSITIVE TO IPA'S LETHAL EFFECTS THAN NON-PREGNANT RABBITS•. OTHER TEST RULE RELATED STUDIES: 3) RAT ORAL REPRODUCTIVE TOXICITY: IN THE RAT REPRODUCTIVE TOXICITY STUDY. THE NOAEL FOR REPRODUCTION INDICES WAS 10DO MG / KG, HOWEVER, THERE WAS A MARKED INCREASE IN POST - WEANING PUP MORTALITY AT THIS LEVEL••; THE NOAEL FOR THIS EFFECT WAS 500 MG / KG. ALSO, THE NOAEL FOR PARENTAL FEMALE BODY WEIGHT DECREASE WAS 100 MG / KG. 4) IN RAT INHALATION NEUROTOXICITY AND ORAL DEVELOPMENTAL NEURDTOXICITY STUDIES, THERE WAS NO EVIDENCE THAT IPA CAUSED NEUROTOXICITY IN ADULTS (MAX DOSE 5000 PPM) OR OFFSPRING (MAX DOSE 1200 MG / KG). 5) SUBCHRONIC RAT AND MOUSE INHALATION TOXICITY: THE SUBCHRONIC NDAEL WAS 500 PPM BASED ON CLINICAL SIGNS OF CNS DEPRESSION (BOTH SPECIES) AND INCREASED BODY WEIGHT AND BLOOD EFFECTS ( RAT ONLY ) SEEN AT 1500 PPM. (NOTE: THE INFORMATION TAGGED BY ABOVE WERE SUBMITTED TO EPA UNDER THE REQUIREMENTS OF TSCA 8(E).) r' •�• v PRODUCT NAME: ISOPROPYL ALCC 70% MSDS 5,502-8 PAGE 3 -------------------------------------------------------•-------------------------------•--------•--- SECTION VII PHYSICAL DATA ...........----------------------------------------------------------------------------------------- SOILING POINT: 190• SPECIFIC GRAVITY: 0.85 VAPOR PRESSURE: 250068 DEG F (DEG F) (H20.1) (MM HG) MELTING POINT: NOT AVAILABLE SOLUBILITY: COMPLETE VAPOR DENSITY: 1.6• (DEG F) (IN WATER) (AIR■1) EVAPORATION RATE (N-BUTYL ACETATE ■ 1): 0.7 •ESTIMATED APPEARANCE AND ODOR: COLORLESS, MOBILE LIQUID. MILD ODOR. •--•-----------•---------------------------------------------------------•---------------------- -- SECTION VIII FIRE AND EXPLOSION HAZARDS FLASH POINT AND METHOD: FLAMMABLE LIMITS A VOLUME IN AIR APX. 77 DEG F -TCC LOWER: 2 UPPER: 12 EXTINGUISHING MEDIA USE WATER FOG, "ALCOHOL" FOAM, DRY CHEMICAL OR CO2, SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS WARNING. FLAMMABLE. CLEAR FIRE AREA OF UNPROTECTED PERSONNEL. DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD. BUNKER COATS, GLOVES AND RUBBER BOOTS), INCLUDING A POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. UNUSUAL FIRE AND EXPLOSION HAZARDS CONTAINERS EXPOSED TO INTENSE HEAT FROM FIRES SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILDUP WHICH COULD RESULT IN CONTAINER RUPTURE. CONTAINER AREAS EXPOSED TO DIRECT FLAME CONTACT SHOULD BE COOLED WITH LARGE QUANTITIES OF WATER AS NEEDED TO PREVENT WEAKENING OF CONTAINER STRUCTURE. SECTION IX REACTIVITY ---------------------------------------------w.------------w---------------------------------------- STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS AND MATERIALS TO AVOID: AVOID HEAT. SPARKS, FLAME AND CONTACT WITH STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS CARBON MONOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION. -------------------------------------------------------------------------------------- SECTION X EMPLOYEE PROTECTION -------- ------------------------------------------•--•----•---------------------------------------- RESPIRATORY PROTECTION IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SEC, IV) USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR 0 ANIC VAPORS. T[. OSHA HAS ESTABLISHED TRANSITIONAL OCCUPATIONAL EXPOSURE LIMITS FOR THIS PRODUCT AND/OR COMPONENTS OF THIS PRODUCT. REFER TO 29 CFR 1910.1000 FOR THESE TRANSITIONAL LIMITS AND REQUIREMENTS FOR MEETING THESE LIMITS. �a 1 I 2RDDUCT NAME: ISOPRDPYL ALCOHOL, 70%' ` MSDS 5,592-3 1 PAGE 4 DROTECTIVE CLOTHING AVOID CONTACT WITH EYES. WEkR CHEMICAL GOGGLES IF THERE IS LIKELIHOOD OF CONTACT WITH EYES. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. WEAR CHEMICAL-RESISTANT GLOVES AND OTHER CLOTHING AS 'IRED TO MINIMIZE CONTACT. TEST DATA FROM PUBLISHED LITERATURE AND/OR GLOVE AND CLOTHING FACTURERS INDICATE THE BEST PROTECTION IS PROVIDED BY NITRILE, NEOPRENE AND NATURAL RUBBER ADDITIONAL PROTECTIVE MEASURES JSE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS. EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE FOR EMERGENCY USE. SECTION XI ENVIRONMENTAL PROTECTION SPILL OR LEAK.PROCEDURES 4ARNING. FLAMMABLE. ELIMINATE ALL IGNITION SOURCES. HAN6L"11140 EQUIPMENT MUST BE GROUNDED TO 3REVENT SPARKING. --- LARGE SPILLS --- EVACUATE THE HAZARD AREA OF UNPROTECTED PERSONNEL. WEAR APPROPRIATE RESPIRATOR AND PROTECTIVE CLOTHING. SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO DO SO. )IKE AND CONTAIN. IF VAPOR CLOUD FORMS, WATER FOG MAY BE USED TO SUPPRESS: CONTAIN RUN-OFF. IEMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY, SAND OR OTHER SUITABLE MATERIAL; PLACE IN NON-LEAKING CONTAINERS FOR PROPER DISPOSAL. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE; DISPOSE OF FLUSH SOLUTIONS AS ABOVE. -+- SMALL SPILLS --- TAKE UP WITH AN ABSORBENT MATERIAL AND PLACE IN NON-LEAKING CONTAINERS; SEAL TIGHTLY FOR GROPER DISPOSAL. ---------------------------------------------------------------------------------------------------- SECTION XII SPECIAL PRECAUTIONS ---------------------------------------------------------------------------------------------------- KEEP LIQUID AND VAPOR AWAY FROM HEAT, SPARKS AND FLAME. SURFACES THAT ARE SUFFICIENTLY HOT MAY IGNITE EVEN LIQUID PRODUCT IN THE ABSENCE OF SPARKS OR FLAME. EXTINGUISH PILOT LIGHTS. CIGARETTES AND TURN OFF OTHER SOURCES OF IGNITION PRIOR TO USE AND UNTIL ALL VAPORS ARE GONE. VAPORS MAY ACCUMULATE AND TRAVEL TO IGNITION SOURCES DISTANT FROM THE HANDLING SITE; FLASH-FIRE CAN RESULT. KEEP CONTAINERS CLOSED WHEN NOT IN USE. USE WITH ADEQUATE VENTILATION. CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, CAN CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, DRILL. GRIND, WELD OR p'4FORM SIMILAR OPERATIONS ON OR NEAR CONTAINERS. DO NOT PRESSURIZE DRUM CONTAINERS TO EMPTY THEM. TIC ELECTRICITY MAY ACCUMULATE AND CREATE A FIRE HAZARD. GROUND FIXED EQUIPMENT. BOND AND JND TRANSFER CONTAINERS AND EQUIPMENT. WASH WITH SOAP AND WATER BEFORE EATING, DRINKING. SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. AIR-DRY CONTAMINATED CLOTHING IN A WELL VENTILATED AREA BEFORE LAUNDERING. 30 NOT STORE OR HANDLE IN ALUMINUM EQUIPMENT AT TEMPERATURES ABOVE 120 DEG. F. ------------.----------------------------------------------------------------------------ft---------- SECTION XIII TRANSPORTATION REQUIREMENTS ---------------------------------------------------------------------------------------------------- 3EPARTMENT OF TRANSPORTATION CLASSIFICATION: °LAMMABLE LIQUID J.O.T. PROPER SHIPPING NAME: ISOPROPANOL OTHER REQUIREMENTS: DOT 1D NUMBER - UN 1219 - GUIDE SHEET 26 ...--------------------------------•------------------------------------------ ---------------------- SECTION XIV OTHER REGULATORY CONTROLS -------------------------------------------------- ------------------------------------------------- THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. IN ACCORDANCE WITH SARA TITLE III, SECTION 313. THE ENVIRONMENTAL DATA SHEETP,(EDS) SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS. I PRODUCT NAME: ISOPROPYL ALCOK 170% MSDS 5,682-8 PAGE 6 ---------------------------------------------------------------------------------------------------- SECTION XV STATF REGULATORY INFORMATION ---------------------------------------------------------------------------------------------------- THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES; OTHER PRODUCT SPECIFIC HEALTH AND SAFETY DATA IN OTHER SECTIONS OF THE MSDS MAY ALSO BE APPLICABLE FOR STATE REOUIREMENTS. FOR DETAILS ON YOUR REGULATORY REOUIREMENTS YOU' SHOULD CONTACT THE APPROPRIATE AGENCY IN YOUR STATE. STATE LISTED COMPONENT PERCENT STATE CODE ---------------------------------------------------------------------------------------------------- ISOPROPYL ALCOHOL CA. FL, MA. ME. MN. NJ. PA. RI (CAS NO: 67-63-0 ) 70 CA - CALIFORNIA HAZ. SUBST. LIST: CASS - CALIFORNIA SAFE DRINKING WATER AND TOXICS ENFORCEMENT ACT LIST; FL - FLORIDA SUBST. LIST: IL - ILLINOIS TOX. SUBST. LIST; MA - MASSACHUSETTS SUBST, LIST; ME - MAINE HAZ SUBST. LIST; MN.- MINNESOTA HAZ. SUBST. LIST; NJ ■ NEW JERSEY HAZ. SUBST. LIST; PA • PENNSYLVANIA HAZ. SUBST. LIST; RI - RHODE ISLAND HAZ. SUBST. LIST. ---------------------------------------------------------------------------------------------------- SECTION XVI SPECIAL NOTES ---------------------------------------------------------------------------------------------------- SEE ENVIRONMENTAL DATA SHEET FOR WASTE DISPOSAL AND OTHER ENVIRONMENTAL INFORMATION. THIS MSDS REVISION HAS CHANGES IN SECTIONS VI. IX. XII, AND XV. ---------------------------------------------------------------------------------------------------- THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF, SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. ---------------------------------------------------------------------------------------------------- J. C. WILLETT --------------------------------------- BE SAFE READ OUR PRODUCT SHELL OIL COMPANY SAFETY INFORMATION . ..AND PASS IT ON PRODUCT SAFETY AND COMPLIANCE (PRODUCT LIABILITY LAW P. 0. SOX 4320 REQUIRES IT) HOUSTON. TX 77310 a 28 I � Crystal Violet (Gram's Stain Solution # 1) Dip Quick Stain Solution# 1 (Fixative) orgensen Laboratories, Inc. Continued MSDS No: MS8221.SGM October 1991 MSDS No: MS8220.SGM October 1991 CHEMICAL PRODUCT IDENTIFICATION Identification CHEMICAL PRODUCT IDENTIFICATION ,,;ohol:.Acetone Qecolorizer. Gram's Identification ( Product Name:Crystal Violet(Grain's Stain Solution N I) tain `;4lutlon# 3)Continued COMPOSITION/INFORMATION ON INGREDIENTS Product Norris: Dip Quick Stain Solution a I(Fixative) Ingredients:Crystal Violet,Ammonium Oxalate,Reagent Alcohol COMPOSITION/INFORMATION ON INGREDIENTS RE FIGHTING MEASURES HAZARD IDENTIFICATION Ingredients:Methyl Alcohol(Methanol) re and Explosion Date Health Hazard Data tsh Point: Isopropyl Alcohol: 53'F(Tag closed cup method);Ace- Exposure/Health Effects: HAZARD IDENTIFICATION e, -4 F Inhalation:No special precautions required. Health Hazard Data Ingestion:Harmful if swallowed. May cause irritation of the mouth, sure/Health Effects: e and Explosion: Flammable liquid.Vapors are heavier than air and esophagus and stomach. ,el along the ground to an ignition source and flash back to vapor Inhalation:Inhalation of vapors can cause drowsiness,headaches,res- arce. Skin Contact: No adverse effects expected.Will slain skin and clothing. piratory irritation,fatigue,nausea,possible unconsciousness,and even Eye Contact:Can cause irritation,redness,tearing and blurred vision. asphyxiation. s Extinguishing Media: Use dry chemical or carbon dioxide for small Precautions Measures: HARMFUL IF SWALLOWED. MAY :s Use alcohol type foam for large fires. Precautionary Ingestion: Ingestion may result in vomiting,nausea,inebriation,blind- CAUSE IRRITATION.Do not get in eyes,on skin,or clothing(will ness or central nervous system damage. rectal Flits Fighting Information: Do nor use ordinary foam. Appli- slain skin and clothing). Wash thoroughly after handling. ion of water fog/spray will aid in keeping fire-exposed materials cool. Skin l:Short-term,non-repeated contact may pose moderate FIRST AID MEASURES irritation on and dryness. First Aid Procedures Eye Contact:Can cause irritation,redness,tearing and blurred vision. 'CIDENTAL RELEASE MEASURES Inhalation: Remove to fresh air if effects occur. Precautionary Measures: HARMFUL IF SWALLOWED OR IN- aWSplll Disposal Information: Eliminate all ignition sources(heal, Ingestion: If swallowed,if conscious,give large amounts of water and HALED MAY CAUSE IRRITATION Do not get in eyes,on skin, me including pilot lights,and sparks). Flush with large quantities of induce vomiting.Never give anything by mouth to an unconscious person or clothing.Avoid breathing vapor.Use with adequate ventilation. ter or absorb with an appropriate absorbent.Small quantities may be Get medical attention. F"ed of in the sewer. Skin Exposure: In case of cuntact,wash with mild soap and water.Get FIRST AID MEASURES medical advice if irritation develops. First Aid Procedures Eye Exposure: Wash eyes with plenty of water for at least 15 minutes Inhalation: Remove to fresh air if effects occur ANDLING AND STORAGE If irritation develops,get medical attention. Ingestion: Induce vomiting and gel medical attention immediately. ecautions for Safe Handling and Use FIRE FIGHTING MEASURES Skin Exposure: In case of contact,wash with mild soap and water Get indling and Storage: Keep in a tightly closed container,stored in a Fire and Explosion Data medical advice if irritation develops. il,dr),ventilated area away from sources of ignition and flame Flash Point: No information found. Eye Exposure:Wash eyes with plenty of water for at least 15 minutes. Fire and Explosion:Alcohol content is 10%or less. If irritation develops,get medical astenUon. (POSURE CONTROLS/PERSONAL Fire Extinguishing Media: Use dry chemical,carbon dioxide or alcohol aOTECTION foam FIRE FIGHTING MEASURES Special Information: No information found. Fire and Explosion Data :cupational Control Measures -borne Exposure Urrt No information found. ACCIDENTAL RELEASE MEASURES Flesh Point:52'F(Tag closed cup method). 'latlon:General room ventilation is usually adequate. Look/Spill Disposal Information:Small quantities may be disposed of Fire and Explosion:Flammable liquid.Vapors are heavier than air and in the sewer. large quantities should be disposed of according to local travel along the ground to an ignition source and flash back to vapor m Protection: Wear resistant gloves. requirements for non-hazardous material. source. e Protection: Use chemical safety goggles. Fire Extinguishing Media:Use dry chemical or carbon dioxide for small HANDLING AND STORAGE fires. Use alcohol type foam for large fires. Precautions for Safe Handling and Use Special Information:Do not use ordinary foam. Application of wa- 1YSICAL AND CHEMICAL PROPERTIES Handling and Storage: Keep in a tightly closed container,slorcd in a ter/fog spray will aid in keeping fire-exposed materials cool. iysieal Data cool,dry,ventilated area. Pearanee: Clear liquid. EXPOSURE CONTROLS/PERSONAL ACCIDENTAL RELEASE MEASURES lot:Characteristic, PROTECTION Leak/Spill Disposal Information:Eliminate all ignition sources(heal, lubllity In Water:Complete. Occupational Control Measures flame including pilot lights,and sparks). Flush with large quantities of water absorb with an appropriate absorbent.Small quantities may be ISOPROPYL ALCOHOL ACETONE Airborne Exposure Limits: No information found. Ventilation:General room ventilation is usually adequate. disposeedd of in the sewer. iline Point 82.5'C 56'C Skin Protection: Wear resistant gloves. rtung Point -88.5-C •139'F HANDLING AND STORAGE Eye Protection: Use chemical safety goggles. :cnic Grartq 0-79 0.79 Precautions for Safe Handling and Use por Densiq(air=l) 21 136 PHYSICAL AND CHEMICAL PROPERTIES Handling and Storage: Keep in a tightly closed container,stored in a pax Pressure(mm Hg) 33 Ca,68'F 226 Physical Data cool,dry,ventilated area away from sources of ignition and flame. aporation Rate(butyl 1.4 60 Appearance: Dark blue/purple liquid. tale=l) Odor:Alcoholic.IWater: EXPOSURE CONTROLS/PERSONAL Solubility n Water: Appreciable. PROTECTION cam Volatile by Volume(%.) IW% 1IX0% Bolling Point: No information found. Melting Point: No information found. Occupational Control Measures Specific Gravity:No information found. Airborne Exposure Umlla:No information found. rABILITY AND REACTIVITY Vapor Density(Air=1): No information found. Ventilation:General room ventilation is usually adequate. lactivlty Data Vapor Pressure(mm Hg): No information found. Skin Protection: Wear resistant gloves. loll": Stable under ordinary conditions of use and storage. Evaporation Rate(Butyl Acetate=1): No information found. Eye Protection: Use chemical safety goggles. zardous Decompositlon: Incomplete combustion may produce car. Percent Volatile by Volume(%):No information found. o dioxide and/or carbon monoxide STABILITY AND REACTIVITY PHYSICAL AND CHEMICAL PROPERTIES zardous Polymerization: Will not occur. Physical Data Reactivity Data : mpatlbllltles:Avoid contact with oxidizers. Avoid sources of ign- Stability:Stable under ordinary conditions of use and storage. Appearance:Clear liquid. n,such as heal,sparks and flames. Hazardous Decomposition:No information found. Odor:Characteristic. Hazardous Polymerization: Will not occur. Solubility In Water:Complete. SPOSAL CONSIDERATIONS Incompatibilities:No incompatibility data found. Bolling Point:64.5'C Melting Point:-144'F rate Disposal: Ensure compliance with local,state and federal regu• DISPOSAL CONSIDERATIONS Speclflc Gravity:0,79 'n' Waste Disposal: Ensure compliance with local,state and federal regu• Vapor Density(Air=1): 1.1 lations. Vapor Pressure(min Hg):96.0 1ANSPORT INFORMATION TRANSPORT INFORMATION Evaporation Rate(Butyl Acetate=l):5.91 )T Heard Cis": Flammable Liquid. DOT Hazard Class:Not Regulated. Percent Volatile by Volume(%): 100% i i i 1 i 1 �- � i i `1 I i I I A-54 7grican Veterinary Distributors Association SECTION III-PHYSICAL DATA Do,J-C1DE L.A.` AVDA MSDS No.:MS 18 Allergroom Shampoo Bolling Paint(°F): GT 2121 Allerderm,Inc.,P.O. Drawer 277i Hurst,TX 76053.Emer- Continued ^"' Specific Gravity(Hr0-1):Q 25°C: 1.04 gency Telephone: (617)589.1700. Vapor Pressure(mm Hg.): WA SECTION I-PRODUCT IDENTIFICATION Evaporation Ratev WA Parcent,Volatile by Volume(%)Water: 56 Trade Names/Synonyms: Duo-Clde LA. Solubility In Water: Miscible Vapor Density(Air-1): N/A Chemical Name end Synonyms:Residual Insecticidal Flea Appearance and Odor: Clear yellow liquid Evaporation Rate: N/A 8 SECTION IV-FIRE AND EXPLOSION HAZARD DATA Solubility In Water: Miscible Tick Spray for Dogs with rollsPyret rin end Pennelhrin Special Fire Fighting Procedures: Use conventional fire Appearance and Odor: Blue clear/hazy liquid with Chemical Family: Productlds extinguisher. characteristic menthol odor. Formula: Finished Product SECTION V-HEALTH HAZARD DATA SECTION IV-FIRE AND EXPLOSION HAZARD DATA SECTION II-HAZARDOUS INGREDIENTS Effects of Ovorexpoauro: Discontinue use or wear rubber Special,Fire Fighting Procedures: Use conventlal fire Nothing listed In this section gloves if Irritation develops. extinguisher. SECTION ill-PHYSICAL DATA Emergency and First Aid Procedures: Contact physician. SECTION V-HEALTH HAZARD DATA Specific Gravity(Hr0-1):1.2 SECTION VI-REACTIVITY DATA Effects of Overexposure: Discontinue use it irritation SECTION IV-FIRE AND EXPLOSION HAZARD DATA Nothing noted in this section. develops. Nothing noted In this section SECTION VII-SPILL OR LEAK PROTECTION SECTION VI-REACTIVITY DATA SECTION V-HEALTH HAZARD DATA Steps to be taken In case material Is released or spilled: Nothing listed In this section. Effects of Overexposure: Skin Irritation study Contain all spills. Spilled material Is slippery. SECTION VII-SPILL OR LEAK PROTECTION (rabbits): not a primary irritant;Eye Irritation study SECTION Vlll-SPECIAL PROTECTION INFORMATION Steps to be taken In case material is released or (rabbits): minimal transient toxicity;Acute oral Nothing noted In this section, spilled: Contain all spills. toxicity(rats):LD.>5g/Kg. SECTION IX-SPECIAL PRECAUTIONS SECTION Vlll-SPECIAL PROTECTION INFORMATION SECTION VI-REACTIVITY DATA Nothing noted in this section. Nothing noted In this section Nothing noted In this section SECTION IX-SPECIAL PRECAUTIONS SECTION Vll-SPILL OR LEAK PROTECTION Nothing noted In this section. Nothing noted in this section ALLERSEB-T.SHAMPOO,. SECTION Vlll-SPECIAL PROTECTION INFORMATION Nothing noted In this section AVDA MSDS No.:MS15 DUO-CIDE FLEA& TICK COLLAR SECTION IX-SPECIAL PRECAUTIONS Allerderm,Inc., P.O. Drawer 277, Hurst,TX 76053. Emer- Nothing noted in this section gency Telephone: (817)589.1700. FOR DOGS SECTION I-PRODUCT IDENTIFICATION Trade Name/Synonyms: Allerseb-T Shampoo DUO-CIDE SAFETY-STRETCH COLLAR Formula: Salicylic Acid.Sulfur&Coal Tar FOR CATS DUO-C1DE SHAMPOO,; ` SECTION 11.HAZARDOUS INGREDIENTS AVDA MSDS No.:MS17 ' AVDA MSDS No.:MS 20 None listed Allerderm,Inc., P.O. Drawer 277, Hurst,TX 76053.Emer- Allerderm,Inc.,P.O.Drawer277,Hurst,TX 76053.Emergency SECTION Ill-PHYSICAL DATA gency Telephone: (817)589.1700. Telephone:(817)589-1700. Boiling Point(°F): approx 212° SECTION I.PRODUCT IDENTIFICATION SECTION I-PRODUCT IDENTIFICATION Specific Gravity(H20-1): Trade Names/Synonyms: Duo-Clde Flea&Tick Collar for Trade Names and Synonyms: Duo-Clde Shampoo Vapor Pressure(mm Hg.) N/A Dogs,Duo-Cide Safely-Stretch Collar for Cats Chemical Name and Synonyms: D•Trens Allelhrin 8 Percent,Volatile by Volume(%):Water/Ethanol 80 Chemical Family:Chlorpyrifos Sumithrin SECTION it-HAZARDOUS INGREDIENTS Chemical Family: Pyethroids ChlorpyVapor Density(Air-1): N/A , Formula: Finished Product Evaporation Rate: N/A SECTION /it 89e;PHYTLVSICAL (Units)-0.2 mg/m Solubility In Water: Partially Soluble SECTION 111-PHYSICAL DATA SECTION Il-HAZARDOUS INGREDIENTS Bolling Point(°F): WA Nothing noted In this section Appearance and Odor: Viscous opaque tan liquid with coal s SECTION 111-PHYSICAL DATA tar odor. Vapor Pressure(mm Hg.):1.87x10 SECTION IV-FIRE AND EXPLOSION HAZARD DATA Specific Gravity(H°0-1):N/A Specific Gravity(H.0-1): 1.2 Percent,Volatile by Volume(%):N/A SECTION IV-FIRE AND EXPLOSION HAZARD DATA Special Fire Fighting Procedures: Use conventional fire Nothing noted In this section extinguisher. Vapor Density(Air-1): WA Solubility In Water: N/A SECTION V-HEALTH HAZARD DATA SECTION V-HEALTH HAZARD DATA Evaporation Rate: NIA Effects of Overexposure: Skin irritation Study(rabbits): Effects of Overexposure: Discontinue use or wear rubber Note primary irritant;Eye Irritation Study rabblls gloves ft irritation develops. Appearance end Odor: White crystalline solid. Very faint P ry Y y(rabbits): Emergency and First Aid Procedures: Contact physician. mercaptan odor, mildly Irritating;Acute oral fox.5.15 gm/Kg slightly SECTION VI-REACTIVITY DATA SECTION IV-FIRE AND EXPLOSION HAZARD DATA toxic. Flash Point: No fire or explosion hazard SECTION VI-REACTIVITY DATA Nothing noted In this section.SECTION Vll-SPILL OR LEAK PROTECTION Extinguishing Media: Use standard fire fighting Nothing 9 noted in This section procedures depending on source of surrounding fire. SECTION Vll-SPILL OR LEAK PROTECTION Steps to be taken In case material Is released or spilled, Nothing noted In this section Contain all spills and leaks to prevent discharge Into Contain runoff. SECTION V-HEALTH HAZARD DATA SECTION Vlll-SPECIAL PROTECTION INFORMATION environment. Spilled material is slippery. Nothing noted In this section Waste Disposal Method: Recover material,or d,sposo In Emergency andFlrelAldProcedured:Wash with soap and B accordance with all applicable loderal,stale and iocai raglula- water after handling. Atropine is antidote. SECTION IX-SPECIAL PRECAUTIONS lions. SECTION VI-REACTIVITY DATA Nothing noted in this section SECTION Vill-SPECIAL PROTECTION INFORMATION Incompatibility: Strong oxidizers Nothing noted in this section. Hazardous Decomposition Products: Product Is stable. SECTION/X-SPECIAL PRECAUTIONS Poisonous gas is produced In lire. EFA-Z PLUS AVDA MSDS No.:MS21 Nothing noted in this section. SECTION VII-SPILL OR LEAK PROTECTION Allerderm,Inc.,P.O. Drawer 277,Hurst,TX 76053.Emer- Waste Disposal Method:Avoid contamination with water gency Telephone: (617)589-1700. supplies. Place material in sealed containers and SECTION I-PRODUCT IDENTIFICATION dispose of In accordance with applicable federal,slate Trade Name and Synonyms: EFA-Z.PLUS DERMACOOL' - AVDA MSDS No.:MS16 and local regulations. Formula: Vegetable Oil wNltemins R zinc sulfate SECTION Vlll-SPECIAL PROTECTION INFORMATION SECTION 11-HAZARDOUS INGREDIENTS Allerderm,Inc.,P.O. Drawer 277,Hurst,TX 76053. Emer- WA gency Telephone: (817)589.1700. Nothing noted In this section SECTION!-PRODUCT IDENTIFICATION SECTION IX-SPECIAL PRECAUTIONS SECTION It/ PHYSICAL DATA Trade NemelSynonyms: DermsCool WA Specific Gravity(H.0-1):@ 25°C: 0.92 Formula: Water-based astringent - — - Solubility In Water: Mostly insoluble SECTION II-HAZARDOUS INGREDIENTS Appearance and Odor: Yellow olly liquid with suspended None listed. powders and characteristic odor. iI c it i is I t MATE"'1 1- SAFETY DATA SHEET 010.6029 SECTION I 1=Acrtrasra �... .�...... w. .:.. ..... ... : c.Hcu�.ww�>~ „rtY►a, �:::. M....w<: ..w.. �,� .,. :�.. .w�:.,.<.. ::K., ianofi Animal Health, Inc. �+ Atropine Sulfate Injection .Ew .,J..• .ut�.a. ��ra�`s�z :3.::�'»` :'`�`�v.''�ewia3il�Oes:::i»w. ..�,. .,.. !116 8th Avenue South,Fort Dodge,IA 50501 Atropine Sulfate Injection, 15 mg/ml MERC/ENCY P1iONE e` FQR1d(1LA .2 vh Thc••.,j:..:•: J�- Ki. � `a:°�a\\:;. ... ... ....�.., ... ... ... ,..,. ....,v... 515)576-4225 C17H23NO3 ,�r1:PREP�►RF:D;.f :>: :Kr :-J QQ.,�+��p��� 1-18-91 SECTION II - MATERIAL IDENTIFICATION AND INFORMATION COMPONENTS—Chemical Name&Common Names OSHA ACGIH OTHER LIMITS (Hazardous Components 1%or groalor:Carcinogens 0.1%or greater) % PEL TLV RECOMMENDED ,lropine Sulfate 1.5 Unknown Unknown LDLo:lntraduodenal—rat 350 mg/kg L050:Intravenous—mug 58 mg/kg I.050:Subcutaneous—mug 723 mg/kg ert Ingredients and other Active Ingredients at levels<1%(0.1%for carcinogens)and/or rtermined to be Non—Hazardous as defined by 29 CFR Part 1910,July 1980 'OTAL100 MONSOON SECTION III - PHYSICAL DATA )ILING POINT(f) Unknown SPECIFIC GRAVITY(H20-1) Unknown 1POR PRESSURE(mm Hg) Unknown PERCENT VOLATILE BY VOLUME(%) Unknown uPOR DENSITY(AIR-1) Unknown EVAPORATION RATE Unknown )LUBIUTY IN WATER Complete (Butyl Acetate-1) 'PEARANCE AND ODOR Gear,odorless solution SECTION IV— FIRE AND EXPLOSION HAZARD DATA IISEi ..:..... .:.,�:.. :.. .. POIh!'1''- �;. i.`�C}•s .:.. .:.:,::�::;,..:�:: ':...,. .... -.;-.. :.,..���?;::. ?�«�;�:v:,.. :. <I�?; ' "':::klc: �> s-, ....•:...:.....,..,�;a.,.t.,..;.wc.-.ar�r:.w�... .,,:,wc..�:.. ... .c,:aca..i;ry✓.ws.;,wHv'3ot�: f1XIi�.U1BL�t.19�A1TS �:. .. :• ' :,.,,._Ln�wk ,.,; ' it iknown Unknown Unknown Unknown TINQWSIiINQIKE tAi .i96AQ�� <v • x. ryS :,.,,...,:..w.•.w,:c. ...,;j3. .,:,.Yx:.}c ...... ::.n......� '•''+ •''' s}.�w :Y., .- ater spray,carbon dioxide,dry chemical powder,alcohol or polymer foam F.�I�t..�tc..M.T!as!7ii� .�flvv(��t�,tty}" �,t-.-:. li.�-.:•e)r K` ,•>\ ,;• Yk,'. F:. y'2:ro ':i:i''� � - t 'y:. :i J•if .. ., :Yi . '��• ••t::� JR`z $:?;.; ........... �r"�i'as>:,,,x�•:,.'•''"�a}''t"�''''3at:'v:,� itrwtiG'i•Sa��S�`lwr'"'''�oa .. ........,,..vY.w.,wr.,:.:a.a•..�....:..::..:..:..........,.-::.,tto},•::+d.}::.W}S�,.i'ao:� .a�a#.,V�..<.b'}:..waY�u•:.. r.::•Si':f.';,w?'.•...:..w- vacs ,,. refighter should use sell contained breathing apparatus and turn out gear. .k• f-i'%'J'.:"•.:v.: ::}•O.}:"wrii•:Y riN n': ','.[„K ♦ {'Y;'4'�. 'O +'T'.M rY. w3vAC Piflt At�2.Exptoll :. .: ' .• b:f. .. <i, >: ::: » t' :, `?::. ii t� :. �.� 'fF'tt: „ t: ti.. K. ..::..::.:;...:.:w.:,•.,,:wzw...vw.www. H�gt•. .,•'��6: wa�iv?f`'".... '.>���c`'' �%". -' .:::.ww:•?'.'�•'aa.ua»iia%.ci:;:.•�rSawa�a�15fa4wG(irk`wfSw�.,S}�:c.:.::-.v�x;w ._ t'�+ t'• imwi:v.,vw.x•nwn N» rvW'.;':4itr' v.J.:: .....,. .. 14 �Wn A2 �'� �I 1 ,, i i i 1 I f i i SECTION V—HEALTH HAZARD DATA THRE.41iO1Dt.Ad ..:... ....«..o.:w>.aww.w;oi::<.•,..:e.,,+�,+c�ArF�o�x�. i�_ ...: ...... ... .......... .:.. -.i.�' yAW, .J.rX :< .•2>.'�<::.`�,.K i�\'a,:'.>Y�.' _ 8 QF �...:,..'x.vc,,- ..;w,.ww.S n+.+Rc.7' ` K- --'� Z"'� v......,..::. .o-:.. ....:,w:..<x o .'»iK.21i� ay..aCaU'v`.iecaiA•-�i.�>,>'\.. ,4"`' oifa - -.w<st'hrC• :.<.....>,,.:,• �` ?€ •�. r�.aY.,;io,,,., sfo,<�.,a.,<•:;t.�c,��`, ,, .� `�u.\.2So ' ram:' f � f��F `3�tb:�.,�,: vas•�;,��.v; 2 axa Maybe fatal Whaled,swallowed or absorbed through skin. Obtain medical assistance at once. May cause irritation. Highly toxic. .,.......,+..arc..:.w<woa.a,Wuco.....n.u.w.:.w .:..ws:• v.Y'.��'Z Q,i ,..., R`�"` .. \C6���Wa2iJt3c''�.�»#>`. .,'�' ..w: If Ingested,wash out mouth with water. Call a physician. In case of skin contact,flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. If Inhaled,remove to fresh air. If not breathing give artificial respiration. If breathing is difficult,give oxygen. In case of eye contact,flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating eyelids with fingers. Wash contaminated clothing before reuse. SECTION VI — REACTIVITY DATA STABILITY UNSTABLE CONDITIONS TO AVOID STABLE X .zsr',.� .,w...,.....•,.,,,.�c�siai,,.,,.w.-..,�„'... �� '' :.'.; :, �.:._>ib:'. �..l'`.u,:ic.. > 2 .. ...:.,>.,........a•.,'x<, we...:...�, ..,,.....,.>f' ... w..,,•,•,,,::::.: ``S..tr-'on,�g�oxkllzing agents. Sensitive to Ilght. .JS/�J1/WV� � '( _ _-.. _.>- Sor•R�>; v'1:::;;..!f: :; •t:.,:.C;.p�F::.. ,ray::;:,:•.an'i::::;:aC•.:,, �:4�. e .. ..:w:!,:wo ;.:o:,•S .P ."3. ,n>, ,t: K :i3Aq�. ,'j• a:<.at.".2 \3i.i�>' '"a. C ., u�4iJkZEG�a'.: 'S :: Ff,qO%-.w.J4C90VM,14YF:b.A .. i//\..H�xi'c.0v;o,,,,;,< -:.:K<�a rw:.�»,:ci2'•''':.r�`--TfxG�at�'4' .^.x�"` `�`'�% dct5"rc"r.Y`4�' �i. a Thermal decomposition may produce carbon monoxide,carbon dioxide.nitrogen oxides and sulfur oxides. MAY OCCUR CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION WILL NOT OCCUR X SECTION VII —SPILL OR LEAK PROCEDURES - :. :.. -Y.v,:S:i' ::i:� �� ♦ h Y>:v:Y:•'f,-:<{r�:J:j-r.'S.+:.<j-\<:::is:.v./v.y:;`.!:^r::>r/.::i('.;Y.v+. STEPS TC7 t3TNCHf M CASi;InTE FtIAI fS REt I:J�S7 QNt e� _ \ ...:.: ..... ............ ...x:..: .. :: , :._...:... ..-.. ......-.., t ;E'rM :>`r:.:.... ,....:?.. ,w.::k:..:....:.r-rr•:1...• ;2.Y..,..\,a..v..:a>n.J f,�wf>zaif+'.',:...o.Y.ra.:..r„sf.A.�.:S:aSa2..,.5„•::sx;.,...,,•.....:L Evacuate area. Wear NIOSH approved self-contained breathing apparatus,chemical resistant gloves,safety goggles,other protective clothing. {QAbsorb onn sand or vermiculite and place 1n closed container for disposal. Wash spill site after material pick-up is complete. RA�VIHrV\7IM.iKT►iTN Y\ �'L C.Y',4 K - R - - - .:;aa:-.,..a,�aa,aao:o»uc•�.a..i`,:;•.✓�,o..aarw ''' �s�rai,+"Xh�x'w�E'�.'>�' '* R�.'&°,�Sc¢•dw�".�avo. >.t A - 3.. : ... .. .: -;.@ .�+ti`, .. Incineration or chemical waste landfill in accordance with local,state,or Federal regulations. SECTION VIII —SPECIAL PROTECTION INFORMATION t�SYQa i:�1. �'L �,.a�..;.J�'.''.XC �. ;':9;.!,i».r :.;t' ,w.:�� Yo�Cu•:S£? �:,iY:�i t ,� :.:�.>,,.>:,::C.. ;i:'f:..::.b7l?:t>;fNYt;>Y.•. `,. :..,,,.....,v..............w.,,:.,...:.��.�Y+�uEua'�`�xstat>.aa6F cco:;,riwK-s� �:�iu \'' Y 'i�'�d�:'>"�`a1Q�lib3.�•ik'bb7.iuiC+L`i� .' ...�?.rfE�>� .. �:'3°• '��bC'a.'�Y:wc`�'`� A:• NIOSH/MSHA Approved respirator VENTILATION EOCXL,I�7Q'IAtlb"E' ..::..;" �' `�S`,••,.ov-�.`..° `• ;'.•� `";°��� � �\�;d .,K. �.. �� r ....:. , -..,.,::...dtt�.a'' ''4:a:::f:,A.w::.,;ae6r::`.N:2•.;..�QX2aY:6ohir�.it"»�».. !.�'c�'.�osa,'.'o�:'�oLa:�ro��aiC�Vu�"A'�w:aiKrlw>+>^,..'`JR'o'.`Y.'a, .,o.�,.:•�`. ..V�S'�����Sa: Should be provided IEC _,.......t t'tA ?7F^�o>. •2pe�`:iu:CYa.'4:2°.',>?'iwv,':, ;:fi::>,.>:::�ru�-c':rti ti :c�.Yc.,..xv:.,..:.�. : £. :thi44Tw` T' `kyy::C?c;\::.J:C'3'f.;e ;4, %>'l.>�;"•p•C\°+. ..>:< v.:. :., -. N�iAt..aa�:G9kw�'i.�;>:iwwNc.�.:Scoc`�.�;:FG:t�tq'+dRS�;k�.`C 'a�Y. -�'.`}o"`�.�.�� ;:r:::::„tCo'c �. •.S;�h.*.-�\.,.,.8'-:'0' •>..�'> '•�" Yes Use with adequate ventillation PF1071�.7TYE f3i.0YEH ak`�i .' «°Z>` >. � > °>.,`•. 'w �Z: �cwr ({ s}� `t� 3` 'sC, :aM x, S•. Q.+:+kt'au�kta+cis:Ne>'.:N::viyd:L'vYsI.SX•kwnatei:F5koeacweUL.LS.i. Wva+ehn>fd•,vi?�• `.'+'•••+>' Chemical -resistant gloves Goggles -..,>..:,er•,. ::a:.::.;Y,,.;,:... 3;C;,.),..:.:..tea:.c: :.o..:... .:..... YPa...-..->.::>x•:'�:.,.:,a,.+.v:?V:F..::.:fiY:3•n:,�::>•"?isjt:}u:>;iix�;i::::.rJ:;+'v.::..:.c::tt:'%`Y:'�cv'L.,.. O7litc�i�PO��V!~Z�Vtt�l�'`.<.\n::� N. ,,, „:. .: >..�...>•,.' ..:; �� <..:;::,.;....,.��.. .y.:. .,:<.:.,,.:::.: ...,..x, � � > -.:.....::...,.•.,.,.,..: K.........:.........:.:.:.....:...cxh,,,o;%c�,. ,a�a�us:�c,,, ,oauw,.,6Rao.�,:>t�s: .a:»::::..,.<•>..' ' £:s,-'-+csc::�..✓„��v..,.,ucFsasD�£',..,,,,w.osr�tc�w.,.,,.,.,��.:z.,x:c>,.�.�;��..s�s .:3A.,t��<f:Y::v:�> Safety shower and eye bath �Y SECTION IX—SPECIAL PRECAUTIONS .......::::.....FY..:,!.... 4.............. 'xr: •,UC><�n.:i::nY.....y.�•f M. •: E%h n:. ...,��}\-:v'v:F.�' S b. PR£r. 70BET1�KQi IN HANDLtttG A... ..:...:.. :..,..,..: ,.:�:..•:: .::..-:... .Y....: .......:... ........ ......,5.'.:KS:/4X<.:Kox;,oa�x`f,C�,w<a:.i��.•:.>:a>•:t',3,-�»'�c'-�/..-:Yw�'a�'` ����4•>xr�::x�fKtixK�`��cw�o"'�•'f�>voS�O� � Do not get in eyes,on skin,on clothing. Avoid prolonged or repeated exposure. Wash thoroughly after handling. Highly toxic. Keep tightly closed. Light-sensitive. Store In a cool,dry place. OTH1R PRIi3CAtJTiONS ?s ::' Yl., .....:...:.\ v�.g Yo.`'n'\a�`ri:$::,7>tiv iiaicv�i,:;'"Fs ;,L'<'..'•,fi4v r�<,•'^F .vs ,�D"h f. ia:•'t:'� .'Ft4 j". o s `•a�: Highly toxic. May be fatal if Inhaled,swallowed or absorbed through skin. Judgements as to the suitability of information herein for purchaser's purposes are necessarily purchaser's responsibility. Therefore, although reasonable care has been taken in the preparation of such information,Sanofl Animal Health,Inc.extends no warranties, makes no representations and assumes no responsibility as to accuracy or suitability of such Information for application to purchaser's Intended purposes or for consequences of its use. Page 2 of 2 a ` t �.� _. .I a. I American Veterinary Distributors Associatit A-59 Overoxposurs Effects: May cause reversible suppression ATROPINE SULFATE 1%OPHTHALMIC incineration: Yes Dispersal to water: No of the Hypothalamic-PoultaryAdrenal Axis, Cushing's Syn. Ocean dumping: No Lagooning: No drome.hyperglycemia and glycosuria. OINTMENT U.S.P. AVDA MSDS No.:MS537 Sanitary Landfill: No Chemical Landfill: Yes Chronic EHebts:May cause allergic reactions In susceptible Aliens, Inc., BYK Pharmaceutical Group. 60 Baylis Road, Deep Wall ed Dispose No Open Disposal: No individuals. Melville.NY 11747.Emsrgency Telephones:Business Hours: Undetermined Disposal:N/A Priority Pollutant: No 4 Neutralization: No Inhalation: Not likely due to the physical stale of the product. (518) 54.7677;Other Hours:(516)454.7692;TELEX 144662. SECTIONIX-PERSONAL PROTECTION&HYGIENE INFOR- Eyes: May cause Irritation Date of MSDS:August 3,1988 MATION Ingestion: May cause hyperglycemia and I cosuria. SECTION I-PRODUCT IDENTIFICATION Personal hygiene practices must Include:Wasq thoroughly B Yg Y Yg Skin: May cause irritation, Common Name:Atropine Sulfate 1%Ophthalmic Ointment after handling. U.S.P. Protect our eyes with: Normal hygiene Medical Conditions Potentially Aggravated by: Hy Y Y Yg pothalmic-Pitwtary-Adrenal dysfunction,skin irritation and al- CAS Number: N/A Protect your hands by: Normal hygiene lergies in susceptible individuals. Synonyms: N/A Protect your skin by using: Normal hygiene SECTION Vlll-SPECIAL PRECAUTIONS AND SPILULEAK Formula: Alropme Sulfate 1%, Lanalin(Anhydrous)WNlo protect your breathing by using: Adequate ventilation PROCEDURES Polrolaturnk,Mineral Oil.Purified bvah,r,Chlorubulanol Precautions to be Taken In Handling/Storage; Keep con- Chemical Family; Pharmaceutical Ophthalmic Ointment SECTION X-CONTAINERS AND LABELING lainers closed when not in use. Do not handle or store near SECTION 11-SAFETY AND HAZARD RATINGS (a)Storage and Containers: heal,Name or oxidizers. Health(Acute-Chronic):2-2 Special Precautions:Keep at controlled room temperature. Hygienic Practices: Wash thoroughly.her handling.Use : Recommended Containers: As supplied(not sold in bulk Flammability:normal hygiene to protect hands,eyes and skin. Use general lY 0 quantity). ventilation to protect your lungs_ Do not wear contaminated Environment(Air-Water-Soil):0-2.1 Protect the container by: Avoiding physical damage,heal clothing until thoroughly laundered. Reactivity: 0 and freezing. When Material to Released or Spilled: Assure slippery Protective Equipment: Not applicable under normal condi- Container should be handled In an area with: Adequate conditions are nullified.Add sand or dirt.Scoop up and remove. tions of use. ventilation. Dispose in accordance with Federal,state and local regula- SECTION 111-FIRST AID The Empty Container Is: Not reusable. lions. Waste Disposal Methods:Assure conformity with applicable If First Aid Is Required: (b)Precautionary Label disposal regulations.Dispose of absorbed material at approved Eye:Flush with plenty of water for at least 15 minutes.Call Precautionary Label:Federal law prohibits dispensing with- incineration or chemical landfill waste disposal site. a physician. out prescription. Keep tightly closed. SECTION IX-SPECIAL PROTECTION INFORMATION Skin:Flush with plenty of water. Warning Placard: Keep out of reach of children. Respiratory Protection: General ventilation. Ingestion:Delay absorption uy gi.mo activated charcoal, IMO Hazard Clas":WA UN/WA M:WA Skin Protection: Normal hygiene. then remove by gastric Iavaqu Call a physician. Hazard Classification: N/A Eye Protection: Normal hygiene. SECTION IV-HAZARDOUS INGREDIENTS DOT Name: N/A Other Protective Clothing or Equipment: As needed to Hazardous Materials: Atropine Sulfate Shipping Instructions:Keep away from oxidizers,strong prevent repeated/prolonged contact. CAS Number: 55.48-1 acids,alkalies,and sources of strong heat. SECTION X-CONTAINERS AND LABELING Percent: 1 SECTION XI-ENVIRONMENTAL RISKS Special Precautions: Keep container closed. Store away TWA(mg/m3): N/A Aquatic Toxicity: Nil Rom oxidizers and sources of heal and flame. STEL(mg/m3):WA Biodegradability: WI Recommended Container: As supplied(not sold in bulk Carcinogenicity: IARC: N/A;NTP:N/A; Other: N/A Partition Coefficient: WI quantity) SECTION V-FIRE AND EXPLOSION HAZARDS SECTION XII-REGULATOR YREFERENCES Protect the Container by:Avoiding physical damage and heal Extinguishing Agents Recommended: Foam,Dry Chemi- Refer to the following references: Container should be Handled In an Area with: Cool,dry cal,Carbon Dioxide. OSHA Regulations: II respirator used 29 CFR 1910 134 conditions. Flash Point(Closed Cup): DOT Regulation.: WA The Empty Container Is: Not reusable. Fahrenheit:WI Celsius: Nil EPA Regulations: N/A Precautionary Label: For veterinary use only. Federal law Flammability Limits In Air(Percent by Volume): Other: FDA:21 CFR 330.5; NDC 0168.0065-3 prohibits dispensing without prescription. To be used in dogs Lower: N/IUpper: Nil SECTION XIII-PHYSICAL DATA and cats only. Not for use in animals raised for food. Aulolgnitlon will occur at: Nil Odor: Odorless Appearance: Ointment Warning Plaqord: Keep out of the reach of children. Special Firefighting Procedures: Wear self-contained Color: Pale Yellow Molecular Weight: N/A IMO Hazard Clas": Not applicable. UN/NAN:Not appli• breathing apparatus. cable. Unusual Fire&Explosion Hazards:May emit toxic fumes. pH:N/A Hazard Classification: Not applicable. Decomposition Products: Carbon monoxide,carbon diox- Specific Gravity et 20°C:>1.0 DOT Name: Not applicable. Ide,oxides of sulphur. Refractive Index 20°C: Nil Shipping Instructions: Keep away from oxidizers and Avoid the Following: Strong oxidants,alkalies and sources Viscosity CPS®25°C:Nil sources of heat. of heal. Freezing/Malling Point: SECTION XI-ENVIRONMENTAL RISKS SECTION VI-HEALTH HAZARD DATA Fahrenheit: 98.6 Celsius: 37 Aquatic Toxicity: Not indicated. Overexposure Effects: Depression,Circulatory Collapse, Bolling Point: Fahrenheit: Water-212;Remainder at Biodegradability: Not indicated. Convulsions,Respiratory Failure >480: Celsius:Water-100;Remainder at>250 Partition Coefficient: Not indicated. Inhalation: None expected under normal condition of use. Congealing Point:Fahrenheit:WI;Celsius:WI SECTION XII-REGULATORY INFORMATION Eyes: None expected under normal conditions of use. Vapor Pressure(mm Hg.): WI Refer to the following references: Ingestion: Dry mouth, burning sensation, marled ill Vapor Density(Air-1): WI blurred vision pholophobia,restlessness,disorientation,hallu- OSHA Regulations: If respirator used,29 CFR 1900.134 cination. Percent Volatile: >10 DOT Regulations and EPA Regulations: Not applicable. Skin: Hot,dry,flushed,appearance of rash..Desquamation Evaporation Rate: Nil Other: NDC 0462-0123-75,NDC 0462-0123.15. may occur. Solubility In Water: Atropine Sulfate(Soluble), SECTION XIII-PHYSICAL DATA Chronic Effects: See Ingestion and Skin(above). Remainder(insoluble). Appearance and Odor: A yellow to ten cream that has a faint, Medical Conditions Potentially Aggravated by:Skin irrita- Solubility In Alcohol: Partially soluble. waxy odor lion and allergy In sensitive individuals. Difficulty emptying Solubility In Oil: Base soluble. Molecular Weight: Not appocable. bladder completely,glaucoma,G.I.effects. Solubility Other: WA PH: 6.5 SECTION Vll-REACTIVITY DATA Refractive Index 0 Nil Not applicable. Product Is: Stable ally CPS Chemicals and Conditions to Avoid: Strong oxidizers, Vlecc - visco a 25 25 too°C°C: Not determined. strong acids and bases,and sources of heat. BACITRACIN,-NEOMYCIN-POLYMIXIN- Boiling Point:ng/Maltlny Point:-140°F;Freezing Point: 60°C Hazardous Polymerization: Will not occur. OINTMENT AVDA MSDS No.:MS538 FroazCongealing Point°F:t:-determined. Hazardous Decomposition: May emit toxic fumes. Allen, Inc., BYK Pharmaceutical Group, 60 Baylis Road, Vapor Pressure(mmHg t determined. Not determined. SECTION Vlll-SPILL,LEAK AND WASTE DISPOSAL PRO- Melville,NY 11747.Emergency Telephones:Business Hours: CEDURES (516)454.7677;Other Hours:(516)454.7692;TELEX 144662. Vapor Density(AIR-1):Not determined. Report major leaks and spills to the appropnale local,state Dale of MSDS: May 15,1986 Solubility In Water: Disperses ani federal governmental agency. SECTION 1 PRODUCT IDENTIFICATION Solubility In Alcohol: Partly soluble. Precautionary Measures: Use adequate ventilation and Solubility In Oil: Partly soluble, proper personal hygiene. Stop spill at source If Possible. Common Name: Bacilracin-Neomycin-Polymixin•Ointment Solubility In Other: Not determined. Pickup&Removal: Assure slippery conditions are nullified. CAS Number: WA H Add sand or din. Scoop up a Specific Gravity remove.Wash area with soap Synonyms: N/A ( sO.1):0.99(d 20°C and water, Dispose of in accordance with Federal,state and %Volatile by Volume: -50% local regulations. Formula: Less Than 1%each of the enlibaclerials In Petro l.• bum. Evaporation Rate(diethyl ether reference):0.02 ------- ------------ -- MATERIAL SAFETY DATA Sh iT -- --------------------- Altana ATROPINE SULFATE 1% OPTRALMIC OINTMENT U.S.P. MANUFACTUEC_R'S NAME: ALTT,NA IN,-'. - BYK PHARMACEUTICAL GROUP -------------------------------------------- E. FOUGFRA F. COMP•.NY DIVISION SECTION 7: HEALTH HAZARDS PIiARMADG'RM DIVISION SAVAGEL7,BORATORTES DIVISION PRIMARY ROUTE(S)SIGNS AND SYMPTOMS OF ENTRY: Dermal OF EXPOSURE (For animal effects see 60 BAYL�!• ROAD MELVILL NEW YORK 11747 package insert.): EMERGEI.v C': '"f31-R PHON[; NO. : (51G) -[54-7677 (Business Hours) A. OVEREXPOSURE BFFBCT9: Depression, circulatory (SIG) 454-7692 (other Times) collapse, convulsions, respiratory failure. --------------- B. CHRONIC EFFECTS: See ingestion and skin SECTION 1: IDENTITY 1. INHALATION: None expected under normal condition of use. ----------------- --------------- 2. EYES: None expected under normal conditions of use PRODUCT N.41E Atropine Sulfate 1% ophthalmic Ointment 3. SKIN: Hot, dry, fluohed, appearance of rash. U.S.P. Desquamation may occur. SYNONYMS: 4. INGESTION: Dry mouth, burning sensation, marked thirst, blurred vision photophobia, restlessness, CAS #. CHEMICAL FAMILY: Pharmaceutical ophthalmic ointment disorientation, hallucination. CHEMICAL ;,_i.ropine armace ti Lanolin, white petrolatum, S. MEDICAL CONDITIONS POTENTIALLY AGGRAVATED BY: Skin mineral --ro purified water, chlorobLanolin, tanolwhite petrolatum, irritation and allergy in sensitive individuals. - difficulty emptying bladder completely, glaucoma, G.I. ----- - ------_-_-__-__,_-- SECTION 2: SAFETY AND HAZARD RATINGS effects. ---------------------- HEALTH (Ac;te-Chronic) : 2-2 SECTION 8: SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES FLAI•IMABILI TY: 0 RfiACTIVITT: 0 HYGIENIC PRACTICES: Use proper personal hygiene. ENVIRONMENT (Air-Water-Soil) : 0-2-1 WHEN MATERIAL IS RELEASED OR SPILLED: Stop spill at source ENVIRON ENT (Ds: if possible. Assure slippery conditions are nullified. SPECIAL,IVF EQUIPMENT: Not applicable under normal Add sand or dirt. Scoop up and remove. Waoh area with PROCOTECTIVE of use soap and water. Report major leako and spills to the appropriate local, state and/or federal governmental RATINGS: MINIMAL: 0 agency. WASTE DISPOSAL METHODS: Assure conformity with applicable SLIGHT: 1 MODERATE: 2 disposal regulations. Dispose of absorbed material at SEVERE: approved incineration or chemical landfill waster disposal site. EKTREME: 4 SEt^ ION 3 EMERGENCY AND FIRST AID PROCEDURES SECTION 9: SPECIAL PROTECTION INFORMATIO __ -------------- ------------------------ BYES n Flu . eyes with plenty of water for at least 15 RESPIRATORY PROTECTION: Adequate ventilation. SKIN PROTECTION: Normal hygiene. minute.-•. SKIN: Flu:•!-: with plenty of Eater. EYE PROTECTION: Normal hygiene. INGESTION. Delay absorption by giving activated charcoal, OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Care to avoid then rem-ve by gastric lavage. slippery conditions. ------------------ CALL A PHYSICIAN ---------------------------------- CONTACT A POISON CONTROL CENTER SECTION 10: CONTAINERS AND LABELING SECTION 4: HAZARDOUS INGREDIENTS SPECIAL PRECAUTIONS: Keep at controlled room temperature. -------------------------------------------- RECOMMENDED CONTAINER: As supplied (Not sold in bulk HAZARD DATA quantity) CARCINOGEN ACGIH OSHA PROTECT THE CONTAINER BY: Avoiding physical damage and NAME/CAS ;, 0 IAEC NTP OSHA TLV nEL heat. CONTAINER SHOULD BE HANDLED IN AN AREA WITH: Adequate Atropine :7u1fate No No No Not Applicable ventilation. THE EMPTY CONTAINER IS: Not reusable. 55-48-1 PRECAUTIONARY LABEL: Federal law prohibits dispensing _-_____-___-_-__- ______________________ without prescription. Keep tightly closed. :�':CTION 5: FIRE AND EXPLOSION HAZARD DATA WARNING PLACARD: Keep out of reach of children. IMO HAZARD CLASS#: Not applicable '- UN/NA#: Not applicable FLASH POIN'i' (Closed Cup) : Not indicated HAZARD CLASSIFICATION: Not applicable AUTO-IGNITION TEMPERATURE deg. F: Not indicated DOT NAME: Not applicable FLAMMABLE LIMITS IN AIR BY VOLUME: LEL: Noc indicated SHIPPING INSTRUCTIONS: Keep away from oxidizers, strong UEL: Not. indicated acids, alkalies, and sources of strong heat. ------- --- --------------------------------- EXTINGUISHING MEDIA: Foam -------------- - - , dry chemical, carbon dioxide SECTION 11: ENVIRONMENTAL RISKS SPECIAL F]kE FIGHTING PROCEDURES: Wear self contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: May emit toxic fumes AQUATIC TOXICITY: Not indicated BIODEGRADABILITY: Not indicated PARTITION COEFFICIENT: Not indicated SECTION 6: REACTIVITY DATA (PHYSICAL HAZARDS) STABILITY. Stable CHEMICALS _;ND CONDITIONS TO AVOID: Strong oxidizers, strong acid❑ a:,,d bases, and sources of heat. HAZARDOUS ')ECOMPOSITION PRODUCTS: May emit toxic fumes HAZARDOUS POLYMERIZATION: Should not occur 9/30/97--------------------------------------------- ------------------- 3536254 NORTHWEST VET CLINIC/STANWOOD Page 1 of 2 MWI VETERINARY SUPPLY tii � - - - - - - - -------- - - MATERIAL SAFETY DATA SZ--6T - - - - - -- - - - - - - - -- - -- --- - Altana ATROPINE SULFATE 1% OPTHALMIC OINTMENT U.S.P. ----------------------------------------------------------- SECTION 12: REGULATORY INFORMATION ------ ---------------------------------------------------- REFER TO THE FOLLOWING REFERENCES: OSHA REGULATIONS: If respirator used, 29 CFR 1900.134 DOT REGULATIONS: Not applicable EPA REGULATIONS: Not applicable OTHER: FDA: CFR 330.5 NDC: 0168-7931-91 -------_----..---------------------------------------------- SECTION 13: PHYSICAL DATA ---------------------------------------------------------- APPEAR.zNCE AND ODOR: Pale yellow, odorless ointment MOLECULAR WEIGHT: Not applicable pH: Not applicable REFRACTIVE INDEX ,, 20 deg. C: <1.0 VISCOSITY CEPS W 25 deg. C: Not indicated FREEZING/MELTING POINT deg. F: 98.6 deg F (37 deg C) BOILING POINT: Water-212 deg F (100 deg C). Remainder at greater than 480 deg F (2S0 degC) CONGEALING POINT: Not indicated VAPOR PRESSURE (mmHg 0 20 deg. C) : Not indicated VAPOR DENSITY (Air = 1) : Not indicated SOLUBILITYi IN WATER: Atropine Sulfate (soluble), Remainder (insoluble) SOLUBILITY IN ALCOHOL: Partially soluble SOLUBILITY IN OIL: Base soluble SOLUBILITY IN OTHER: Not applicable SPECIFIC GRAVITY (H20 = 1) : % VOLATILE BY VOLUME: <10 EVAPORATION RATE (diethyl ether reference): Not indicated ----------------------------------------------------------- DATE OF PPEPARAT ION/CHANGE: [larch 27, 1992 REV.: 1 REPLACES: 08-03-89 ----------------------------------------------------------- The information presented herein relates to the specific material described and may not be valid for this material used in combination with any other materials or in any process. This information is, to the best of our knowledge, accurate and reliable on the date compiled. We make no representation, warranty, or guarantee as to its accuracy, reliability,- or completeness. It is the reader's responsibility to ascertain whether the information supplied is suitable and complete for that person'. -pecific uses. ----------------------------------------------------------- DISCLAIMEL. OF EXPRESSED AND IMPLIED WARRANTIES: Although reasonable care has been taken in the preparation of this docl:mei,t, extend nQoarranties and make no representation as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose(s) . A request has been made to the manufacturer to approve the contents of this material safety data sheet. Upon receipt a new MSDS will be made available. ----------------------------------------------------------- COMPAS Code 14060020 NAC Approved Date: / / . 9/30/9?----------------- -------------------------------—-------- MWI VETERIN_=.PY ,SUPPLY 3536254 NORTHWEST VET CLINIC/STANWOOD Page 2 of 2 -- - - -- - - - - --------- -- MATERIAL SAFETY DATA 5 ')ET -- -- - -- - - - -- - - - - -- - - - - - Pharmaderm BACITRACIN-NEOMYCIN-POLYMYXIN TOPICAL OINTMENT AND STERILE OPHTHALMIC OINTMENT --------------------------------------------------------------------------------------------------------------------------- MANUFACTURER'S NAME: PHARMADERM, INC. ----------------------------------------------------------- DIVISION OF ALTANA INC. SECTION 7: HEALTH HAZARDS 60 BAYLIS ROAD ----------------------------------------------------------- MELVILLE, NEW YORK 11747 PRIMARY ROUTE(S) OF ENTRY: Dermal EMERGENCY TELEPHONE NO. : SIGNS AND SYMPTOMS OF EXPOSURE: (516) 454-7677 (Business hours) a. OVEREXPOSURE EFFECTS: Allergy, kidney and liver (516) 454-7692 (Other times) impairment, dizziness, incoordination, sensory loss, ----------------------------------------------------------- deafness, nausea, vomiting and diarrhea. SECTION 1: IDENTITY b. CHRONIC EFFECTS: May cause allergic reactions in ----------------------------------------------------------- susceptible individuals. PRODUCT NAME: Bacitracin-Neomycin-Polymyxin Topical 1. INHALATION: Not likely due to the physical state of the Ointment and Sterile Ophthalmic Ointment product. SYNONYMS: "Triple" Antibiotic Ointment 2. EYES: Use only specified ophthalmic ointment in eyes. CAS #: Not applicable Topical ointment will cause eye irritation. CHEMICAL FAMILY: Antibacterials in petrolatum. 3. SKIN: Non-toxic under standard application. FORMULA: Less than It each of the antibacterials in 4. INGESTION: May cause kidney, liver and gastro-intestinal petrolatum. Ophthalmic ointment also contains mineral impairment; may induce dizziness, incoordination, oil. sensory loss and deafness. ----------------------------------------------------------- 5. MEDICAL CONDITIONS POTENTIALLY AGGRAVATED BY: SECTION 2: SAFETY AND HAZARD RATINGS Susceptible individuals may have an allergic reaction. ----------------------------------------------------------- ----------------------------------------------------------- RATINGS: Minimal 0; Slight 1; Moderate 2; Severe 3; SECTION 8: SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES Extreme4 ----------------------------------------------------------- HEALTH (Acute-Chronic) : 1-1 PRECAUTIONS TO BE TAKEN IN HANDLING/STORAGE: Keep FLAMMABILITY: 1 containers closed when not in use. Do not handle or store REACTIVITY: 0 near heat, flame or oxidizers. ENVIRONMENT (Air-Water-Soil) : 0-0-3 HYGIENIC PRACTICES: Wash thoroughly after handling. Use SPECIAL HAZARDS: None normal hygiene to protect hands, eyes and skin. Use PROTECTIVE EQUIPMENT: General ventilation, eye and hand general ventilation to protect your lungs. Do not wear wash. contaminated clothing until thoroughly laundered. ----------------------------------------------------------- WHEN MATERIAL IS RELEASED OR SPILLED: Assure slippery SECTION 3: EMERGENCY AND FIRST AID PROCEDURES conditions are nullified. Add sand or dirt. Scoop up and ----------------------------------------------------------- remove. Dispose in accordance with federal, state and EYES: Flush eyes with copious amounts of water for at least local regulations. 15 minutes. (Non-ophthalmic form only.) WASTE DISPOSAL METHODS: Assure conformity with applicable SKIN: Wash with soap and water. disposal regulations. Dispose of absorbed material at INGESTION: Induce vomiting. Do not give anything to an approved incineration or chemical landfill waste disposal unconscious person. site. CALL A PHYSICIAN ---------------------------------------- ----——---- CONTACT A POISON CONTROL CENTER SECTION 9: SPECIAL PROTECTION INFORMATION ----------------------------------------------------------- ----------------------------------------------------------- SECTION 4: HAZARDOUS INGREDIENTS RESPIRATORY PROTECTION: General ventilation. ----------------------------------------------------------- SKIN PROTECTION: Normal hygiene. HAZARD DATA EYE PROTECTION: Normal hygiene. NAME/ CARCINOGEN ACGIH OSHA OTHER PROTECTIVE CLOTHING OR EQUIPMENT: As needed to CAS # IARC NTP OSHA TLV PEL prevent repeated/prolonged contact. ----------------------------------------------------------- ----------------------------------------------------------- This section is not applicable to the products: SECTION 10: CONTAINERS AND LABELING Bacitracin-neomyxin-polymyxin topical ointment and sterile ----------------------------------------------------------- ophthalmic ointment SPECIAL PRECAUTIONS: Keep container closed. Store away from ----------------------------------------------------------- oxidizers and sources of heat and flame. SECTION 5: FIRE AND EXPLOSION HAZARD DATA RECOMMENDED CONTAINER: As supplied (not sold in bulk ----------------------------------------------------------- quantity) . FLASH POINT (Closed Cup) : 390 deg F, 199 deg C (97% PROTECT THE CONTAINER BY: Avoiding physical damage and petrolatum concentration) heat. AUTO-IGNITION TEMPERATURE deg F: Not determined CONTAINER SHOULD BE HANDLED IN AN AREA WITH: Cool dry FLAMMABLE LIMITS IN AIR BY VOLUME: conditions. LEL: Not determined THE EMPTY CONTAINER IS: Not reusable. UEL: Not determined PRECAUTIONARY LABEL: No EXTINGUISHING MEDIA: Alcohol foam, dry chemical and CO2. WARNING PLACARD: No SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective IMO HAZARD CLASS#: Not applicable clothing. UN/NA#: Not applicable UNUSUAL FIRE AND EXPLOSION HAZARDS: May emit toxic fumes. HAZARD CLASSIFICATION: Not applicable ----------------------------------------------------------- DOT NAME: Not applicable SECTION 6: REACTIVITY DATA (PHYSICAL HAZARDS) SHIPPING INSTRUCTIONS: Keep away from oxidizers and sources ----------------------------------------------------------- of heat. STABILITY: Stable ----------------------------------------------------------- INCOMPATIBILITY (Material to Avoid) : Extreme heat, sparks, SECTION 11: ENVIRONMENTAL RISKS open flame, oxidizers, strong acids and alkalies. ----------------------------------------------------------- HAZARDOUS DECOMPOSITION PRODUCTS: May give off fumes of AQUATIC TOXICITY: Not indicated carbon monoxide and carbon dioxide. BIODEGRADABILITY: Not indicated HAZARDOUS POLYMERIZATION: Should not occur PARTITION COEFFICIENT: Not indicated 3/28/97------------------------------------------------------------------------------------------------------------------- ProVet*Seattle 226580 NORTHWEST VET CLINIC Page 1 of 2 •� r 1: [� I I 701 PHYSICAL AND CHEMICAL PROPERTIES STABILITY AND REACTIVITY Miles Inc. Physical Data Reactivity Baling Pam: 100*F Stability:Stable P;p. Box 3�0 Appearance: Dark brown liquid Conditions to Avoid: Keep away from heal and fire. ! iq l,L, f. h Odor: Bleach smell Materials to Avoid: Oxidizers,strong reducing agents,powdered metals, Shawnee Mission; KS 66201 cyanides,carbides,chlorates,nitrates,fulminates,picrates and sulfides STABILITY AND REACTIVITY Hazardous Decomposition: None Emergency # (913) 631-4800 Reactivity TOXICOLOGICAL INFORMATION Stability:Stable See"Hazard Identification" Hazardous Decomposition: None - Baytril 22.7 mg/ml Iniectablo DISPOSAL CONSIDERATIONS MSDS No: MS4295 September 26,1989 TOXICOLOGICAL INFORMATION Waste Disposal Method:To be performed in accordance with all cur- See"Hazard,Identification" rent local,Slate and Federal regulations CHEMICAL PRODUCT IDENTIFICATION DISPOSAL CONSIDERATIONS Product Identification Waste Disposal Method:To be performed in accordance with all cur- Safranin Product Nome: 22.1 my/ml Injectable rent local,Stare and Federal regulations. Product Code Nuumbembe r:Objective No. 10261 MSDS No: MS3491 Chemical Family:Antimicrobial-Quinoline Compound CHEMICAL PRODUCT IDENTIFICATION Chemical Name:Active Ingredient (A.L) Ityclopropyl-7{4-ethyl•l- piperazinyl)-6-fluoro-l4-dihydro-4oxo-3-quinolinecarboxylic acid Identification rtio Synonyms:A I Enrofloxacin, Bay Vp 2674 Gram Decolorizer Product Name:Safra 60-6 MSDS No: MS3489 August 6,1990 Catalog No.:6002,6006,6008,6014,6016,6022,6133,SP770.25 CAS Number.A.I. data a LS.C.A.Status:No data available(NDA),To be listed with FDA CHEMICAL PRODUCT IDENTIFICATION COMPOSITION/INFORMATION ON INGREDIENTS Chemical Formula: Mixture,does not apply Identification Hazardous Ingredients Product Name:Gram Decolorizer Component Concentration COMPOSITION/INFORMATION ON INGREDIENTS Catalog No.:6002,6005,6008,6012,6013,6016,6020,6021.6131,SP Denatured Ethanol 20% Hazardous Ingredients 770.25 EXPOSURE HAZARD IDENTIFICATION i UMIT COMPOSITION/INFORMATION ON INGREDIENTS Health Hazard Data OSHA- ACCIH- Hazardous Ingredients COMPONENTS: Approximate%PELITWA TLV/TX.TA Toxicology:Skin-Nnin-irritant,noncorrosive;Eyes-Irritant,corrosive. Component Concentration Airborne Exposure Umlt: 200 ppm n-Butyl alcohol 3.0 50 PPM ceiling 50 PPM ceiling Denatured Alcohol 750 ml/h Effects of overexposure: Eye irritation,drowsiness,nausea,ingestion (CAS 71-36-3) Skin Skin Acetone 250 mNt may cause blindness. Enrofloxacin 2.27 NE NE FIRST AID MEASURES 6)AS 9310660- HAZARD IDENTIFICATION First Aid Procedures Health Hazard Data Eyes: Flush with water,contact a physician. Toxicology:Skin-Irritatm,corrosive;Eyes-Irriant,corrosive. Skin:Wash with soap and water. HAZARD IDENTIFICATION Airborne Exposure Limit: I mg/cubic meter Inhalation: Remove to fresh air,contact a physician. Human Health t:This Data Effects of Overexposure: May cause bums of skin,eyes and mucous Ingestion: Induce vomiting,contact a physician Hazard Statement:This product t hazardous under the criteria of the Federal OSHA Hazard Communication Standard,29 CFR 1910J200. membranes IRE FIGHTING MEASURES Primary Route(s)of Entry:Skin contact,eye and inhalation F FIRST AID MEASURES FIRire and Explosion Data Human Effects and Symptoms of Overexposure:NDA on product- P treat as unknown.Avoid excessive exposure;Acute Exposure-Excessive First Aid Procedures Flash Point:48•F Closed Cup exposure may occur during manufacturing or due to unusual conditions Eyes: Flush with water,contact a physician Fire and Explosion Hazards: Flammable,keep from heat and sparks. such as large spill which may subject inidividuals to potentially excessive Skin: Flush with water,contact a physician. Extinguishing Media: Dry chemical,carbon dioxide,water spraylfoam. hazardous components of the product.The effects of the normal exposure Inhalation: Remove to fresh air,contact a physician. Unusual Fire and Explosion Hazards: None would be minimal due to the concentration of the hazardous components Ingestion: If conscious,give large quantities of water,contact a physi- in the product and small product packages;Chronic Exposure-Butyl clan ACCIDENTAL RELEASE MEASURES alcohol may cause hearing loss., Spill or Leak Procedures Eye:NDA on product,may cause irritation; Acute Fxpcaurc •Bury[ FIRE FIGHTING MEASURES Spill Procedure: Mop up with paper towels and discard alcohol will cause irrilation.Vapors ofBury]alcohol can causel;crtmation, Fire and Explosion loslon Data splashes cause inflammation and blurred vision. Technical-NDA,may P cause irritation;Chronic Exposure-NDA Flash Pam:21•F,closed Cup HANDLING AND STORAGE Dermal:NDA on product;a scratch test was performed on one employee Fire and Explosion Hazards: Flammable,keep from heat and sparks Handling and Storage:Store in a cool,dry place,avoid heat&flames. to check for allergic response to the A.I.the mdietdual was found not to Extinguishing Mole: Dry chemical,carbon dioxide,water spray/foam be sensitive;Acute Exposure-Butyl alcohol will cause irrtaton Chronic Unusual Fire and Explosion Hazards:None EXPOSURE CONTROLS/PERSONAL Exposure-Bury]alcohol may cause drying and cracking of the skin. PROTECTION Inhalation: NDA on product;Acute Exposure-Butyl alcohol is irritating ACCIDENTAL RELEASE MEASURES Special Protection Information to mucous membranes and upper respiratory tract. Butyl alcohol may Spill or Leak Procedures Ventilation: Local exhaust ventilation cause NDA headache and dizziness,drowsiness may occur;Chronic Exposure Spill Procedure:Neutralize spills with lime or soda ash. Respiratory Protection:N/A Protective Clothing:Gloves Ingestion:NDA on product;Acute Exposure-Butyl alcohol may have Eye Protection: Safety gogggles narcotic effect and may cause abdominal pain, nausea and diarrhea; HANDLING AND STORAGE Chronic Exposure-NDA Handling and Storage:Store in a cool,dry place,avoid heat and flame. PHYSICAL AND CHEMICAL PROPERTIES Medical Conditions Aggravated by Exposure:Persons with pre- Physical Data existing skin disorders or eye problems, or impaired liscr, kidney or EXPOSURE CONTROLS/PERSONAL Boiling Pant:Not known for this mixture respiratory function may be more susccptable to the etfceu of Bury[ PROTECTION Appearance: Red liquid alcohol. Special Protection Information Odor: Pungent odor Carcinogenicity:NTP-Not Listed;IARC-Not Listed;OSHA-Not listed Exposure Guidelines:OSHA P.E.L-NE;ACGIH TLV-NE;Other- Ventilation: local exhaust ventilation NE Respiratory Protection:N/A STABILITY AND REACTIVITY Protective Clothing:Gloves Reactivity FIRST AID MEASURES Eye Protection:Safety goggles Stability:Stable Emergency&First Aid Procedures Hazardous Decomposition: None In Case of Poisoning: Contact a physician. PHYSICAL AND CHEMICAL PROPERTIES TOXICOLOGICAL INFORMATION Eye Contact: Flush with water for 15 minutes. Physical Data See"Hazard Identification" Skin Contact: Wash with soap and water. Boiling Part:65•C Inhalation: Move to fresh air Vapor Pressure'(mm Hg): 70 DISPOSAL CONSIDERATIONS Ingestion: If person is conscious,give liquids to dilute,induce vomiting, Appearance:Clear liquid Waste Disposal Method:To be performed in accordance with all cur- repeat until clear,contact a physician. Odor: Pungent odor rent local,State and Federal regulations. Note to Physician: None :;, r 77e �APOSURE CONTROLS/PERSONAL C(_ ,OSITION/INFORMATION ON INGREDIENTS PROTECTION Hazardous Ingredients The Prince Manufacturing Company Control Measures Name % Toxicological Data continued Respiratory Protection: Use NIOSH approved particulate respirator if Povidine Iodine USP 10 Mouse Oral LDw>8100mg/kg. Rat IV dust generation occurs or is anticipated USBM approved schedule 21B LD 80>640mg/kg respirator or equal is recommended Glycerin I Ventilation:A system of local and/or general is recommended to keep Manganous Oxide continued employee exposures below the Airborne Exposure limits.Local exhaust Igepal CO 0.25 is generally preferred because it can control the emissions of the u,niam• Purified Mier 8875 inane at its source,preventing dispersion of it into the general work area. No component is listed by NTP or IARC as having carcinogenic potential. COMPOSITION/INFORMATION ON INGREDIENTS Please refer to the ACGIH document,"Industrial Ventilation,A Manual Components and Contaminants of Recommended Practices,"most recent edition,for details. HAZARD IDENTIFICATION Chemical Name: Protective Gloves: Yes Chemical Eye Protection: Safety goggles are recommended. Health Hazard Data Name CAS# OSHA PEL ACGIH TLV Percent Other Protective Clothing or Equipment: Use other protective equip- Threshold Limit Value:None established en OSHA or ACGIH ment when necessary in order to avoid prolonged exposure to skin a tops of Overexposure:This produce is generally recognized g safe es Manganese 7439.96.5 5 mg/m(C)5 mg/m(C) 60.67%Mn a topical antimicrobial agent No evidence is available that it aggravates Compound(as Work and Hygienic Practices:Observe good personal hygiene Wash medical conditions or has an adverse effect upon inhalation. Mn) after handling. Iron Oxide 1309-37.1 — — 4.5%Fe203 FIRST AID MEASURES Silica,Crys• 14808.60-7 0.1 mg1m3 0.1 3.3.5%Si02 PHYSICAL AND CHEMICAL PROPERTIES Emergency and First Aid Procedures for Eyes: Flush with running talline Quartz 3 Physleel Data water. Emergency and First Aid Pruccdures if Swallowed: No harmful mg/m(TWA) effect expected. Not(respirable) Bolling Point: NA Aluminum 1344.28.1 15 mg/ma 15 3.5%A1203 Specific Gravity(H20=1): 5.0 recommended toendedfor Physicians: on iodine Solution contains iodine,Therefore,is not Oxide mg/ma(TWA) Vapor Pressure(mm/Hg): NA recommended for use on iodine sensitive patients. Banum Oxide 1304-28-5 0.5 mg/ma 0.5 0.2.2%BaO Melting Point(Decomposes); 190•C FIRE FIGHTING MEASURES mg/m'(TWA) Vapor Density(Air=l): NA Fire&Explosion Hazard Data Evaporation Rate(Butyl Acelaie=l): NA Flash Point:Not flammable HAZARD IDENTIFICATION Solubility In Water: insoluble Flammable Limits: None;Lower•N/A;Upper•NIA Appearance and Odor:green to greenish brown,no odor Special Fire Fighting Procedures: N/A Health Hazard Data Unusual Fire and Explosion Hazards:None Route of Entry: INHALATION: May irritate the respilatory tract. STABILITY AND REACTIVITY May mcicase the incidence of upper respiratory Infections(pneumonia). ACCIDENTAL RELEASE MEASURES )KIN May cause irritation. INGESTION:May cause abdominal pain Reactivity Data lls and nausea, Manganous oxide dust is absorbed through the digestive Stability:Stable under ordinary conditions of use and storage. shout to W Taken in Coonase Material ; ash Released a Spilled: dote tract Conditions to Avoid: Will decompose if heated to manganese sesquiox- should be r dilute ups soon as pole sol;wash anaffd copious area with dilute Health Hazards(Acute and Chronic):Chronic exposure and inhalation ide. ammonia or dilute sodium thiosulfate solution and copous quantities of l excessive manganese dust may cause disorders of the central nervous water u B Y Incompatibility(Materials to Avoid):Calcium Hypochlarile,fluorine system Prolonged exposure to silica dust may result in silicosis,a fibrotic Hazardous Decomposition or Byproducts: None HANDLING AND STORAGE lung disease Carcinogenicity:NTT-No;IARC Monographs-Yes(Silica) Hazardous Polymerization:Will not occur. Special Precautions Signs and Symptoms of Exposure: Early symptoms of manganese Precautions to be Taken In Handling and Storing:N/A icy include sluggishness,sleepiness,and weakness in legs.Symptoms DISPOSAL CONSIDERATIONS Other Precautions:N/A icosLs include impaired pulmonary function and wheezing Waste Disposal Method: Dispose of unreclaimable material in a EXPOSURE CONTROLS/PERSONAL Aggravation of Pre-Exuding Conditions: Persons with impaired respi• RCRA-approved waste facility PROTECTION rator)function may be more susceptible to the effect of this substance. REGULATORY INFORMATION SpecialRespiratory Protection ivN/A Information Respiratory Protection:NIA ' FIRST AID MEASURES SARA Title III Section 313 Supplier Notification:This product can- Ventilation: Local Exhaust-N/A;Mechanical(General)•N/A;Special Emergency and First Aid Procedures tains the following toxic chemicals subject to the reporting requirements .NIA;Other•N/A If Inhaled: Remove to fresh air and seek medical attention for any breath- of section 313 of the Emergency Planning and Community Right-to Know protective Gloves: N/A ing difficulty. Act'of 1986 and of 40 CFR 372.45:In Case of Skin Contact: Wash with soap&water. Seek medical at. Component CAS# %by Weight Other Eye Protector: N/A Protection: llva Equipment: NIA tention if red&irritated. Manganous Oxide 1311J5.7 60-63%Mn In Case of Eye Contact:Flush eyes immediately with water for at least Aluminum Oxide 1344-28-1 3-5%AI203 PHYSICAL AND CHEMICAL PROPERTIES IS minutes.Seek medical attention if irritation persists. Barium Oxide 1304.28.5 0.1.1.8%Ba Physical Data If ingested: Induct vomiting immediately by giving two glasses of water Specific Gravity(H20=1): 1.02 and sticking finger dvwn'thtom Never give anything by mouth to an This information must be included in all MSDS's that are copied and unconscious person Call a physician immediately. distributed for this material. Appearance 6.0 prenee and Odor: Reddish brown,clear liquid,faint odor. FIRE FIGHTING MEASURES STABILITY AND REACTIVITY Fire and Explosion Hazard Data Reactivity Data Flash Point: Not Combustible Stability:Stable Flammable Limits: LEL-NA;UEL-NA The Purdue Frederick Company Storage:Store at room temperature Exftingulshing Media: Foam,CO2,dry chemical or water Incompatibility: Not stable toward reducing agents or strong alkalies. Special Fire Fighting Procedures: In the event of fire,wear full pro- 100 Connecticut Avenue Hazardous Decomposition Products: None iective clothing and NIOSH-approved self-contained breathing apparatus Hazardous Polymerization:Will not occur with full face piece operated in the pressure demand or other positive Norwalk, CT 06856 Conditions to Avoid: None pressure mode Unusual Fire and Explosion Hazards: Not combustible. Information # (203) 853.7700 Corrosive to Metal: Yes Type: Iron;can discolor gold or silver Oxidizer Yes ACCIDENTAL RELEASE MEASURES Material Raise"or Spill Precautions:Should a spill occur,ventile Betadlne Solution DISPOSAL CONSIDERATIONS area Cleanup personnel require respiratory protection. Recover on* Waste Disposal Method: Do not discharge more than minute quantities contaminated material for use. Vacuum or sweep remaining material, MSDS N0: MS3370 into waterways or sewer systems.Neutralize with suJmm thiosulfate prior keeping dust to a minimum. to disposal. CHEMICAL PRODUCT IDENTIFICATION Container Disposal: In similar manner as other plastic battles. HANDLING AND STORAGE Identification Precautions for Safe Handling and Use Product Name: Beladine Solution OTHER INFORMATION dling and Storing Precautions:Protect containers from damage Chemical Names/Synonyms: Povidone Iodine Solution USP PVP•I. Environmental Data keep closed when not in use. Chemical Family: Polymer,complex of Poiyvinylpyrrolidone with iodine Hazardous Substance Under'Superfund': No Other Precautions: Observe good personal hygiene. Wash after ban. Formula: (C6119NO)n x 1 Hazardous Waste,40 CFR 2621: No dltng CAS Registry No.:25655.41-8 Hazardous Waste Number: N/A 802 FIRE FIGHTING MEASURES Flash Point: NIA Betamethasone Valerate Cream 0.1% Rugby Labs, Inc. continued Flammable Limits: Lower-N/A;Upper-NIA MSDS No: MS4870 Extinguisher Media: Water spray,dry chemical,carbon dioxide or foam as appropriate for surrounding lire and materials. CHEMICAL PRODUCT IDENTIFICATION Co-lgnttlon Temperature: N/A Identity Social Fire Fighting Procedures:As with all fires,evacuate personnel to safe area. Firefighter vhould use self-contained breathing equipment Common Name Used on Label:Betamethasone Valerate Cream USP Betamethasone Sodium Phosphate, and protective clothing 0.1% MSDS No: MS4886 March 24,1988 Visual Fire and Explosion Hazards: lbrs material is assumed to be CAS No,: N/A combustible.As with all dry powdets it o advisable to ground mechanical Chemical Name: Betamethasone Valerate Cream USP 0.1% equipment in contact with dry material to dissipate the potential buildup Chemical Family: CHEMICAL PRODUCT IDENTIFICATION of Italic electricity. When heated to decomposition material emits toxic Formula:See Package Insert Identity fumes. Emits toxic fumes under fire conditions. NDC 0536-4310-28 Prod.No.6004315:Rugby Betamethasone Valer• Common Name: Betamethasone Sodium Phosphate ate Cream,USP 0.1%,Net Wt.45g. Synonyms: Betamethasone Disodium Phosphate ACCIDENTAL RELEASE MEASURES CAUTION:Federal law prohibits dispensing without prescription. CAS Number: 378.44-9(Betamethasone) Special Precautions and Spill/Leak Procedures RTECS Number:TU4000000(Betamethasone) Steps to be Taken In Case Materiel Is Spilled or Released:Wear Chemical Name:Pregna•1,4-diene•3,20-dione,9•fluoro•11,17•di- approved respirator and chemically compatible glove%.Vacuum of sweep COMPOSITION/INFORMATION ON INGREDIENTS hydrom-16-methyl-21•(phos phonoxy)•,disodium sail(I ib,16) up spillage.Arvid dust Place spili.rge tit appropriate container for waste Hazardous Ingredients:N/A•See Innovator's Product Chamlcal Family:Steroid disposal. Wash contaminated clothing fettle reuse- Ven/ilale area and Contains: Each gram of Betamethasone Verile Cream d,1'1 conrauo Therapeutic Category: Adrenocorticoid (topical); anti-inflammalory wash spill site L2 mg betamc(hasonc+alerale,(equivalent to Lit mg bctamcthauinc) (steroidal) with mnerii od.%hilt pclniLnum,pclyclhylenc glycol i0o) iceeare0:- Formula: C,_Hj8FNa;ONP HANDLING AND STORAGE 15,celyl alcohol,stearyi atcuhui,propylene glycol,punned water and Precautions to be Taken In Handling and Storage:Store in tight 4-chloro-m•cresol as preservative. COMPOSITION/INFORMATION ON INGREDIENTS container as defined in the United States Pharmacopeiris material sho a. "I uld be handled and stored per label and other instructions to ensure HAZARD IDENTIFICATION Hazardous Ingredients product integrity. No data provided. THRESHOLD LIMIT Other Precautions:Avoid contact with eyes,skin or clothing. Avoid NAME PERCENT VALUE(UNITS) brathing dust or mist.Use with adequate dust control.Wash thoroughly after handling. Wear fresh clothing daily Wash contaminated clothing FIRST AID MEASURES Betamethasone Sodium Pure Material Not Established before reuse. Do not permit eating,drinking of smoking near material. Phosphate Attention:This Product is Sold as a Reference Standard for Use In No data provided. Chemical Analysis Not For I luman Consumption. HAZARD IDENTIFICATION FIRE FIGHTING MEASURES Health Hazards EXPOSURE CONTROLS/PERSONAL Flash Point: NIA Threshold Limit Value: None established PROTECTION Flammable Limits In Air by Volume: N/A Lower Upper Signs and Symptoms of Overexposure:Betamethasone CAS RN: Special Protection Information Extinguisher Media:N/A 378.44.9 Reproductive Effects Data IRTECSJI Betamethasone Dipfe- Respiratory Protection(Specify Type):NIOSH approved respirator Auto Ignition Temperature:NIA ownate CAS RN 5593.20434 LD,o 103 of iniraperitoncal•mouse; Ventilation:Adequate; Local Exhaust-Recommended; Mechanical Special Fire Fighting Procedures: LD_T: 78100 micrograms/kg subcutaneous-mouse;Reproductive Effects (General)-Recommended:Other-N/A Unusual Fire and Explosion Hazards:N/A Data IRTECSJJ protective Gloves: Rubber The usual adult dose(topical)is to the oral mucous membranes,I pellet Eye Protection: Safety goggles lour limes a day,to be dissohcd close to the ulcer. Possible allergic Other Protective Clothing or Equipment:Appropriate laboratory zp- ACCIDENTAL RELEASE MEASURES reaction to dust of inhaled,ingested or in contact with skin,Suppression of adrenal gland secretion,Cushing's syndrome,water retention,electrolyte parel,protect exposed skin No data provided. Imbalance,hyperglycemia,edema and hypotension. Acute: Eye.skin and/or respiratory tract irritation PHYSICAL AND CHEMICAL PROPERTIES HANDLING AND STORAGE Chronic: Possible hypersensitization Physical and Chemical Characteristics(Fire&Explosion For dermalologic use only,not for ophthalmic use. Precautions to Consider: Persons developing hypersensitivity(anaphy- Data) Usual Dosage:Apply a small amount of cream to the affected skin lactic)reactions must receive immediate medical attention.Material may Bolling Point:MA area one to three times daily See package insert for full Prescribing be irritating to mucous membranes and respiratory tract. As a general rule,when handling USP Reference Standards avoid all contact and in. SPeclflc Grevlty Hz0=1: NIA information Store at r and expiry room temperature of IS'•DO'C(59 halation of dust,fumes,mists,and/or vapors associated with the material. Vapor Pressure(nine lig): NIA 86'F).For lot number and expiry date see crimp. Keep container tightly closed and use with adequate ventilation:wash Percent Volatile by Volume(If): NIA thoruughly after handling- Individuals working with chemicals should Vapor Density(Ati= 1): NIA EXPOSURE CONTROLS/PERSONAL :onsider all chemicals to be potentially hazardous even if their individual Evaporation Rate: N/A PROTECTION hazards may be uncharacterized or unknown. Exposure may cause eye and skin irritation or allergic reaction in sensitive individuals. Solubility In Water: Freely solublr No data provided. Medical Conditions Aggravated by Exposure; Hypersensitivity to ma. Reactivity In Water: N/A terial,systemic fungal infections Appearance and Odor: White to practically white hygroscopic powder, PHYSICAL AND CHEMICAL PROPERTIES Chemical Listed at Carcinogen of Potential Carcinogen: NTP-No; odorless [ARC Monographs-No; OSHA-No;Other-NIA Physical&Chemical Characteristics(Fire&Explosion ACGIH TLV: N/A STABILITY AND REACTIVITY Other Exposure Limits Used: NIA Physical Hazards Bolling Point: N/A OSHA Permissible Exposure Limit:Not established Solubility:Stable Specific Gravity(H20-1):N/A Other Exposure Llmk Used:Not established Conditions to Avoid: Material is stable from a safety point of view. Vapor Pressure(mm Hg):N/A Inhalation: May cause irritation of respiratory tract. Remove to fresh Avoid heal,moisture and excessive light. Percent Volatile by Volume(%):NIA au. Incompstablllly(Materials to Avoid): Acids,bases,oxidant and reduc- Vapor Density(Air=[):N/A Eyes: May cause irritation. Flush with copious quantities of water. live agents Evaporation Rate(=1):N/A Skin: May cause irritation. Flush with copious quantities of water. Hazardous Decomposition Products: When heated to decomposition Solubility In Water: Very slightly soluble(Readily miscible with water) Ingestion: May cause irritation. Flush out mouth with water. material emits toxic fumes. Emits toxic fumes under fire conditions. Reactivity In Water: Not Reactive Hazardous Polymerization: Will Not Occur Appearance and Odor:Smooth while cream with a characteristic odor. FIRST AID MEASURES Emergency and First Add Procedures: Remove from exposure. Re- DISPOSAL CONSIDERATIONS STABILITY AND REACTIVITY move contaminated clothing.Persons developing serious hypersensitivity Waste Disposal Methods: Dispose of waste in accordance with all No data provided, reactions must receive immediate medical attention Upon eye or skin applicable Federal,State and local laws. contact,flush affected area with copious quantities of water.Obtain med- ical attention. If not breathing give artificial respiration. If breathing is difficult give oxygen. Manufacturer:Sicris Laboratories,Inc Manufacturer:Taro Pharmaceuticals,Inc. �• �, z I +I I - - MATERIAL SAFETY DATA SE - ------ ------------ -- -- Schering-Plough BEUTHANASIA-D SPECIAL — ----------------------------------------------------- DATE: January 1993 MANUFACTURER: 9CHBRING-PLOUGH ANIMAL HEALTH EXPOSURE AND EFFECTS P.O. BOX 529 ----------------------------------------------------------- KSNILWORTH, NJ 07033 INHALATION: This product contains materials at greater than COMPANY CONTACT: Animal Health Tech. Services one percent which, if undiluted, have the following TELEPHONE NUMBER:Animal Health health effects upon inhalation: May be irritating to EMERGENCY CONTACT: 800)Sche 932-Plough mucous membranes. Can cause sleepiness, mental confusion, unsteadiness, come with slow, shallow respiration, EMERGENCY PHONE NUMBER: Rocky Mountain Poison Center,595-4869. flaccid muscles, hypertension, cyanosis, hypothermia or 303 hyperthermia, and absent reflexes. -------------------- IDENTIFICATION FIRST AID: Remove from exposure. If breathing is feeble or ceases, give cardiopulmonary resuscitation. Obtain PRODUCT: Beuthanasia-D Special medical attention. CAS NUMBER: Not Established SKIN: This product contains materials at greater than one CHEMICAL FAMILY: N/A percent which, if undiluted, have the following health CHEMICAL FORMULA: N/A effects upon skin contact: May be irritating to the skin. HAZARD RATING: FIRST AID: Remove contaminated clothing. Thoroughly wash exposed area with ooap and water. Obtain medical HEALTH: 1 Slight attention. FIRE: 1 Slight REACTIVITY: 0 Negligible EYES: This product contains materials at greater than one SPECIAL HAZARDS: A schedule III controlled drug. percent which, if undiluted, have the following health effects upon eye contact: May be irritating to the eyes. CHEMICAL COMPONENTS FIRST AID: Flush with water for at least 15 minutes. -------------------------- ____-.-__________________________ obtain medical attention. Component of Mixture OSHA PEL ACGIH TLV INGESTION: This product contains materials at greater than CAS No. one percent which, if undiluted, have the following __________ ______________________________ health effects upon ingestion: Can cause sleepiness, Benzyl Alcohol 2.0 None None mental confusion, unsteadiness, come with slow, shallow 100-51-6 respiration, flaccid muscles, hypotenoion, cyanosis, Ethyl Alcohol 10.0 1000 ppm 1000 ppm hypothermia or hyperthermia, and absent reflexes. FIRST AID: Give copious amounts of water and induce 64-17-5 Pentobarbital Sodium .4 None None vomiting, if conscious. Obtain medical attention. 0 MISCELLANEOUS TOXICOLOGICAL INFORMATION: Pentobarbital 57-33- P57-33-in Sodium 05 None None Sodium is a physiologically active drug substance, It is toxic is ingested. 630-93-3 --------'--------- Propylene Glycol 16.0 None None REACTIVITY & POLYMERIZATION 57-55-6 PHYSICAL DATA STABILITY: Stable. -- _ ____________________________________________ CONDITIONS TO AVOID (STABILITY) : Avoid open flame and high BOILING POINT (deg C): N/A temperatures. MELTING POINT (deg C): N/A HAZARDOUS DECOMPOSITION PRODUCTS: CO & CO2 VAPOR PRESSURE: N/A HAZARDOUS POLYMERIZATION:-Will not occur. ----------- ------- --------------- SPECIFY GRAVITY: N/A SOLUBILITY (H2O): N/A SPILL, LEAK, & DI PROCEDURES ------ PERCENT VOLATILES: N/A EVAPORATION RATS: N/A STEPS TO BE TAKEN IN THE EVENT OF SPILLS, LEAKS, OR RELEASE: Squeegee, sweep, scoop, or vacuum up spill. APPEARANCE: Clear, pink solution.---- __________________ Minimize contact with spilled material. Keep other ------------- ------------ FIRE FIGHTING & EXPLOSION DATA personnel away from the clean up area. Wear appropriate ______ ___________________________________ respiratory protection and protective clothing in the FLASH POINT (deg F): N/A spill area. Notify your supervisor immediately. Clean AUTOIGNITION (deg F): N/A area with a wet mop. Dispose of spilled material and LOWER EXPLOSIVE LIMIT (t): N/A clean up materials as given in Waste Disposal Methods UPPER EXPLOSIVE LIMIT (%): N/A below. FIRE AND EXPLOSION HAZARDS: Under normal conditions of use WASTE DISPOSAL METHODS: While not considered a hazardous this material does not present a significant fire or waste, material should be disposed of in the presence of explosion hazard. a DEA representative. EXTINGUISHING MEDIA: CO2, Dry Chemical, Water, Water Spray. SPECIAL FIRE FIGHTING INSTRUCTIONS: Fight fire from a oafs distance or protected location. Use water spray to keep containers and equipment cool. Wear full protective equipment including self-contained breathing apparatus (SCBA). -------------------------------------------------------------------- 4/19/96------------------------------ 2541342 NORTHWEST VET CLINIC/STANWOOD Page 1 of 2 MWI VETERINARY SUPPLY �i lJ I ------------------- - - MATERIAL SAFETY DATA S1. - - - - --- ---- - ------- -- - - Schering-Plough BEUTHANASIA-D SPECIAL ----------------------------------------------------------- SPECIAL PROTECTIVE MEASURES -----------------------—--------------------------------- VENTILATION: Provide adequate local exhaust ventilation when handling bulk material. EYE PROTECTION: Splash goggles/safety glasses when handling bulk material. SKIN PROTECTION: Gloves - Latex or better and lab coat or uniform when handling bulk material. RESPIRATORY PROTECTION: None usually required. Use a half- mask respirator with HEPA cartridges for the material in bulk. WORK/HYGIENIC PRACTICES: Train employees concerning hazards and precautions. Provide adequate local exhaust ventilation. Wash hands and forearms after each use. Use indicated protective equipment while handling. Change respirator cartridges after four hours of continuous use or upon detection of an increase in breathing resistance or eye or nasal irritation. ----------------------------------------------------------- SPECIAL PRECAUTIONS ----------------------------------------------------------- STORAGE & HANDLING: Store in a cool, dry, well ventilated area. ----------------------------------------------------------- DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpoee(e) . ----------------------------------------------------------- COMPAS Code: 39400221 NAC Approved Date: / / . 4/19/96------------------------------------------------------------------------------------------------------------------- MWI VETERINARY SUPPLY 2541342 NORTHWEST VET CLINIC/STANWOOD Page 2 of 2 A '------------------- --- MATERIAL SAFETY DATA S. 1 c:T - - - -- ---- - - - - - - - - ---- - - Upjohn CARBOCAINE-V(R) HYDROCHLORIDE -------------------------------------------- --------------------------------------------------------------------------- REVISION DATE: July 01, 1994 AGENT ID#: 43791 6. ACCIDENTAL RELEASE MEASURES ------------------------------------ ---------- ---------------------------------------------------------- 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: ---------------------------------------------------------- Provide ventilation and respiratory, akin and eye COMMON NAME: Carbocaine-V(R) Hydrochloride protection to prevent overexposure. Keep out of drains; SYNONYMS: 402613 - EDP NUMBER prevent entry to surface water, ground water and soil. MOLECULAR FORMULA: Mixture Vacuum or scoop spilled material and place in container. USE: Veterinary product used for local or regional -------- ------------------------------- anesthesia. Not for human use. 7. HANDLING AND STORAGE MANUFACTURER/SUPPLIER: ----------------------------------------------------------- THE UPJOHN COMPANY PRECAUTIONS FOR HANDLING AND STORING: Avoid contact with 7171 PORTAGE RD. akin, eyes and clothing. Wash thoroughly after handling. KALAMAZOO, MI 49001-0000 Launder contaminated clothing before reuse. Store in a TELEPHONE NUMBERS: (616) 323-5122 - (24 HOURS) cool dry place. Protect from light. Keep out of reach of (616) 323-7555 - (8:00 A.M. - 4:30 P.M.) children. 2. COMPOSITION/INFORMATION ON INGREDIENTS e. EXPOSURE CONTROLS/PERSONAL PROTECTION ----------------------------------------------------------- ----------------------------------------------------------- COMMON NAME: $ BY WEIGHT: CAS NUMBER: RESPIRATORY PROTECTION: Not required. ---------------------------------------------------------- VENTILATION: Local exhaust. INGREDIENT 1 98% 7732-18-5 PROTECTIVE GLOVES: Rubber. Water EYE PROTECTION: Not required. EXPOSURE LIMIT(S) : Not established. OTHER PROTECTIVE EQUIPMENT: Not required. INGREDIENT 2 2% 1722-62-9 ---------------^----------------_---________--------------- Mepivacaine hydrochloride 9. PHYSICAL AND CHEMICAL PROPERTIES EXPOSURE LIMIT(S) : Not established. --------------------------------------------------------- EXPOSURE LIMIT(S) FOR THE MATERIAL: Not established. APPEARANCE/PHYSICAL STATE: Colorless solution. The MSDS for the active ingredient may be referred to for MOLECULAR WEIGHT: Mixture. additional information in handling the bulk product. SOLUBILITY IN WATER: Soluble. ----------------------------------------------------------- ----------------------------------------------------------- 3. HAZARDS IDENTIFICATION 10. STABILITY AND REACTIVITY ----------------------------------------------------------- ------------------------------------------—---------------- PRIMARY ROUTE(S) OF EXPOSURE: Skin contact, eye contact, STABILITY: Stable. inhalation, and ingestion. PHYSICAL CONDITIONS TO AVOID: Storage at elevated EFFECTS OF OVEREXPOSURE: Adverse reactions to Carbocaine temperatures. are generally dose related and due to high plasma levels INCOMPATIBILITY WITH OTHER MATERIALS: None. which may result from unintentional intravascular HAZARDOUS DECOMPOSITION PRODUCTS: None. injection or the local anesthetic solution. Reactions may HAZARDOUS POLYMERIZATION: Does not occur. include: restlessness, anxiety, dizziness, tinnitus, ------------ ------------------ blurred vision, or tremors. Other effects may be nausea, 11. TOXICOLOGICAL INFORMATION vomiting, chills and constriction of the pupils. ----------------------------------------------------------- Inadvertent intravaecular injection may lead to high ACUTE STUDIES: The following data applies to mepivacaine plasma levels and related depression of the myocardium, hydrochloride: decreased cardiac output heart block, hypotension, INTRAVENOUS LD50 (RAT): 30 mg/kg bradycardia, ventricular arrhythmias, and possibly ORAL LD50 (RAT) : >5 grams/kg cardiac arrest. SUBCUTANEOUS LD50 (RAT) : 500 mg/ml MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Hypersensitivity OTHER STUDIES: to any local anesthetic agent of the amide-type. CARCINOGENICITY: Ingredient(s) are not listed as -------------------------------- ------ carcinogenic by IARC, NTP or OSHA. 4. FIRST AID MEASURES ----------------------------------------------------------- 12. DISPOSAL CONSIDERATIONS EYES: Flush with water for 15 minutes. Hold eyelids open to --------------------------- -----------------'- assure complete contact with water. WASTE DISPOSAL METHOD: Dispose of by incineration in SKIN: Wash with soap and water. Remove contaminated accordance with applicable international, national, clothing. state, and/or local waste disposal regulations. INHALATION: Remove from exposure. ---__--- - INGESTION: Contact a physician or poison control center. 13. SHIPPING REGULATIONS ----------------------------------------------------------- 5. FIRE FIGHTING MEASURES Not regulated for transportation by the United States ----------------------------------------------------------- Department of Transportation (DOT), International FLASH POINT: Nonflammable. Maritime organization (IMO), or International Air LOWER EXPLOSION LIMIT (LEL): Not applicable. Transport Association (IATA) . May be subject to state UPPER EXPLOSION LIMIT (UEL) : Not applicable. and/or local transportation requirements. EXTINGUISHING MEDIA: Water, carbon dioxide, or dry -------------------------------------------------------- chemical. 14. OTHER INFORMATION FIRE-FIGHTING PROCEDURES: Wear self-contained breathing -- ------------------------ apparatus and full body protective equipment. REVIEWED BY: Health and Safety Regulatory Affairs UNUSUAL FIRE OR EXPLOSION HAZARDS: None known. DISCLAIMER: The MSDS information is believed to be correct HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide. Carbon but should only be used as a guide. The Upjohn Company dioxide. Nitrogen oxides. disclaims any express or implied warranty as to the accuracy of the MSDS information and shall not be held liable for any direct, incidental or consequential damages resulting from reliance on the information. 7/19/00------------------------------------------------------------------------------------------------------------------- MWI VETERINARY SUPPLY 6039619 NORTHWEST VET CLINIC/STANWOOD Page 1 of 2 L �� I -------------------• -- MATERIAL SAFETY DATA Sf )T ----------------------- Upjohn CARBOCAINE-V(R) HYDROCHLORIDE --------------------------------------------------------------------------------------------------------------------------- ----------------------------------------------------------- 15. LABELING ----------------------------------------------------------- This drug is subject to FDA labeling requirements; therefore, it is exempt from the labeling requirements of the OSHA Hazard Communication Standard. DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: although preparer and owner have taken reasonable care in the preparation of this document, we extend no warranties and make no representation as to the accuracy or completeness of the information contained herein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each user should make a determination as to the suitability of the information for their particular purpose(s). A request has been made to the manufacturer to approve the contents of this material safety data sheet. Upon receipt of any changes a new MSDS will be made available. ----------------------------------------------------------- COMPAS Code: 41SO0103 7/19/00------------------------------------------------------------------------------------------------------------------- MWI VETERINARY SUPPLY 6039619 NORTHWEST VET CLINIC/STANWOOD Page 2 of 2 1 '-� .. f - - - ---------- --------- - MATERIAL SAFETY DATA SHKL- -- - --------- - --- - -- --- - Evsco CARDOXIN --------------------------------------------------------------------------------------------------------------------------- IDENTITY (As Used on Label and List) : Cardoxin ----------------------------------------------------------- --------------------------------------------------------—- SECTION VI - HEALTH HAZARD DATA SECTIONI --------------------------------------------- -----------------------------------------------—---------- ROUTE(S) OF ENTRY: MANUFACTURER'S NAME: EVSCO PHARMACEUTICALS INHALATION? AFFILIATE OF IGI, INC. SKIN? PO BOX 209 (HARDING HWY) INGESTION? BUENA, NJ 08310 HEALTH HAZARDS (Acute and Chronic): Acute - Eye irritation, EMERGENCY TELEPHONE NUMBER: (609) 691-2411 abdominal pain, slowed heart rate. Chronic - possible TELEPHONE NUMBER FOR INFORMATION: (609) 691-2411 hypereensitization. DATE PREPARED: 11-10-88 CARCINOGENICITY: ----------------------------------------------------------- NTP? SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION IARC MONOGRAPHS? ----------------------------------------------------------- OSHA REGULATED? Hazardous Components SIGNS AND SYMPTOMS OF EXPOSURE: Same as above (Specific Chemical OSHA ACGIH $ MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Any Identity; Common Name(s)) PEL TLV (optional) cardiac related condition ----------------------------------------------------------- EMERGENCY AND FIRST AID PROCEDURES: The principal hazards involved with this product stem from EYES: Flush with plenty of water for at least 15 minutes. the presence of the following: Consult physician if irritation persists. Ethyl Alcohol 30$ IF INGESTED: Contact physician immediately Digoxin, USP 0.015% ----------------------------------------------------------- The information contained in this Material Safety Data SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Sheet has been compiled from information believed to be ----------------------------------------------------------- accurate and from our own experience. While we believe STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: that the data presented is factual, IGI, Inc. and its Soak up with absorbant material and place in closed affiliates make no warranty or representation, nor container for disposal. Take appropriate personal assumes any responsibility in conjunction with the use of protective measures to prevent exposure. this information. WASTE DISPOSAL METHOD: Dispose of waste in accordance with ----------------------------------------------------------- all applicable Federal, State and Local laws. SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Store in a ----------------------------------------------------------- secure area away from heat. BOILING POINT: OTHER PRECAUTIONS: VAPOR PRESSURE (mm Hg.) : --------------------------------------------------------- VAPOR DENSITY (AIR - 1) : SECTION VIII - CONTROL MEASURES SPECIFIC GRAVITY (H20 = 1): 1.06 ----------------------------------------------------------- MELTING POINT: RESPIRATORY PROTECTION (Specify Type) : Not required with EVAPORATION RATE (Butyl Acetate = 1): normal use. _ SOLUBILITY IN WATER: Soluble VENTILATION: APPEARANCE AND ODOR: Clear pink liquid having vanilla- LOCAL EXHAUST: Acceptable raspberry odor MECHANICAL (General) : Acceptable ----------------------------------------------------------- SPECIAL: SECTION IV - FIRE AND EXPLOSION HAZARD DATA OTHER: ----------------------------------------------------------- PROTECTIVE GLOVES: Not required with normal use. FLASH POINT (Method Used): Assumed to be flammable EYE PROTECTION: Not required with normal use. FLAMMABLE LIMITS: OTHER PROTECTIVE CLOTHING OR EQUIPMENT: LEL: WORK/HYGIENIC PRACTICES: UEL: ----------------------------------------------------------- EXTINGUISHING MEDIA: Alcohol foam, carbon dioxide or dry DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: Although chemical extinguisher reasonable care has been taken in the preparation of this SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained document, we extend no warranties and make no breathing apparatus. representation as to the accuracy or completeness of the UNUSUAL FIRE AND EXPLOSION HAZARDS: None known information contained therein, and assume no responsibility ----------------------------------------------------------- regarding the suitability of this information for the SECTION V - REACTIVITY DATA user's intended purposes or for the consequences of its ----------------------------------------------------------- use. Each individual should make a determination as to the STABILITY: Stable suitability of the information for their particular CONDITIONS TO AVOID: purpoee(e) . A request has been made to the manufacturer to INCOMPATIBILITY (Materials to Avoid): N/A approve the contents of this material safety data sheet. HAZARDOUS DECOMPOSITION OR BYPRODUCTS: N/A Upon receipt a new MSDS will be made available. HAZARDOUS POLYMERIZATION: Will Not Occur ----------------------------------------------------------- CONDITIONS TO AVOID: COMPAS Code: 13820030 NAC Approved Date: / / 1/19/98------------------------------------------------------------------------------------------------------------------- MWI VETERINARY SUPPLY 3780370 NORTHWEST VET CLINIC/STANWOOD Page 1 of 1 LO ,.06 -M7 - - - - - - - - - - - - --- - - - - - - - MATERIAL SAFETY DATA SHED_ - - -- - - - - - - - - - -- - - -- - --- 3M Health Care Group 1468 VETCAST PLUS VETERINARY CASTING TAPE -—---------------------—------------------------------------------------------------------------------------------------- 14-14 ----------------------------------------------------------- 29786 4. REACTIVITY DATA MANUFACTURER'S NAME: ANIMAL CARE PRODUCTS ----------------------------------------------------------- 3M HEALTH CARE GROUP STABILITY: Stable 3M CENTER INCOMPATIBILITY - MATERIALS TO AVOID: Strong Bases, Water. ST. PAUL, MINNESOTA SS144-1000 Avoid contact with alkaline materials and atmospheric 612/733-1110 moisture. DIVISION: Animal Care Products Project HAZARDOUS POLYMERIZATION: Will Not Occur TRADE NAME: 1468 Vetcast Plus Veterinary Casting Tape HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and 3M I.D. NUMBER/U.P.C.: 70-2005-8896-3 +H-44414-3783A-0 Carbon Dioxide, Oxides of Nitrogen 70-2005-8897-1 +H-44414-3793B-0 70-2005-8898-9 --------------—-------------------------------------------- +H-44414-38033-0 70-2005-8899-7 +H-44414-38134-0 5. ENVIRONMENTAL INFORMATION ISSUED: March 8, 1995 —---- ----------------------------------------- SUPERSEDES: May 31, 1993 SPILL RESPONSE: Not applicable. DOCUMENT: 11-6123-1 RECOMMENDED DISPOSAL: Incinerate uncured waste in an ----------------------------------------------------------- industrial or commercial incinerator. Dispose of waste 1. INGREDIENTS product in a facility permitted to accept chemical waste. ----------------------------------------------------------- Disposal alternative: Dispose of completely cured (or INGREDIENTS C.A.S. NO. PERCENT polymerized) material in a sanitary landfill. ---------------------------------------------------------- ENVIRONMENTAL DATA: No data available. Fibrous glass None 50.0 - 55.0 REGULATORY INFORMATION: Since regulations vary, consult Isocyanate terminated None 35.0 - 40.0 applicable regulations or authorities before disposal. urethane prepolymer BPCRA HAZARD CLASS: Modified 4-4' None 5.0 - 12.0 FIRE HAZARD: No diphenylmethane PRESSURE: No diisocyanate (MDI) REACTIVITY: No Lubricant None 0.5 - 5.0 ACUTE: No Amine catalyst None 0.1 - 2.0 CHRONIC: No Antioxidant None <0.5 ----------------------------------------------------------- Antifoam None <0.5 6. SUGGESTED FIRST AID Acid chloride None <0.5 ----------------------------------------------------------- ----- --------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of 2. PHYSICAL DATA water. Get immediate medical attention. ----------------------------------------------------------- SKIN CONTACT: Wash affected area with soap and water. BOILING POINT: N/A INHALATION: If eigne/symptoms occur, remove person to fresh VAPOR PRESSURE: N/A air. If eigne/symptoms continue, call a physician. VAPOR DENSITY: N/A IF SWALLOWED: Drink two glasses of water. Call a physician. EVAPORATION RATE: N/A --------------------------—------------------------------- SOLUBILITY IN WATER: Slight 7. PRECAUTIONARY INFORMATION SP. GRAVITY: N/A ----------------------------------------------------------- PERCENT VOLATILE: N/A EYE PROTECTION: Avoid eye contact. VOLATILE ORGANICS: N/A SKIN PROTECTION: Avoid prolonged skin contact with uncured VOC LESS H2O & EXEMPT SOLVENT: N/D product. pH: N/A VENTILATION PROTECTION: Use in a well-ventilated area. VISCOSITY: N/A RESPIRATORY PROTECTION: Not applicable. MELTING POINT: N/D PREVENTION OF ACCIDENTAL INGESTION: Wash hands after APPEARANCE AND ODOR: Yellowish resin impregnated on knit handling and before eating. Do not ingest. fiberglass, slight odor RECOMMENDED STORAGE: Keep container dry. Keep container ----------------------------------------------------- closed when not in use. 3. FIRE AND EXPLOSION HAZARD DATA FIRE AND EXPLOSION AVOIDANCE: Not applicable. ---------------------------------------------------------- ----------------------------------------------------------- FLASH POINT: <220.00 F PMCC EXPOSURE LIMITS FLAMMABLE LIMITS: INGREDIENTS VALUE UNIT TYPE AUTH SKIN* LEL: N/A ----------------------------------------------------------- UEL: N/A Fibroue glass None None None None AUTOIGNITION TEMPERATURE: N/A Isocyanate None None None None EXTINGUISHING MEDIA: Carbon dioxide, Dry chemical, Foam terminated SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective urethane clothing, including helmet, self-contained, positive prepolymer pressure or pressure demand breathing apparatus, bunker Modified 4-4' None None None None coat and pants, bands around arms, waist and loge, face diphenylmethane mask, and protective covering for exposed areas of the diisocyanate (MDI) head. Lubricant None None None None UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Amine catalyst None None None None Decomposition section for products of combustion. Antioxidant None None None None NFPA-HAZARD-CODES: Antifoam None None None None HEALTH: 2 Acid chloride None None None None FIRE: 0 REACTIVITY: 0 UNUSUAL REACTION HAZARD: None 10/24/97-------------------------------------------------------------------------------------------------------------------/ MWI VETERINARY SUPPLY 3594625 NORTHWEST VET CLINIC/STANWOOD Page 1 of -- - - - -- - - - -- -- - - - -- -- - MATERIAL SAFETY DATA SHEEN)- - - - - - - - - - - - - - - -- -- - --- 3M Health Care Group 1468 VETCAST PLUS VETERINARY CASTING TAPE --------------------------------------------------------------- - - - - --- --------------------------- * SKIN NOTATION: Listed substances indicated with "Y" under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - AIHA: American Industrial Hygiene Assoc. Workplace Environmental Exposure Level - NONE: None Established ----------------------------------------------------------- 8. HEALTH HAZARD DATA ----------------------------------------------------------- EYE CONTACT: Eye contact is not expected to occur during normal use of the product. MILD EYE IRRITATION: Signs/symptoms can include redness, swelling, pain, and tearing. SKIN CONTACT: ALLERGIC SKIN REACTION: Signs/eymptome can include redness, swelling, blistering, and itching. MILD SKIN IRRITATION: Signs/eymptome can include redness, swelling, and itching. INHALATION: No adverse health effects are expected from inhalation exposure. IF SWALLOWED: Ingestion is not a likely route of exposure to this product. ----------------------------------------------------------- SECTION CHANGE DATES --------------------------------------------------------- HEADING Section Changed Since May 31, 1993 Issue ABBREVIATIONS: N/D - Not Determined N/A - Not Applicable ----------------------------------------------------------- The information on this Data Sheet represents our current data and best opinion as to the proper use in handling of this material under normal conditions. Any use of the material which is not in conformance with this Data Sheet or which involves using the material in combination with any other material or any other process is the responsibility of the user. ----------------------------------------------------------- DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representation as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose(s). A request has been made to the manufacturer to approve the contents of this material safety data sheet. Upon receipt a new MSDS will be made available. COMPAS Code: 93800101 NAC Approved Date: / / MWI VETERINARY SUPPLY 3594625 NORTHWEST VET CLINIC/STANWOOD Page 2 of 2 F-58 American Veterinary Distributors Association SECTION IV-FIRE&EXPLOSION DATA Auto-49nitlon Temperature:WA C@fa-Drops Flesh Point:N/A; Method Used:N/A Extinguisher Media:CO,,Dry Chemical,Foam,Water,Water Flammable Limits In Air(%by Volume):Let-N/A:Uel-N/A Spray. Continued Auto-Ignition Temperature: N/A Special Fire Fighting Procedures: None Extinguisher Media:CO,,Dry Chemical,Foam,Water,Water Unusual Fire and Explosion Hazards: None Mist. SECTION V-PHYSICAL HAZARDS(REACTIVITY DATA) Reactivity In Water: N/A Special Fire Fighting Procoduros: Mono Stability: Stable Appearance: While powder Unusual Fire and Explosion Hazards: None Conditions to Avoid: None known Melting Point: Not known SECTION V-PHYSICAL HAZARDS(REACTIVITY DATA) Incompatibility(Materials to Avoid): None known SECTION/V-FIRE 8 EXPLOSION DATA Stability: Stable Hazardous Decomposition Products: None known Flesh Point:N/A; Method Used:WA Conditions to Avoid: None known Hazardous Polymerization: WIII not occur. Flammable Limits In Alr(%by Volume):Let-N/A;Uel-N/A Incompatibility(Materials to Avoid): None known Conditions to Avoid: None known Auto-Ignition Temperature:WA Hazardous Decomposition Products: None known SECTION VI-HEALTH HAZARDS Extinguisher Media:CO,Dry Chemical,Water,Water Spray. Hazardous Polymerization: Will not occur. Acute: None;Chronic:None Special Fire Fighting Procedures: None Conditions to Avoid: None known Signs and Symptoms of Exposure: None-product is non- Unusual Fire and Explosion Hazards: None SECTION VI-HEALTH HAZARDS toxic.Cefadroxil Is a bactericidal agent that causes death of SECTION V-PHYSICAL HAZARDS REACTIVITY DATA bacterial cells through a diversity of biological and biochemical ( ) Acute: None;Chronic:None Stability: Stable effects on the cell wells. ty: Signs and Symptoms of Exposure: None-product Is non- Medical Conditions Generally Aggravated by Exposure: Conditions to Avoid: None known toxic Inlramammary infusion anliobiotic for use In wet cows. None Incompatibility(Materials to Avoid): None known Medical Conditions Generally Aggravated by Exposure: Chemical Listed as Carcinogen or Potential Carcinogen:No Hazardous Polymerization: WIII not occur. None Chemical Listed as Carcinogen or Potential Carcinogen:No Emergency and First Procedures: Eyes:Flush with Conditions to Avoid: None known excess water. Skin:Wash with soap and water. Ingestion: SECTION VI-HEALTH HAZARDS Emergency and First Aid Procedures: Eyes:Flush with Contact a physician. excess water. Skin:Wash with soap and water. Ingestion: Route(s)a ( )s of Entry: Sl9ns and Symptoms of Exposure: None.product is non- Rout*tact a of Entry: Inhalation: N/A;Eyes: Mild-flush with water; Skin: Mild- toxic. wash with soap and water; Ingestion:Contact a physician. Inhalation:N/A;Eyes:Moderate.flush with water;Skin:Mild SECTION VII-SPECIAL PRECAUTIONS AND SPILL/LEAK Medical Conditions Generally Aggravated by Exposure: -wash with soap and water; Ingestion: Contact a physician. PROCEDURES None SECTION VII.SPECIAL PRECAUTIONS AND SPILL/LEAK Chemical Listed as Carcinogen or Potential Carcinogen:No PROCEDURES Precautions to be Taken In Handling and Storage;Not to be Emergency and First Aid Procedures: Eyes:Flush with Precautions to be Taken In Handling and Storage:Store at used in animals which are raised for food production. Other Precautions:Keep out of reach of children.Federal law excess water. Skin:Wash with soap and water. Ingestion: room temperature(590 660F).Avoid excessive heat.For use in restricts this drug to use by or on the order of a licensed Contact a physician. lactating cows only. of Ent veterinarian. Routes ( ) Entry: Other Precautions:Keep cut of reach of children.Federal law Steps to be Taken In Case Material Is Released or Spilled: Inhalation:WA;Eyes:Moderate-flush with water;Skin:Mild restricts this drug to use by or on the order of a licensed Collect and place in suitable container for future disposal. -wash with soap and water;Ingestion:Contact a physician veterinarian. Wash contaminated surfaces and flush to drain. SECTION VII-SPECIAL PRECAUTIONS AND SPILULEAK Steps to be Taken in Case Material Is Released or Spilled: Waste Disposal Methods: Incinerate In accordance with PROCEDURES Collect and place In suitable container for future disposal. local,state and toderal rogulations. Precautlona to be Taken In Handling and Storage: For use Wash contaminated surfaces and flush to drain. SECTION Vill - SPECIAL PROTECTION INFORMATION/ in dogs and cats only. Not to be used In animals raised for food Waste Disposal Methods: Incinerate in accordance with CONTROL MEASURES production.Shake well belore using. local,slate and lederal regulations. Other Precautions:Keep out of reach of children.Federal law SECTION VI11 - SPECIAL PROTECTION INFORMATION/ Respiratory Protection: Not needed.. restricts this drug to use by or on the order of a licensed CONTROL MEASURES Ventilation:Local exhaust and mechanical. veterinarian. Respiratory Protection: Not needed. Protective Gloves: Recommended-latex or rubber. Steps to be Taken In Case Material Is Released or Spilled: Ventilation:Local exhaust and mechanical. Eye Protection: Recommended-safety glasses Collect and place in suitable container for future disposal. protective Gloves: Recommended-latex or rubber. Other Protective Clothing or Equipment: None Wash contaminated surfaces end(lush to drain. Work/Hygienic Practices: Follow label directions-see pack- ack- Waste Disposal Methods: Incinerate in accordance with Eye Protection: Recommended-safety glasses age Insert local,state and federal regulations. Other Protective Clothing or Equipment: None g SECTION Vlll - SPECIAL PROTECTION INFORMATION/ Work/Hygienic Practices: Follow label directions-see pack- CONTROL MEASURES age Insert Respiratory Protection: Not needed. CENTRINE INJECTION&TABLETS Ventilation:Local exhaust and mechanical. AVDA MSDS No.:MS1133 Protective Gloves: Recommended.latex or rubber. CEFA-TAB$® AVDA MSDS No.:MS1132 Fort Dodge Laboratories,Inc.,P.O.Box 518,8005th St.N.W., Eye Protection: Recommended-safety glasses. Fort Dodge,IA 50501.Emergency telephone:515.955-4600. Work/Hygienic lenlc Practices: Follow label directions-see pack- Fort Dodge Laboratories,Inc.,P.O.Box 518,80051h St.N.W., Dale of MSDS: July 7,1966 Y9 P Fort Dodge,IA 50501.Emergency telephone:515-955 4600.age insert. SECTION I-IDENTIFICATION Date of MSDS: July 7,1988 product Name: Centrine Injection&Tablets SECTION 1•IDENTIFICATION SECTION If-HAZARDOUS INGREDIENTS Product Name: CEFA-TABSs Aminopentamide Hydrogen Sulfate-10ml Vials Veterinary CEFA-LAK!TODAY AVDA MSDS No.:MS1130 SECTION II-HAZARDOUS INGREDIENTS Injection 0.5mg/mL Fort Dodge Laboratories,Inc.,P.O.Box 518,80051h St.N.W., Cefadroxil-equivalent to 50mg celadroxil per tablet Tablets 0.2mg Veterinary tablet Fort Dodge,IA 50501.Emergency telephone:515-955-4600. 50mg/tablel(for use In dogs and cats only) Date of MSDS: July 7,1988 Cefadroxil-equivalent to 100 mg cefadroxll per tablet Centrine is a potent antispasmodic agent. As a chollnergic SECTION I-IDENTIFICATION 100mg/tablet(use In dogs and cats only) blocking agent for smooth muscle, It's action Is similar to atropine. Product Name: CEFA-LAK°/Today Celadroxll-equlvallent l0 200mg celadroxil per tablet SECTION Ill-PHYSICAL 8 CHEMICAL CHARACTERISTICS SECTION ll-HAZARDOUS INGREDIENTS 200mg/tablet(use in dogs only) Boiling Point: N/A Cefadroxil-equivalent to 1000mg(1 Gm)cefadroxll per tablet Each 10ml disposable syringe contains 200mg of cephapirin 1000mg/tabiet(use in dogs only) Specific Gravity(H20-1): WA activity in a stable oil gel. Cefa-Lak(cephaplrin sodium)for In tramammary infusion Into the wet cow provides wide range of SECTION 111-PHYSICAL 8 CHEMICAL CHARACTERISTICS Vapor Pressure(mm Hg): N/A bactericidal activity against gram-positive and Gram-negative Boiling Point: N/A Vapor Density(AIR-1): WA organisms. For lactating cows only for the treatment of Bovine Specific Gravity(H2O=1): N/A Solublllly In Water: N/A Mastills. Vapor Pressure(mm Hg): N/A Reactivity In Water: WA SECTION Ill-PHYSICAL&CHEMICAL CHARACTERISTICS Vapor Density(AIR=1): N/A Appearance and Odor: Tablets and Injection Bolling Point: N/A Specific Gravity(H2O=1): 0.922 Solubility In Water: WA Malting Point: N/A Vapor Pressure(H, .1): .92N/A Reactivity In Water: N/A SECTION IV-FIRE&EXPLOSION DATA Appearance and Odor: 50mg green tablet;100 mg black Flesh Point:N/A; Method Used:WA Vapor Density(AIR-1): N/A tablet;200mg green tablet Flammable Limits In Air(%by Volume):Lei-WA;U&I-WA Solubility In Water: WA Melting Point: WA Auto-ignition Temperature:N/A Reactivity In Water: NIA SECTION IV-FIRE 8 EXPLOSION DATA Extinguisher Media:CO,,dry chemical,loam,water,water Appearance and Odor: White suspension Flash Point:N/A; Method Used:N/A spray. Melting Point: N/A Flammable Limits In Air(%by Volume):Let-N/A;Uel-N/A Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None 1 I I American Veterinary Distributors Association U - 11 Synonyms:Cheque;EDP Number:247050;Mibolerone;U- Flammable Limits: Lei-2.6%; Uel-12.5% Molecular Formula:C24-H45-N-08 10,997 Extinguishing Media:Water,alcohol loam,carbon dioxide or Chemical Name:7-[3 Alpha,5 Alpha-Dihydroxy-2 Bela-[(3S)- Molecular Formula:C20-1-130-02 dry chemical 3-Hydroxy-trans•l-oclenylj•1 Alpha-CyclopentylJ-CIS-5-Hep- Chemlcal Famlly:�AnJrogen Special Fire Fighting Procedures: Wear sell contained lenoic Acid Compound with 2•Amino-2-(Hydroxymethyl)-1,3- SECTION I/-PHYSICAL DATA breathing apparatus and protective clothing to prevent contact Propanediol Appearance:Crystalline with skin and eyes Chemical Family:Proslaglandin SECTION 111-FIRE AND EXPLOSION DATA Unusual Fire and Explosion Hazards: Thermal decomposi- SECTION/I-PHYSICAL DATA lion may yield carbon monoxide and other toxic substances Appearance:White or off-white crystalline powder Flash Point:N/A SECTION V-REACTIVITY Melting Point:I00°C(approx.) Method:WA Stability: Stable Flammable Limits: Lei WA; Uel N/A Odor:Odorless Conditions to Avoid: None Solubility In Water:Soluble Extinguishing Media:Water,carbon dioxide or chemical Incompatibility: None Vapor Density: WA Special Fire Fighting Procedures:None Hazardous Decomposition Product:Toxic substances may Vapor Pressure:WA Unusual Fire and Explosion Hazards:None be released when product is subjected to intense heal or fire SECTION III-FIRE AND EXPLOSION DATA SECTION IV-REACTIVITY conditions. Does not decompose Stability:Stable Hazardous Polymerization: Spontaneously will not occur Flash Point:N/A Conditions to Avoid:None SECTION VI-HEALTH HAZARD Method:N/A Incompatibility:None Effects of Overexposure: Adverse effects to persons han- Flammable Limits: Let WA; Uel N/A ty• dling this material in a clinical setting are not anticipated. Extinguishing Media:Water,carbon dioxide or chemical Hazardous Polymerization:Will not occur Overexposure could lead to nausea edema and adverse repro- Special Fire Fighting Procedures:None SECTION V-HEALTH HAZARD ductive ellects. One study in humans indicated potential al- Unusual Fire and Explosion Hazards:None Permissible Exposure Limit:Not established(29 CFR 1910). tered-liver function. Ocular exposure may cause irritation Threshold Limit Value:Not estaolished(ACGIH,1984-85). Toxicity: Mibolerone has been shown to be an anabolic and SECTION IV-REACTIVITY Upjohn Exposure Guideline:Not established(1985). androgenic steroid in rats. When compared to melhyltestoster- Stability:Stable one,it is 41 limes more potent as an anabolic agent and 16 Incompatibility:None Effects of Overexposure: limes more potent as an androgen. Mibolerone has no estro- Male: Inhibition of testicular function;nausea;edema. genic activity in mice when used at levels up to 1.0 mg per Hazardous Decomposition Products:None Female: Masculinization;nausea;edema animal per day. It is antiestrogenic in mice in intravaginal tests Conditions to Avoid:None at 0.9 mcg and in subcutaneous tests at 10 mcg or less when Hazardous Polymerization:WIII not occur Medical Conditions Aggravated by Exposure:Not estab- tested against estradiol.The acute oral LD50 in the rat is greater SECTION V-HEALTH HAZARD lished than 1,600,000 mcg/kg while the intraperitoneal LD50 in the SECTION VI-FIRST AID mouse is 555,600 mcg/kg Mibolerone has been well tolerated Permissible Exposure Limit:Not established(29 CFR 1910). Emergency and First Aid Procedures:No specific antidote in rats at levels of 3,000 or 10,000 or 30,000 mcg/kg orally for up Threshold Limit Value:Not established(ACGIH,1984.85). exists. Remove further exposure. to 28 days. Changes observed included hypertrophy of the Upjohn Exposure Guideline:1 UG/M3(1982). myometrium,reduction of the amount of stainable lipid in all SECTION VII-SPILL,LEAKAND DISPOSAL PROCEDURES three zones of the adrenal cortices.arrest of spermatogenesis Effects of Overexposure:Stimulates smooth muscle contrac- Sleps to be Taken In Case Material is Released or Spilled: and atrophy of the accessory sex gland of male rats at 3,000 and tion:causes extreme eye irritation. May cause intense bron- Sweep or vacuum up spillage. Wash down area with water. 10,000 mcg/kg. Treated animals ate less than the controls and chospasm,particularly in asthmatic patients,gastrointestinal Waste Disposal Method:Incineration required more food per unit of body weight gain. Mibolerone disturbances,increased bone lormalion and adverse reproduc- SECTION VIII-SPECIAL HANDLING was nonmutagenic in Ames assay. live effects. May cause skin irritation. Carcinogenicity:Not carcinogenic. Toxicity:Oral LD50:665 mg/kg.Intraperiloneal LD50:101 mot Respiratory Protection:Approved dust respirator;air-sup- k9. plied hood if needed. Medical Conditions Aggravated by Exposure: Not eslab- Medical Conditions Aggravated b Exposure:H rsensi- lished 99 Y Po Ype Ventilation:Local exhaust: preferable. Mechanical: accept- SECTION VI/.FIRST AID tivity to Dinoprosl Tromethamine. able SECTION VI-FIRST AID Protective Gloves:Plastic or rubber Emergency and First Aid Procedures: Eyes:Flush with water for 15 minutes.Skin:Wash with soap Emergency and First Aid Procedures: Eye Protection:Safety glasses and water;Inhalation:Remove from exposure;Ingestion:Con- Eyes:Flush with water for 15 minutes.Skin:Wash with soap SECTION IX-SPECIAL PRECAUTIONS tact a physician or poison control center. and water to remove all traces of compound.Inhalation:Re- Precautions to be Taken In Handling and Storing:Danger: SECTION Vlll-SPILL,LEAKAND DISPOSAL PROCEDURES move patient to fresh air;call a physician. Ingestion:Call a harmful if swallowed, inhaled or absorbed through the skin. physician. Pregnant females should avoid exposure. Steps to be Taken In Case Materiel Is Released or Spilled: Notes to Physician: The time of onset and duration of symp- Vacuum spilled material and place in container toms resulting from accidental overexposure has not been Waste Disposal Method: Dispose of in accordance with determined, but Is expected to be relatively rapid.The half-life Local,State,and Federal regulations. of prostaglandin F2 alpha itself is thought to be no more than a CHEQUE DROPS AVDA MSDS No.:MS1803 SECTION/X-SPECIAL HANDLING few minutes although effects of overexposure may fast consid- Respiratory Protection: For large spills:approved respirator erably longer If untreated.The action of prostaglandin F2 alpha Upjohn Company,7171 Portage Rd.,Kalamazoo,MI 49001. on smooth muscle may cause abortion,bronchospasm, in- Emergency Phone:616-323-7555(8:00am-4:30pm);616-323- Ventilation: For large spills:Local exhaust creased heart rate,diarrhea and vomiting.Chronic overexpo- 6722(24 hours). Protective Gloves: For large spills: rubber sure may lead to proliferation of bone.Prostaglandins as a class Date of MSDS:September,19,1989 Eye Protection: For large spills:chemical goggles may be leratogenic. There is no known antidote for SECTION I-MATERIAL IDENTIFICATION SECTION X-SPECIAL PRECAUTIONS prostaglandin F2 alpha. Lulalyse is packaged In 10 ml and 30 ml vials. Common Name: Cheque Drops Precautions to be Taken In Handling and Storing:DANGER: SECTION VII•SPILL,LEAK AND DISPOSAL PROCEDURES Upjohn ID Number: P-000014-58-6 Harmful if swallowed,inhaled or absorbed through the skin. Slope to be Taken In Case Material Is Released or Spilled: Molecular Formula: Mixture Keep out of reach of children. Wash thoroughly after handling. Pregnant females should avoid exposure.Not for human use. Vacuum or sweep up spillage(avoid contact)and neutralize Chemical Family: Androgen CAUTION:Federal(U.S.A)law restricts this drug to use by or on area with 1:1 bleach and water. Chemical Name: Cheque(Mibolerone) Drops are 17-Bela- the order of a licensed veterinarian. Waste Disposal Method:Incinerate or sanitary landfill. hydroxy-7alpha•17-dimelhyl-estr•4•en-3•one, generic name The above precautions apply to handling large quantities or SECTION Vlll-SPECIAL HANDLING mibolerone, a non-progestalional steroid. In its pure form, spills of cheque drops.For precautions specific to the active Respiratory Protection:Approved respirator or air hood. mibolerone is a white crystalline solid. ingredient,consult the material safety data sheet for mibol- SECTION I/-INGREDIENTS erone. Cloe Local: recommended. Mechanical: acceptable. Other:Other: r no recirculation of exhaust air. Materials CAS No. % Notes Protective Gloves:Plastic or rubber(disposable). Propylene glycol 000057-55-6 >99 UEG,PEL,TLV:No[ established D/NOPROST TROMETHAM/NE Eye Protection:Chemical goggles. Mibolerone 003704.09.4 Not provided Conc.: AVDA MSDS No.:MS2496 Other Protective Equipment: Tyvsk coveralls, booties, shower at the end of the day. 100mcg/mg; Upjohn Company,7171 Portage Rd,Kalamazoo,MI 49001 UEG,TLV,PEL:Not established Emergency Telephone: 616.323.7555(8:00 AM-4:30 PM) SECTION IX-SPECIAL PRECAUTIONS SECTION Ill-PHYSICAL DATA 616-323-6722(24 HOURS) Precautions to be Taken In Handling and Storing:Pregnant Appearance: Liquid in 55 ml bottles with graduated dropper Dale of MSDS:October 8,1985 females should avoid exposure to this compound. Boiling Point: 88 C(propylene glycol) SECTION I.MATERIAL IDENTIFICATION Solubility In Water: Complete(Propylene Glycol) Common Name:Dinoprost Tromethamine Specific Gravity: 1.038 at 20C(Propylene Glycol) CAS Number:038562-01-5 Vapor Density: 2.62(air=1)(Propylene Glycol) Synonyms: Vapor Pressure: 0.22 mmhg at 20C(Propylene Glycol) EDP Number:224279,Lutaiyse Volatility: N/A(Propylene Glycol) PGF2.Alpha.Them SECTION/V-FIRE AND EXPLOSION DATA Prostaglandin F2 Alpha Tromethamine Flesh Point: 103 C(Propylene Glycol) Prostaglandin F2A Tris Cell Culture Tested Method: PM Proslln F2 Alpha U-14,583E .+ I A-62 American Veterinary Distributors Association Solubility In Oil: Mostly soluble. Hygienic Practices: Wash thoroughly after handling. Use Boric Acid Ointment(and/or Boric Acid Solubility Other: N/I normal hygiene to protect hands,eyes and skin. Use general Ophthalmic) C011fl/IUBd ventilation to protect your lungs. Do not wear contaminated P clothing until thoroughly laundered. When Material Is Released or Spilled: Assure slippery Chronic Effects: Not indicated(N/1). CHLORAMPHENICOL 1% STERILE conditions are nullfled.Add sand or dirt.Scoop up and remove. Medical Conditions Potentially Aggravated by: Skin dla- Dispose In accordance with federal,slate and local regulations. eases. METERINARYOPHTHALMIODINTMENT West.Disposal Methods:Assure conformity with applicable SECTION VII-REACTIVITY DATA CHLORAMPHENICAL-PREDNISOLONE disposal regulations.Dispose of absorbed materiel at approved incineration or chemical landfill waste disposal site.. Product Is: stable ACETATE STERILE VETERINARY SECTION IX-SPECIAL PROTECTION INFORMATION Chemicals and Conions to Avoid:Oxidizers,strong acids OPHTHALMIC OINTMENT Skin Protection: Normal hygiene. and alkalies.Sourcesroes of of extreme heat and flame. Hazardous Polymerization: Will not occur. AVDA MSDS No.:MS540 Eye Protection: Normal hygiene. Hazardous Decomposition: Oxidizers,strong acids and Aliens, Inc., BYK Pharmaceutical Group, 60 Baylls Road, Other Protective Clothing or Equipment:As needed to bases. Sources of extreme heat and flame. Melville,NY 11747.Emergency Telephones:Buslness Hours: prevent repeated/prolonged contact. SECTION Vlll-SPILL,LEAK AND WASTE DISPOSAL PRO- (516)464-7677;Other Hours:(516)454-7692;TELEX 144662. SECTION X-CONTAINERS AND LABELING CEDURES Date of MSDS: January 17,1989 Special Precautions:Keep container closed. Store away Report major leaks and spills to the appropriate local,state SECTION I-PRODUCT IDENTIFICATION from oxidizers and sources of heal and flame. and/or federal governmental agency. Common Name: Chloramphenicol 1% Sterile Veterinary Recommended Containers: As supplied(not sold in bulk Precautionary Measures: Use proper hygiene.Wear safely Oplhalmic Ointment;Chloramphenical-Prednisolone Acetate quantity). glasses. Use absorbent material. Flush area with water to Sterile Veterinary Ophthalmic Ointment. Protect the container by: Avoiding physical damage and eliminate slippery conditions.Stop spill at source if possible. CAS Number: N/A heat. Pickup& Removal: Scoop up and remove. Place In a Synonyms: N/A Container should be handled In an area with: Adequate Su�tablo Conlainor. Flush area with water. general ventilation. Formula: See package insert. Incineration: Yes Dispersal to water: No The Empty Container Is: Not reusable. Oc ean dumping: No Legooning: No Chemical Family:Veterinary Ophthalmic Ointment Precautionary Label: For velerinary use only. Federal law Sanitary Landfill: No Chemical Landfill: Yes SECTION II-SAFETYAND HAZARD RATINGS restricts this drug to use by or on the order of a licensed Deep Well Subsurlaco: No Open Disposal: No Health(Acute-Chronic):1-3 veterinarian. Undetermined Disposal: WA Priority Pollutant: WA Neutralization: No Flammability: 0 Waming Placard: Keep out of reach of children. Not for use SECT/OIN/X-PERSONAL PROTECTION d HYGIENE IN- Environment(Air-Water-Soil):2-2.1 In animals which are raised for food production. FORMATION Reactivity: 0 Contralndleatlons:Chloramphenicol products must not be used In meal,egg or milk•producing animals.The lenglh of time Personal hygiene practices must Include: Washing daily Special Hazards:None that residues persist in milk or tissues has not been determined. Protect your eyes with: Normal hygiene Protective Equipment: General ventilation,eye and hand IMO Hazard Ciao":Not applicable. UWNAN:Not applicable Protect your hands by: Normal hygiene wash. Hazard Classification: N/A Protect your akin by using: Normal hygiene SECTION Ill-EMERGENCYAND FIRST AID PROCEDURES DOT Name: N/A Protect your breathing by using: General ventilation Eyes: Flush with copious amounts of water for at least 15 minutes. Shipping Instructions:Keep away from oxidizers,bases and X-CONTAINERS AND LABELING sources of heat. Skin:Wash with soap and water. (a)Storage and Containers: SECTION XI-ENVIRONMENTAL RISKS Recommended Containere: As supplied not sold In bulk ingestion:Induce van unp If large quantities are ingested.Do Aquatic Toxicity: Not Indicated(WI) PP ( not give anything to an unconscious person. quantity). Call a physician.Contact a Poison Control Center. Biodegradability: N/I Protect the container by: Avoiding physical damage and SECTION IV-HAZARDOUS INGREDIENTS Partition Coefficient: N/I heat.Container should be handled In an area with: Cool,dry Chloramphenicol-CAS No.:56.75.7-1.25%. Carcinogen: SECTION XII-REGULATORY REFERENCES conditions. IARC-yes;NTP-No.;OSHA-No. ACGIH TLV and OSHA PEL- Refer to the following references: Not determined. OSHA Regulations: Not applicable The Empty onaryConta nor Is: Not reusable. SECTION V-FIRE AND EXPLOSION HAZARDS DOT Regulations: WA (b)Precautionary La Label Extinguishing Media:As needed for surrounding materials. Precautionary Label: No g g 9 EPA Regulations: N/A Warning Placard: No Flash Point IF(and method): Nol determined Other: NOC 0462.0093-38 IMO Hazard Clan":WA UN/N/A C N/A Flammability Limits In Air(Percent by Volume): SECTION XII-PHYSICAL DATA Hazard Classification: WA Lower:Not determined; Upper: Not determined. Appearance and Odor: Pale yellow ointment that is essen- DOT Name: WA Autoignlllon will occur at: Not determined. Bally odorless. Shipping Instructions:Kee awe from extreme heal end Special Firefighting Procedures: Use self-contained Molecular Weight: Not applicable pp g p y breathing apparatus and protective clothing. pH:Not'determined oxidants. Unusual Fire&Explosion Hazards: Toxic fumes of carbon P Refractive Index 20°C: Not applicable SECTION XI-ENVIRONMENTAL RISKS monoxide,carbon dioxide,nitrogen oxides and hydrogen chlo- Viscosity CPS @ 25°C:Not determined. Aquatic Toxicity: WI ride gas may be released. Biodegradability: N/I SECTION VI-REACTIVITY DATA(PHYSICAL HAZARDS) Bolling Point: Fahrenheit:-437;Celsius:-225 Partition Coefficient: WI Stability: Stable Melting Point: Fahrenheit-104;Celsius:-40 SECTION X11-REGULATORY REFERENCES Incompatibility(Materials to Avoid):Extreme heat,sparks, Congealing Point:Not determined Refer to the following references: open flame,and strong oxidizers. Vapor Pressure(mm Hg.):Not determined OSHA Regulations: If respirator used 29 CFR 1910.134 Hazardous Decomposition Products: Unlikely Vapor Density(Air-1): Not determined DOT Regulations: N/A Hazardous Polymerization:Should not occur. Solubility In Water: Partially soluble EPA Regulations: WA SECTION Vll-HEALTH HAZARDS Solubility In Alcohol: Not determined Other: 21 CFR 330.5 Primary Routes)of Entry: Dermal Solubility In Oil: Mostly soluble SECTION XIII-PHYSICAL DATA Signs and Symptoms of Exposure: Solubility In Other:Not determined Odor: Odorless Appearance: Ointment Overexposure Effects: May cause local irritation,slinging or Specific Gravity(Hr0-1): Chloramphenicol-0.86 Color: White Molecular Weight: WA burning. Chloramphenicol-Prednisolone Acetate-0.69. pH;WI Chronic Effects:May cause allergic reactions in susceptible %Volatile by Volume: 0.1% Specific Gravity at 20°C:0.89®60 deg C. Individuals. May suppress Individuals response and thus In- Evaporation Rate: Hydroscopic Refractive Index 20°C: WI crease the hazard of a secondary ocular Infection. Chloram- phenlcol Is a suspected human carcinogen(IARC). Viscosity CPS®25°C:N/I Inhalation: Not likely due to the physical state of the product. EFOD/NE AVDA MSDS No.:MS27 Freezing/Molling Point: Eyes: Possible eye irritation. Fahrenheit: 104 Celsius: 58 Altana, Inc., BYK Pharmaceutical Group, 80 Baylis Road, Ingestion: May cause nausea,vomiting and indigestion, Nelvllle, NY 11747. Emergency Phones: Business Hours: Boiling Point: Fahrenheit:320;Celsius:160 Skin: May cause slight skin irritation and poor wound healing. (516)454.7677:Other Hours:(516)464-7692;TELEX 144662. Congealing Point:Fahrenheit:WI;Celsius:N/I Medical Conditions Potentially Aggravated by:Susceptible Date of Preparation/Change:January 28,1986 Vapor Pressure(mm Hg.): WI Individuals may have an allergic reaction. SECTION I-PRODUCT IDENTIFICATION Vapor Density(Air.1): WI SECTION Vlll-SPECIAL PRECAUTIONS AND SPILULEAK Common Name:Efodine Percent Volatile: 0 PROCEDURES CAS Number:WA Evaporation Rate: 0(Ether reference) Precautions to be Taken In Handling/Storage:Keep con- Synonym*:WA tainers closed when not in use. Do not handle or store near Formula:90%Polyethylene Glycol,10%Povidone Iodine Solubility In Water: Insoluble heat,flame or oxidizers. Chemical Family:Hydroxylpolyelher with Halogenated Poly- Solubility In Alcohol: Practically Insoluble mer Complex i �, ti 1 SmithKline Beecham MSDS NUMBER: 10000255 PAGE: 1 MATERIAL. SAFETY DATA SHEET 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING SUBSTANCE: CZMETIDINE HYDROCHLORIDE ` TRADENAMES/SYNONYMS: N' ' -CYANO-N-METHYL-N' - II(5-METHYL-IH-IMIDAZOL-4-YL)METHYL]THIO]ETHYL-G UANIDINE, MONOHYDROCHLORIDE 2-CYANO-I-METHYL-3- [2- I I(5-METHYLIM:1DAZOL-4-YL) -MET=]THIO]ETHYL] -GUA NIDINEMONOHYDROCHLORIDE * TAGAMET * CET 7 * STOCK NUMBER 22185 SK&F 92334-A * SKF-92334-A CHEMICAL FAMILY: Substituted imidazole MOLECULAR FORMULA: C10-H16-N6-S . H-Cl MOLECULAR WEIGHT: 288.80 EINECS NUMBER: NOT ASSIGNED ELINCS NUMBER: NOT ASSIGNED COMPANY: SMITHKLINE BEECHAM CORPORATION CORPORATE ENVIRONMENTAL HEALTH AND SAFETY 709 SWEDELAND ROAD KING OF PRUSSIA, PA 19406 PHONE: (215)270-7807 2-COMPOSITION/INFORMATION ON INGREDIENTS i INGREDIENTS CAS REGISTRY NO pERCM]T CIMETIDINE HYDROCHLORIDE 70059-30-2 98 CONTAMINANTS: SK&F 9240E-A2, SK&F 92422-A, SK&F 92452 3. HAZARDS IDENTIFICATION PRnQRY ROUTES OF EXPOSURE: � Avoid breathing dust, skin contact, eye contact, ingestion. SKIN CONTACT: Irritation can occur following direct contact to skin that is intact or has cuts or abrasions. Allergic skin reaction can occur following direct contact with this material. Symptoms such as itching, redness, or swelling might be immediate or delayed. EYE CONTACT: Irritation can occur following direct contact with this material. Symptoms might include redness or swelling. INHALATION: Allergic reaction can Occur following repeated contact. Symptoms might include running nose, sneezing, itching, pulmonary obstruction, or signs similar to asthma such as coughing, wheezing or difficulty breathing. INGESTION: Toxicity following ingestion is not expected. However, ingestion should be avoided. DATE APPROVED: 03 January 91 DATE REVISED: 28 July 93 �. tlt I I I I MSDS NUMBER: 10000255 MATER PAGE: 2 IAL SAFETY DATA SHEET CONDITIONS AGGRAVATED BY EXPOSURE: Exposure to this material might alter the effectiveness of other pharmaceuticals. In cases of exposure., a physician should consider whether dose levels of prescribed drugs should be adjusted. 4. FIRST-AID MEASURES SKIN CONTACT: Remove contaminated clothing and wash exposed area with copious amounts of soap and water. Obtain medical. assistance if skin reaction occurs, which may be immediate or delayed. NOTE TO PHYSICIAN: None. EYE CONTACT: Wash eyes with water for at least 15 minutes then obtain medical assistance. NOTE TO PHYSICIAN: None. INH_Ar•ATI ON: Move exposed subject to fresh air. In case of known or possible over exposure, refer to a physician. If breathing has stopped, institute basic life support and seek immediate medical attention. Observe for chest pain, difficulty breathing, loss of consciousness or other adverse effects which may be delayed. NOTE TO PHYSICIAN: For combustion products, refer to section number S. INGESTION: In the event of swallowing this material, treat subject supportively and symptomatically. Seek immediate medical attention. NOTE TO PHYSICIAN: Medical treatment in cases of over exposure should be treated as an overdosage of Tagamet. Refer to the most recent edition of the Physicians Desk Reference. ANTIDOTES: None known. S.FIAE-FIGHTING MEASURES FIRE CONTROL: Toxic or corrosive gases are expected from fires involving this material. Use water, carbon dioxide, foam or dry chemical extinguishers. SPECIAL FIREFIGHTING PROCEDURES: Toxic or corrosive gases including oxides of carbon, nitrogen, sulfur together with chlorine and hydrogen chloride are expected in fires involving this material. Self contained breathing apparatus and full protective equipment are recommended for firefighters. Move containers from fire area if possible without increased personal risk. Dike area if possible to contain water for later disposal. 6. ACCIDENTAL RELEASE MEASURES SPILLS: Remove or shut off all sources of ignition. Instruct all personnel not involved in clean up operations to keep at a designated, safe distance. wear protective clothing and equipment consistent with the degree of hazard. Carefully sccop up the spillage and place in a suitable, properly labeled container for recovery TEorEdisposal . Take VISED: 28 July care to avoid DATE APPROVED: 03 January 91 L 'i6Y w SmithKline Beecham MSDS NUMBER: 10000255 PAGE: 3 MATERIAL SAFETY DATA SHEET excessive dust during cleanup. Wash down spillage area with copious amounts of water. This must only be undertaken if waste water can be directed to an on-site waste water treatment system. DECONTAMINATION PROCEDURES: Water based detergents are expected to be effective in cleanup and decontamination operations. 7. HANDLING AND STORAGE HANDLING: All plant, equipment and operators must be earthed (grounded) to ensure that no isolated conductors are present. This material is of low conductivity and coupled with its appreciable charge decay time might represent a source of electrostatic charge accumulation. Enclosure is recommended to routinely control airborne dust levels below published exposure limits. STORAGE: Avoid prolonged storage at elevated temperatures (greater than room temperature, approximately 20 degrees C) . Keep in tightly closed containers or packages away from moisture. 8.' EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE CONTROLS: No permissible exposure limits established by SmithKline Beecham, Australia, Belgium, Denmark, France, Germany, United Kingdom (ESE) or United States (ACGIH,OSHA) ,INDUSTRIAL HYGIENE METHOD: For SmithKline Beecham operations, contact the site Occupational or Industrial Hygienist or regional Corporate health and safety group, as appropriate, for advice on suitable monitoring methods. For other operations, industrial hygiene monitoring advice may be obtained from the health and safety group identified in section 1. PERSONAL PROTECTION: RESPIRATORS: If dust is present, a laboratory fume hood, local exhaust ventilation or an appropriate respirator should be used. The specific type used will be determined by air concentrations present. Follow local regulations for respirator use in the workplace. GLOVES: Wear neoprene or other equivalent impervious gloves for handling wet or dry powder. EYE PROTECTION: Wear safety glasses with sideshields when handling this material. HYGIENE PRACTICES: Wash hands and arms thoroughly after handling this material. Clean up spills immediately. OTHER PROTECTIVE EQUIPMENT: Wear lab coat or other protective clothing with long sleeves. An eye wash station should be available. 9 . PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: A white to off white, odorless or almost odorless powder. FLASH POINT: Expected to be greater than 55 degrees C. DATE APPROVED: 03 January 91 DATE REVISED: 28 July 93 i MSDS NM-MER: 10000255 PAGE: 4 MATERIAL SAFETY DATA SHEET AUTOIGNITION TEMP: Not determined. LOWER EXPLOSIVE LIMIT: Not applicable for solids. UPPER EXPLOSIVE LIMIT: Not applicable for solids. MELTING POINT: 183 to 185 degrees C. BOILING POINT: Not applicable. VAPOUR DENSITY: Negligible. VAPOUR PRESSURE: Negligible. EVAPORATION RATE: Negligible. VOLATILE COMPONENTS M : None expected. VISCOSITY: Not applicable for solids. PH OF AQUEOUS SOLUTIONS: Mildly acidic (pH approximately 4 to 5 for a 5k solution) . -RELATIVE DENSITY: Not determined. CONDUCTIVITY: Not applicable for solids. OCTANOL/WATER DISTRIBUTION COEFFICIENT: Kow = 1.49 (at pH 7) . DISSOCIATION CONSTANT (pKA) : 6.9 SOLUBILITY: Soluble in water (approximately 6 g/L) and ethyl alcohol. Slightly soluble in chloroform. Insoluble in ether. OXYGEN BALANCE: This material is considered to be of moderate energy hazard potential based oxygen balance calculated as minus 158. TRAIN FIRE TEST: This material is classified as a non combustible solid. It is therefore considered not to support combustion in bulk quantities. Time for a 10 can burn was not applicable. DUST EXPLOSIVITY: Classification: Not determined. Minimum explosive concentration (grams/cubic metre) : Not .determined. Minimum ignition temperature - cloud (degrees C) : Not determined. Minimum ignition temperature - layer (degrees C) : Not determined. Minimum oxygen concentration (fir v/v) : Not determined. Explosion characteristics: Pmax (bar) : Not determined. dP/dT (bar/second) : Not determined. Kst (bar metre/second) : Not determined. St class: Not determined. DUST ELECTRICAL PROPERTIES: Minimum ignition energy (mjoules) : Not determined. Resistivity at ambient humidity (ohm meter) : Not determined. Charge decay time at ambient humidity (seconds) : Not determined. Resistivity at low humidity (ohm metre) : Not determined. DATE APPROVED: 03 January 91 DATE REVISED: 28 July 93 to .; ,�_ '� .s SmithKline Beecham MSDS NUMBER: 10000255 PAGE: 5 MATERIAL SAFETY DATA SHEET Charge decay time at low humidity (seconds) : Not determined. 10. STABILITY AND REACTIVITY i t CONDITIONS TO AVOID: Equipment used to mill, grind or transfer this material should be designed with proper grounding and to avoid excessive heat or sparks. All electrical equipment used in milling, grinding or transferring this material should be rated for Class II, Division I electrical classification (per US National Electrical Code) or equivalent. Mills should be equipped with ammeters and the lowest possible overload heaters. Previous experience supports using a maximum overload heater of 7;r greater than the mill electrical load. Cooling systems can be used in addition to ammeters to control heat. INCOMPATIBILITY: Not identified. STABILITY: This material is expected to be stable. THERMAL STABILITY: Capillary tube test: Not determined. Differential scanning calorimetry: Not determined. Accelerating rate calorimeter: Not determined. HAZARDOUS POLYMERIZATION: Not expected to occur. HAZARDOUS DECOMPOSITION PRODUCTS: Not identified. FIRS AND EXPLOSION HAZARDS: As with many organic dusts, explosions can result if excessive dust concentrations are present. Based on laboratory studies, this material is a combustible dust which presents potential for dust deflagration. 11. TOXICOLOGY INFORMATION ORAL TOXICITY: The oral rat LD50 was not determined but is expected to be greater than 2000 mg/kg based on the results of the chemical base form of this material. INHALATION TOXICITY: Allergic type reactions were reported for a small number of individuals after breathing dust. SKIN IRRITATION: This material was classified as a mild irritant to rabbit skin. Minimal signs of irritation occurred up to 1 hour after direct application to unabraded rabbit skin for 4 hours. Skin appeared normal 1 day after treatment. This material caused redness to occur up to 3 days after direct application to abraded rabbit skin for 4 hours. Skin appeared normal 7 days after treatment. EYE IRRITATION: This material was classified as a mild irritant in rabbit eyes. Conjunctival redness, swelling and discharge occurred up to 2 days after direct application in rabbits. Eyes appeared normal 3 days after treatment. SENSITISATION: This material was classified as a moderate sensitises to guinea pig skin. Adverse skin reactions or irritation occurred in 50V of guinea pigs used to test for allergic reaction or sensitisation (maximisation DATE APPROVED: 03 January 91 DATE REVISED: 28 July 93 MSDS NUMBER: 10000255 PAGE: 6 MATERIAL SAFETY DATA SHEET test) . Allergic skin reactions were reported for some individuals working with this material. MUTAGENICITY: This material is not expected to be mutagenic in bacteria (Ames test or Bacillus subtilis rec assay) or mice (micronucleus test) based on effects of cimetidine base. CARCINOGENICITY: This material is not listed as a carcinogen by SB, IARC, NTP or US OSHA. REPRODUCTIVE EFFECTS: No teratogenic effects (birth defects) , embryotoxicity or adverse effects on female or male reproduction resulted in studies with mice, rats or rabbits. PHARMACOLOGICAL EFFECTS: This material inhibits gastric acid secretion and is used to treat gastric and duodenal ulcers. 12. ECOLOGICAL INFORMATION i ACUTE AQUATIC EFFECTS: 48-hour EC50 for Daphnia pulex - 740 mg/L (as cimetidine base) . 48-hour no-observed-effect-concentration for Daphnia pulex = 230 mg/L (as cimetidine base) . 96-hour EC50 for Bluegills, not determined. 96-hour no-observed-effect-concentration for Bluegills = 1000 mg/L (as cimetidine base) . BIODEGRADATION: Expected to readily biodegrade. ACTIVATED SLUDGE RESPIRATION INHIBITION (OECD 209 PROTOCOL) : EC50 greater than 1000 mg/L (as cimetidine base) . OTHER EFFECTS: Limited adsorption in soil. 13 . DISPOSAL CONSIDERATIONS i Collect for recycling or recovery, if possible. Dispose of material on site in a licensed chemical incinerator, if allowed by the incinerator license or permit. If no on-site incinerator is. available, dispose of material in a licensed commercial chemical incinerator. 14. TRANSPORT INFORMATION I FOR AIR TRANSPORT (IATA REQUIREMENTS) : Proper Shipping Name: NOT RESTRICTED Technical Name (for n.o.s. , not otherwise specified) : Not applicable UN/Identification Number: Not applicable Class/Division: Not applicable Sub Risk: Not applicable Packing Group: Not applicable RQ (Reportable Quantity) : Not applicable Emergency Response Guide Number: Not applicable FOR MARITIME TRANSPORT (IDMG REQUIREMENTS) Proper Shipping Name: NOT RESTRICTED Technical Name (for n.o.s. , not otherwise specified) : Not applicable UN/Identification Number: Not applicable Class: Not applicable Sub Risk: Not applicable Packing group: Not applicable DATE APPROVED: 03 January 91 DATE REVISED: 28 July 93 It SmithKline Beecham MSDS NUMBER: 10000255 PAGE: 7 MATERIAL. SAFETY DATA SHEET IMDG page number: Not applicable MFAG number: Not applicable EMS number: Not applicable Marine Pollutant: Not applicable Emergency Response Guide Number: Not applicable FOR UNITED STATES GROUND TRANSPORT (DOT REQUIREMENTS) : Proper Shipping Name: NOT RESTRICTED ' Technical Name (for n.o.a. , not otherwise specified) : Not applicable UN/Identification Number: Not applicable Class/Division: Not applicable Sub Risk: Not applicable Packing Group: Not applicable RQ (Reportable Quantity) : Not applicable Emergency Response Guide Number: Not applicable FOR EUROPEAN GROUND TRANSPORT (ADR/RID/ROAD/RAIL REQUIREMENTS) : Not determined. Hazards according to ADR/RID requirements not identified. EMERGENCY INFORMATION: HAZCHEM code: Not applicable. TREMCARD number: Not applicable. 15. REGULATORY INFORMATION ' FOR EC CLASSIFICATION, PACKAGING AND LABELLING REQUIRIIMENTS: FIRE RISK CLASSIFICATION NO FIRE HAZARD IDENTIFIED HEALTH RISK CLASSIFICATION HARMFUL IRRITANT RISK PHRASES: MAY CAUSE SENSITISATION BY INHALATION. (R42) MAY CAUSE SENSITISATION BY SKIN CONTACT. ( R43) SAFETY PHRASES: DO NOT BREATHE DUST. (S22) AVOID CONTACT WITH SKIN. (S24) WEAR SUITABLE PROTECTIVE CLOTHING. (S36) WEAR SUITABLE GLOVES. (S37) SYMBOL: ST. ANDREW'S CROSS(Xn) & ST. ANDREW'S CROSS(Xi) 16. OTHER INFORMATION HAZARD LABEL: **** NO FIRE HAZARD IDENTIFIED **** *•** HARMFUL AND IRRITANT **** ** MAY CAUSE SENSITISATION BY INHALATION. ** MAY CAUSE SENSITISATION BY SKIN CONTACT. ** DO NOT BREATHE DUST. ** AVOID CONTACT WITH SKIN. ** WEAR SUITABLE PROTECTIVE CLOTHING. ** WEAR SUITABLE GLOVES. ** TARGET ORGAN-NO SPECIFIC TARGET ORGAN EFFECTS KNOWN. IF HMIS RATINGS ARE USED AT YOUR SITE, USE THE FOLLOWING: HEALTH = 2 FIRE= 4 REACTIVITY 0 REFERENCES: DATE APPROVED: 03 January 91 DATE REVISED: 28 July 93 , r _-j -------------------• -- MATERIAL SAFETY DATA SH---�T -- ---------- - ---------- Evsco CLIPPER AID --------------------------------------------------------------------------------------------------------------------------- ----------------------------------------------------------- ----------------------------------------------------------- SECTION I SECTION VII - SPILL OR LEAK PROCEDURES ----------------------------------------------------------- ----------------------------------------------------------- MANUFACTURER'S NAME: EVSCO PHARMACEUTICALS, STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: IMMUNOGENETICS, INC. Ventilate area and wash spill site after material pickup P.O. BOX 209 (HARDING HIGHWAY) is complete. Wear self-contained breathing apparatus, BUENA, NJ 08310 rubber boots and heavy rubber gloves. EMERGENCY TELEPHONE NUMBER: (609) 691-2411 WASTE DISPOSAL METHOD: Do not puncture or incinerate. CHEMICAL NAME AND SYNONYMS: Clipper Lubricant Consult local regulations for large quantities that can TRADE NAME AND SYNONYMS: Clipper Aid not be exhausted by use. CHEMICAL FAMILY: Lubricant ----------------------------------------------------------- FORMULA: SECTION VIII - SPECIAL PROTECTION INFORMATION -------------------------------------------------------—-- ----------------------------------------------------------- SECTION II - HAZARDOUS INGREDIENTS RESPIRATORY PROTECTION (Specify Type) : Not usually required ----------------------------------------------------------- for normal use. The primary hazards from this product stem from the VENTILATION: presence of the following ingredients: Mineral Oil, LOCAL EXHAUST: Preferable Isopropyl Alcohol, 1,1,1-Trichloroethane, propane and MECHANICAL (General) : butane SPECIAL: ----------—------------------------------- OTHER: SECTION III - PHYSICAL DATA PROTECTIVE GLOVES: Recommended ----------------------------------------------------------- EYE PROTECTION: Recommended BOILING POINT (deg F) : Not determined OTHER PROTECTIVE EQUIPMENT: VAPOR PRESSURE (mm Hg.) : Not determined ----------------------------------------------------------- VAPOR DENSITY (AIR = 1) : Not determined SECTION IX - SPECIAL PRECAUTIONS SOLUBILITY IN WATER: Not determined ----------------------------------------------------------- SPECIFIC GRAVITY (H2O = 1); Not determined PRECAUTION TO BE TAKEN IN HANDLING AND STORING: Store in PERCENT VOLATILE BY VOLUME (%): Not determined cool dry place. Exposure to temperatures above 130 deg F EVAPORATION RATE ( = 1): Not determined may cause bursting. APPEARANCE AND ODOR: Not determined OTHER PRECAUTIONS: Warning:: Flammable. Contents under ----------------------------------------------------------- pressure. Keep away from heat, sparks and open flame. Do SECTION IV - FIRE AND EXPLOSION HAZARD DATA not puncture or incinerate container. Read label ---------------------------------------------------------— carefully before use. FLASH POINT (Method Used) : ----------------------------------------------------------- FLAMMABLE LIMITS: Highly flammable The information contained in this Material Safety Data LEL Sheet has been compiled from information believed to be UEL: accurate and from our own experience. While we believe that EXTINGUISHING MEDIA: Carbon dioxide, dry chemical powder, the data presented is factual, ImmunoGenetics, Inc. and its alcohol or polymer foam. affiliates make no warranty or representation, nor assumes SPECIAL FIRE FIGHTING PROCEDURES: any responsibility in conjunction with the use of this UNUSUAL FIRE AND EXPLOSION HAZARDS: Exposure to information. temperaturesabove 130 deg F may cause bursting. ----------------------------------------------------------- ----------------------------------------------------------- DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: Although SECTION V - HEALTH HAZARD DATA reasonable care has been taken in the preparation of this ----------------------------------------------------------- document, we extend no warranties and make no THRESHOLD LIMIT VALUE: 1,1,1-Trichloroethane - TLV-TWA 350 representation as to the accuracy or completeness of the ppm information contained therein, and assume no responsibility EFFECTS OF OVEREXPOSURE: May be harmful by inhalation, regarding the suitability of this information for the injection or skin absorption, vapor or mist irritating to user's intended purposes or for the consequences of its the eyes, mucous membranes and upper respiratory tract. use. Bach individual should make a determination as to the Prolonged exposure can cause narcotic effect. suitability of the information for their particular EMERGENCY AND FIRST AID PROCEDURES: purpose(e) . A request has been made to the manufacturer to EYES: Immediately flush with copious amounts of water for approve the contents of this material safety data sheet. at least 15 minutes and consult a physician. Upon receipt a new MSDS will be made available. SKIN: Immediately wash skin with soap and copious amounts ----------------------------------------------------------- of water. COMPAS Code: 13820090 IF INHALED: Remove to fresh air and consult a physician. ----------------------------------------------------------- SECTION VI - REACTIVITY DATA -----------------------—---------------------------------- STABILITY: Stable CONDITIONS TO AVOID: High temperatures. Temperatures above 130 deg F may cause bursting. INCOMPATIBILITY (Materials to Avoid) : HAZARDOUS DECOMPOSITION PRODUCTS: HAZARDOUS POLYMERIZATION: Will Not Occur CONDITIONS TO AVOID: 4/04/00------------------------------------------------------------------------------------------------------------------- MWI VETERINARY SUPPLY 5611235 NORTHWEST VET CLINIC/STANWOOD Page 1 of 1 -- - - - - - - - ------------ -- MATERIAL SAFETY DATA SHZ.r - - - - - - -- - - - - - - -- --- -- -- Beaumont CITRUS II GERMICIDAL DEODORIZING CLEANER --------------------------------------------------------------------------------------------------------------------------- IDENTITY (As Used on Label and List): Citrus II Germicidal SIGNS AND SYMPTOMS OF EXPOSURE: Eye and akin irritation may Deodorizing Cleaner develop depending on duration and severity of exposure. ----------------------------------------------------------- Ingestion may cause irritation nausea, diarrhea or SECTION I vomiting depending on severity of exposure. ----------------------------------------------------------- MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: N/A MANUFACTURER'S NAME: BEAUMONT PRODUCTS, INC. EMERGENCY AND FIRST AID PROCEDURES: 1560 BIG SHANTY ROAD SKIN - flush exposed areas for 15 min. Apply skin lotion KENNESAW, GA 30144 if defatting occurs. EMERGENCY TELEPHONE NUMBER: (770) 514-9000 INGESTION - drink 1-2 glasses of water. Induce vomiting TELEPHONE NUMBER FOR INFORMATION: (770) 514-9000 by taking 1-2 TLBS of syrup of ipecac. Then get DATE PREPARED: 10/17/95 immediate medical attention. ----------------------------------------------------------- BYES - flush for 15 min. Seek medical attention. SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION ----------------------------------------------------------- ----------------------------------------------------------- SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Hazardous Components ----------------------------------------------------------- (Specific Chemical STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Identity; Common OSHA ACGIH Other Limits Do not discharge effluent containing this product into Name(s)) PSL TLV Recommended (optional) lakes, streams, ponds, estuaries, oceans, or other waters ------------------ ------------------------ unless in accordance with the requirements of a National Chelating Agents N.E. N.S. Pollutant Discharge Elimination System (NPDES) permit and Diethylene Glycol N.E. N.E. the permitting authority has been notified in writing n.Butyl Ether prior to discharge. Do not discharge effluent containing ----------------------------------------------------------- this product to sewer systems without previously SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS notifying the local sewage treatment plant authority. For ----------------------------------------------------------- guidance contact your State Water Board or Regional BOILING POINT: 212F Office of the SPA. VAPOR PRESSURE (mm Hg.): NA WASTE DISPOSAL METHOD: This material is regulated under VAPOR DENSITY (AIR = 1): NA sara title III. Follow local, state and federal SPECIFIC GRAVITY (H20 = 1): 1.009 regulations to ensure proper disposal. MELTING POINT: NA PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Maintain EVAPORATION RATE (Butyl Acetate = 1): NA adequate ventilation, wear rubber gloves for prolonged SOLUBILITY IN WATER: Excellent exposure. Wear approved glasses if eye contact if APPEARANCE AND ODOR: Translucent, yellow with a lemony possible. odor. OTHER PRECAUTIONS: Avoid contact with eyes, skin, clothing. ----------------------------------------------------------- Wash thoroughly with soap and water after handling. Wash SECTION IV - FIRS AND EXPLOSION HAZARD DATA contaminated clothing before reuse. ----------------------------------------------------------- ----------------------------------------------------------- FLASH POINT (Method Used): Not Combustible SECTION VIII - CONTROL MEASURES FLAMMABLE LIMITS: ----------------------------------------------------------- LEL: NA RESPIRATORY PROTECTION (Specify Type): USL: NA VENTILATION: EXTINGUISHING MEDIA: Use appropriate media for surrounding LOCAL EXHAUST: Maintain general ventilation structures & containers. MECHANICAL (General) : Maintain general ventilation SPECIAL FIRS FIGHTING PROCEDURES: Wear self-contained SPECIAL: N/A breathing apparatus in contained areas or where smoke or OTHER: N/A fumes can drift or accumulate. PROTECTIVE GLOVES: Wear rubber gloves for prolonged UNUSUAL FIRE AND EXPLOSION HAZARDS: N/A exposure. ----------------------------------------------------------- EYE PROTECTION: Wear approved eyeglasses if eye contact is SECTION V - REACTIVITY DATA possible. ----------------------------------------------------------- OTHER PROTECTIVE CLOTHING OR EQUIPMENT: N/A STABILITY: Stable WORK/HYGIENIC PRACTICES: Wash thoroughly after handling. CONDITIONS TO AVOID: High Temperatures ----------------------------------------------------------- INCOMPATIBILITY (Materials to Avoid) : N/A DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: Although HAZARDOUS DECOMPOSITION OR BYPRODUCTS: oxides of carbon and reasonable care has been taken in the preparation of this nitrogen may form upon thermal decomposition document, we extend no warranties and make no HAZARDOUS POLYMERIZATION: Will Not Occur representation as to the accuracy or completeness of the CONDITIONS TO AVOID: Excessive heat information contained therein, and assume no responsibility ----------------------------------------------------------- regarding the suitability of this information for the SECTION VI - HEALTH HAZARD DATA user's intended purposes or for the consequences of its ---------------------------------------------------------- use. Bach individual should make a determination as to the ROUTE(S) OF ENTRY: suitability of the information for their particular INHALATION? No purpoee(s) . A request has been made to the manufacturer to SKIN? No approve the contents of this material safety data sheet. INGESTION? Yee Upon receipt a new MSDS will be made available. HEALTH HAZARDS (Acute and Chronic): ------------------ ACUTE: Eyes, may cause irritation, ingestion, may cause COMPAS Code: 15480012 NAC Approved Date: gastrointestinal irritation, vomiting, nausea, diarrhea. Skin - may cause irritation due to defatting of skin. CHRONIC: N/A CARCINOGENICITY: No NTP? No IARC MONOGRAPHS? No OSHA REGULATED? No 5/06/97------------------------------------------------------------------------------------------------------------------- MWI VETERINARY SUPPLY 3290679 NORTHWEST VET CLINIC/STANWOOD Page 1 of 1 I MATERIAL SAFETY DATA SHEET PITMAN-MOORE P.O. Box 207, Terre Haute, IN 47808 (800) 541-7459, 24 Hours SECTION 1 . PRODUCT IDENTIFICATION PRODUCT NAME: Conofite Lotion/Spray, 1% THERAPEUTIC CLASS: Antifungal DOT CLASS: Not regulated CAS. NUMBER: N/A PHM-02l SECTION 1:I . COMPOSITION CAS. NO. Ethyl Alcohol 50-60 64-17-5 Polyethylene Glycol 400, USP 40-50 25322-68-3 Miconazole Nitrate 1-3 22832-87-7 SECTION 11I . PHYSICAL DATA SPECIFIC GRAVITY: 0. 9490 APPEARANCE AND COLOR: Clear, colorless with odor characteristic of ethanol . SECTION ; V. FIRE AND EXPLOSION HAZARD DATA FLASH POINT, METHOD: (CC) 75 °F UEL: ND LEL: ND EXTINGUISHING MEDIA: Water fog, alcohol foam, carbon dioxide, dry -chemical. FIREFIGHTING PROCEDURES: Firefighters should wear full protective clothing and self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: None know. SECTION V, REACTIVITY DATA STABILiu r: Stable CONDITIONS TO AVOID: Heat, sources of iVw tion. HAZARDOUS DECOMPOSITION PRODUCTS: Oxidizers. HAZARDOUS POLYMERIZATION: Will not occur. The information data and recommendations contained herein are believed to be accurate. Pitman-Moore, Inc. makes no warranty of any kind whatever with respect thereto and disclaims all liability from reliance thereon. -i- PHM-021 C1111111 Provided as a "Value Added Service" ���, by The Butler Company K t a I I Conofite Lotion/Spray, 1% Page 2 of 2 CARCINOGENICITY: Not listed by NTP, IARC, or OSHA. THRESHOLD LIMIT VALUE: Not established (Ethanol-1000 ppm PEG-100 ppm (DOW) . ROUTES OF EXPOSURE: Eye and skin contact. EFFECTS OF OVEREXPOSURE: May cause eye irritation. May cause drying of skin, irritation, and allergic contact dermatitis. FIRST AID: INGESTION: Rinse mouth thoroughly and call Poison Control Center. INHALATION: Remove to fresh air and support breathing as necessary. EYES: Flush with copious amounts of water for at least 15 minutes while holding eyelid open and turning eye in all directions. SKIN: Wash thoroughly with soap and water after each contact. SECTION VII . SPILL, LEAK, AND DISPOSAL INFORMATION STEPS TO BE TAKE IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition and ventilate area. Soak up spilled material with suitable inert absorbent material and place in suitable containers. WASTE DISPOSAL METHOD: Contaminated material can generally be disposed of at an approved disposal facility, in accordance with applicable federal, state, and local regulations. SECTION VIII . SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: Not necessary under normal conditions of use. If necessary (spill, etc. ) , use a respirator equipped with an organic vapor cartridge. VENTILATION: General and/or local exhaust to keep ethanol vapors belcvv. 'th c IF.. %.cc' l' EYE PROTECTION: glasses. SKIN PROTECTION: Wear gloves to prevent skin contact. OTHER: Wear protective clothing as necessary to prevent skin contact. SECTION IX, SPECIAL PRECAUTIONS STORAGE AND HANDLING: Store in a well closed container away from heat. EXPIRATION: 3 years WORK/HYGIENIC PRACTICES: Avoid contact with skin and eyes. Wear gloves when handling. Wash after contact. FEDERAL LAW RESZRICTS THE USE OF THIS DRUG TO (OR ON THE ORDER OF) A LICENSED VETERIK4RIAN. �g MATERIAL SAFETY DATA SHEET PITMAN-MOORE P.O. Box 207, Terre Haute, IN 47808 ( 800) 541-7459, 24 Hours SECTION I . PRODUCT IDENTIFICATION PRODUCT NAME : Conofite Lotion/Spray, 1% THERAPEUTIC CLASS : Antifungal DOT CLASS: Not regulated CAS. NUMBER: N/A SECTION II . COMPOSITION % CAS. NO. Ethyl Alcohol 50-60 64-17-5 Polyethylene Glycol 400, USP 40-50 25322-68-3 Miconazole Nitrate 1-3 22832-87-7 SECTION III . PHYSICAL DATA SPECIFIC GRAVITY: 0 . 9490 APPEARANCE AND COLOR: Clear, colorless with odor characteristic of ethanol . SECTION IV. FIRE AND EXPLOSION HAZARD DATA FLASH POINT, METHOD: (CC) 75 °F UEL: ND LEL: ND EXTINGUISHING MEDIA: Water fog, alcohol foam, carbon dioxide, dry -chemical . FIREFIGHTING PROCEDURES: Firefighters should wear full protective clothing and self-contained breathing apparatus . UNUSUAL FIRE AND EXPLOSION HAZARDS: None know. SECTION V. REACTIVITY DATA STABILITY: Stable CONDITIONS TO AVOID: Heat, sources of ignition. HAZARDOUS DECOMPOSITION PRODUCTS: Oxidizers . HAZARDOUS POLYMERIZATION: Will not occur. The information data and recommendations contained herein are believed to be accurate. Pitman-Moore, Inc. makes no warranty of any kind whatever with respect thereto and disclaims all liability from reliance thereon. -1- Conofite Lotion/Spray, 1% Page 2 of 2 CARCINOGENICITY: Not listed by NTP, IARC, or OSHA. THRESHOLD LIMIT VALUE : Not established (Ethanol-1000 ppm PEG-100 ppm (DOW) . ROUTES OF EXPOSURE: Eye and skin contact. EFFECTS OF OVEREXPOSURE: May cause eye irritation. May cause drying of FIRST AID: skin, irritation, and allergic contact dermatitis INGESTION: Rinse mouth thoroughly and call Poison Control Center. INHALATION: Remove to fresh air and support breathing as necessary. EYES: Flush with copious amounts of water for at least 15 minutes while holding eyelid open and turning eye .in all directions . SKIN: Wash thoroughly with soap and water after each contact. SECTION VII . SPILL, LEAK, AND DISPOSAL INFORMATION STEPS TO BE TAKE IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition and ventilate area. Soak up spilled material with suitable inert absorbent material and place in suitable containers . WASTE DISPOSAL METHOD: Contaminated material can generally be disposed of at an approved disposal facility, in accordance with applicable federal, state, and local regulations . SECTION VIII . SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: Not necessary under normal conditions of use. If necessary (spill, etc . ) , use a respirator equipped with an organic vapor cartridge. VENTILATION: General and/or local exhaust to keep ethanol vapors below the recommended limit. EYE PROTECTION: Safety glasses . SKIN PROTECTION: Wear gloves to prevent skin contact. OTHER: Wear protective clothing as necessary to prevent skin contact. SECTION IX. SPECIAL PRECAUTIONS STORAGE AND HANDLING: Store in a well closed container away from heat. EXPIRATION: 3 years WORK/HYGIENIC PRACTICES : Avoid contact with skin and eyes . Wear gloves when handling. Wash after contact. FEDERAL LAW RESTRICTS THE USE OF THIS DRUG TO (OR ON THE ORDER OF) A LICENSED VETERINARIAN. Gillette Medical Evaluation Lcibaratorles 401 Professional Drive Gaithersburg, Marylond 20879 , 301-590-9781 MATERIAL SAFETY DATA SHEET NAME: LIQUID,,PAPER CORRECTION FLUID (WHITE AND COLORS, LPCF-49 LPCF•8, LPCF-g): CAS N0: NA .11 Effective Date: 8/22/90 1 . ._� Rev:,` A. lDF--NTlFlCA"Il0N Composition• % Forrn�la: Mixture 1 ,1 ,1-Trichlproethane (71-55-6) Titanium Dioxide (13463-67-7) Resin(s) MolecularWalght: NA Mineral Spirits (64741-65-7) Di(2-ethylhexyl)Phthalate (I17-81-7) synonyms . Mustard Oil (57-06-7)Colorant(s) 1 11 Liquid Paper MENOMINEE PHYSICAL DATA Boiling Point Melting Point . Freezing Point 165 of ---�4 oc N_ of NA_cc NA of NA o Specific Gravity-(H2()-1) Vapor Density (aird) Vapor Pressure ei 68 OF ~1'. 7 4.5 100 mmHg Evaporation Saturation in Air Autoignition Temperature c E th r 61) (by volume @ OF) OF oc low r NA % NA %Volatile$ (by volume) Solubility in Water �50. .. 0% PH NA Appearance/Odor' White or colored fluid with a pungent solvent odor Flash Point and > 200'F, >931C (Closed Cup) Test Method it) Product is non-flammable . Flammable Limits in-Air (See Section H. ) (%by volume) ._; Lower NA % upper NA % Stability Conditions to Avoid Polymerization Conditions to Avoid stable X Contact with open flame or may occur other high temperature NA unstable -source. will not occur X Incom atible Mate i,ls, or solvent: strRng alkalis Hazardous Decomposition Products Thermal degrade- . oxidpizers; a�uminum, zinc and other tion, e.g. , open flame, can produce small reactive metals (e.g. , potassium, sodium, amounts of phosgene, hydrogen chloride magnesium ). and chlorine , -)MULTIPLE INC;FIEDIENTS INCLU=UMBERS FORNA-- NOTAVAILA13LE Footnotes: Physicail data, except % Volatiles and Specific Gravity,refers to 1 0,l-Tri chl oroethane. �,,. I I =upational Exvosurt Limiq (PEL'$,TLV'S'etc.) 8 dour TUA's: 1:00-Trichloroethane - 350 ppm (OSHA/ACGIH) rr Titanium Dioxide , 10 mg/cu m (OSHA/ACGIH) 4, ..01(2-ethylhexyl)Phthalate - 5 mg/cu m (OSHA/ACGIH) These levels are not anticipated under foreseeable use conditions. 'lining Signals NA rotes/Effeeu of Exoosure'_ t, inhalation No adverse effects anticipated from normal use. If vapors are deliberately concentrated and inhaled (abuse) , following symptoms may occur: respiratory irritation, dizziness, drowsiness, headache, nausea, unconsciousness, cardiac sensitization (abnormal heartbeat) , coma and death. (Mustard oil is added to the product as an abuse deterrent. ) 2. Inwstion No adverse effects anticipated from normal use. Depending on amount ingested, most of the symptoms desdribed above may occur. Estimated LD in rats is greater than 5 ml/kg or between 1 pint and 1 quart in humans �Pef. Gosselin, Smith and Hodge, Clinical Toxicology of I Skin . Commercial Products, 5th ed. , 1984) . — a. Contact No adverse effects anticipated from normal use. Irritation may occur if contact ..is prolonged/repeated. b. Absorotion No adverse effects anticipated from normal use. through skin Solvent can be absorbed 9 (prolonged contact) , but not likely in acutely toxic amounts. Estimated LDSG in rabbits is greater than 5 ml/kg. 4, Eye Contact Irritation 5.Other SOO Statement Below a I. Applidble Regulatioritt NA !. DOT Hazard Clau-- !. DOT Shipping Name irpnmental EH*= NA er: Based on animal feeding studies, D1(2-ethy hexy phtha ate or DEHP- is listed by IARC and NTP as a possible human cardinogen, if ingested. Normal use of this Product would result in no ingestion of DEHP. There is no evidence of cancer ` due to isolated incidents of ingestion, such as accidental ingestion. A quantitative risk assessment demonstrates that DEHP in Liquid Paper is not a significant risk to humans because of its low concentration and low exposure Potential . Y �i 1 _',EXPOSURE CONTPOLMETHODS Engineering Controls None under normal use conditions Eye Protection None under normal use conditions Skin Protection None under normal use conditions Respiratory Protection None under.!,normal use conditions Other Product is- rion-hazardous when used as directed in an office/room with normal air circulation. G. _ WORK PRACTICES Handling and Storpe, I. No unusual handling or storage when used as directed; when stored in large quantities '('as in warehouse) , it should be in a well-ventilated, cool area. Normal Clean Up Pick up spills with towels, tissues, etc. 'Nam'Disposal Mgthods Dispose ,in 'iccordance with applicable federal , state and local laws. ,i;, r� ,r S♦ OFFICE DEPOT 814 6195587850 ' P. 05 Steps to be taken if MAWial Is released to the environment or spilled in the work area Not applicable ' Fire and Explosion Hazard Extinguishing Media Concentrated vapor of 1 ,1 ,1-Trichloroethane can burn, As for adjacent fire: dry producing hazardous decomposition products (Sec. C) . chemical , foam, carbon dioxide, water fog Firefighting Procedures In fires involving large quantities of product, use self-contained breathing apparatus. CAL EM • Eyss Flush with plenty of water. If irritation persists, obtain medical attention. Skin Wash with soap and water. Inhalation No adverse effects anticipated from normal use. In an abuse situation, remove from source of exposure. Treat symptomatically. Oxygen may be administered. Seek medical attention immediately and refer to "Notes to Physician" below. Ingestion Consult physic,i. t►. Notes to Physician The formulation-.contains less than 5% petroleum distillates. Induction of vomiting should be considered at the discretion of the physician. Do not use sympathomimetic agents (e.g. , epinephrine) in halogenated hydrocarbon poisoning because of possible induction of ventricular fibrillation. Y The Information contikied in the Material Safety Oau Sheet is based on data considered to be*=rate,however,no warranty is expressed or Implied regarding du accuracy of the data or the results to be obtained from the use thereof. * LP1R - --- - - - -- ----------- -- MATERIAL SAFETY DATA SH:L. T --- - -- --- - - - - - -- - -- -- -- Upjohn DEPO-MEDROL(R) SUSPENSION --------------------------------------------------------------------------------------------------------------------------- REVISION DATE: July 01, 1994 MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Overexposure to AGENT ID#: 43526 corticoeteroide may increase susceptibility to infection ----------------------------------------------------------- (including reactivation of latent tuberculosis and 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION enhancement of secondary eye infections due to fungi or ----------------------------------------------------------- viruses) or mask some signs of infection. Recent COMMON NAME: Depo-Medrol(R) Suspension (Animal Health immunization procedures may result in a lack of antibody Product) response and neurological disorders. Hypersensitivity to SYNONYMS: 468227 - EDP NUMBER this material may result. Corticosteroids exhibit 468228 - EDP NUMBER enhanced effects on persons with hypothyroidism or 468391 - EDP NUMBER cirrhosis. MOLECULAR FORMULA: Mixture ----------------------------------------------------------- USE: Veterinary drug for the treatment of inflammatory and 4. FIRST AID MEASURES allergic conditions in doge and cats and for the ----------------------------------------------------------- alleviation of pain and lameness associated with acute EYES: Flush with water for 15 minutes. Hold eyelids open to localized or general arthritic conditions in horses. Not assure complete contact with water. for human use. SKIN: Wash with soap and water. Remove contaminated MANUFACTURER/SUPPLIER: THE UPJOHN COMPANY clothing. 7171 PORTAGE RD. INHALATION: Remove from exposure. KALAMAZOO, MI 49001-0000 INGESTION: Contact a physician or poison control center. TELEPHONE NUMBERS: (616) 323-5122 - (24 HOURS) ----------------------------------------------------------- (616) 323-7555 - (8:00 A.M. - 4:30 P.M.) S. FIRE FIGHTING MEASURES ----------------------------------------------------------- ----------------------------------------------------------- 2. COMPOSITION/INFORMATION ON INGREDIENTS FLASH POINT: Nonflammable. ----------------------------------------------------------- LOWER EXPLOSION LIMIT (LEL): Not applicable. COMMON NAME: t BY WEIGHT: CAS NUMBER: UPPER EXPLOSION LIMIT (UEL): Not applicable. ----------------------------------------------------------- EXTINGUISHING MEDIA: Water, carbon dioxide, or dry INGREDIENT 1 91 - 93% 7732-18-5 chemical. Water FIRE-FIGHTING PROCEDURES: Wear self-contained breathing EXPOSURE LIMIT(S) : Not established. apparatus and full body protective equipment. INGREDIENT 2 34 UNUSUAL FIRE OR EXPLOSION HAZARDS: None known. Carbowax(TM) Polyethylene HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide. Carbon Glycol 3350 dioxide. EXPOSURE LIMIT(S): Not established. ----------------------------------------------------------- INGREDIENT 3 24 6. ACCIDENTAL RELEASE MEASURES Non-Hazardous Ingredient(B) ----------------------------------------------------------- EXPOSURE LIMIT(S): Not established. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: INGREDIENT 4 2 - 4% 53-36-1 Control the generation of vapors; provide adequate Methylprednisolone Acetate ventilation and respiratory, skin and eye protection to CHEMICAL NAME: Pregna-1,4-diene-3,20-dione, 21-(acetyl- prevent overexposure. Keep out of drains; prevent entry oxy)-11,17-dihydroxy-6-methyl-, (6.alpha.,11.beta.)- to surface water, groundwater and soil. Vacuum or scoop EXPOSURE LIMIT(S) : spilled material and place in container. UPJOHN EXPOSURE LIMIT-TWA: 4 ug/m3 ----------------------------------------------------------- SKIN NOTATION: Yes 7. HANDLING AND STORAGE EXPOSURE LIMIT(S) FOR THE MATERIAL: Not established. ------------------------------------------------------------ The MSDS for the active ingredient may be referred to for PRECAUTIONS FOR HANDLING AND STORING: Avoid contact with additional information in handling the bulk product. skin, eyes and clothing. Wash thoroughly after handling. ----------------------------------------------------------- Launder contaminated clothing before reuse. Store in a 3. HAZARDS IDENTIFICATION cool, dry place. Protect from light. Keep out of reach of ------------------------------------------ children. PRIMARY ROUTE(S) OF EXPOSURE: Skin contact, eye contact, ---------------------------------------- -- inhalation, and ingestion. B. EXPOSURE CONTROLS/PERSONAL PROTECTION EFFECTS OF OVEREXPOSURE: Methylprednisolone acetate is a ----------------------------------------------------------- glucocorticosteroid. Glucocorticoids affect carbohydrate, RESPIRATORY PROTECTION: Not required. protein and fat metabolism; functions of the VENTILATION: Local exhaust. cardiovascular system, kidney, skeletal muscle, nervous PROTECTIVE GLOVES: Not required. system and other organs and tissues; and may modify the EYE PROTECTION: Not required. body's immune responses to diverse stimuli. Chronic OTHER PROTECTIVE EQUIPMENT: Not required. overexposure to glucocorticoide may produce pituitary- ----------------------------------------------------------- adrenal suppression, Cushing's Syndrome (redistribution 9. PHYSICAL AND CHEMICAL PROPERTIES of body fat to face (-moon face"), back of neck and ----------------------------------------------------------- trunk), increased susceptibility to infections APPEARANCE/PHYSICAL STATE: Aqueous solution. (suppression of inflammatory response), osteoporosis, MOLECULAR WEIGHT: Mixture cataracts, glaucoma with possible damage to optic nerve, ----------------------------------------------------------- mental symptoms, hyperglycemia and glycosuria, muscular 10. STABILITY AND REACTIVITY weakness and fatigue, acne, menstrual disorders and --------------------------------------------——----------- peptic ulcers. Naturally occurring glucocorticoide (such STABILITY: Stable. as hydrocortisone and cortisone), in average and large PHYSICAL CONDITIONS TO AVOID: None. doses, can cause elevation of blood pressure, salt and INCOMPATIBILITY WITH OTHER MATERIALS: None. water retention, and increased potassium excretion. These HAZARDOUS DECOMPOSITION PRODUCTS: None. effects are lase likely to occur with methylprednisolone HAZARDOUS POLYMERIZATION: Does not occur. acetate except in large doses. All corticoeteroide increase calcium excretion. 6/09/99------------------------------------------------------------------------------------------------------------------- MWI VETERINARY SUPPLY 4914667 NORTHWEST VET CLINIC/STANWOOD Page 1 of 2 :i' ------------ - - --- - - -- MATERIAL SAFETY DATA SFa_ 'T ----------------------- Upjohn DEPO-MEDROL(R) SUSPENSION --------------------------------------------------------------------------------------------------------------------------- ----------------------------------------------—------------ 11. TOXICOLOGICAL INFORMATION -------------------------------------------------------- ACUTE STUDIES: The following data applies to the active ingredient methylprednisolone acetate. EYE IRRITATION (RABBIT): Non-irritating. SKIN IRRITATION (RABBIT): Non-irritating to intact or abraded akin. SENSITIZATION: No information found. ORAL LD50 (RAT) : > 30 gramB/kg (not acutely toxic) INTRAPERITONEAL LD50 (MOUSE): > 1,409 mg/kg OTHER STUDIES: GENOTOXICITY: Mutagenicity: methylprednieolone was negative in the DNA damage/alkaline elution assay. TERATOGENICITY: Corticosteroide are generally teratogenic in laboratory animals when administered systemically but there are no well-controlled studies in women. The safety of their use in pregnant women has not been absolutely established. CARCINOGENICITY: Methylprednisolone was negative in the DNA-cell-binding (DCB) assay. Not listed as a carcinogen by IARC, NTP or OSHA. ----------------------------------------------------------- 12. DISPOSAL CONSIDERATIONS ----------------------------------------------------------- WASTE DISPOSAL METHOD: Dispose of by incineration in accordance with applicable international, national, state, and/or local waste disposal regulations. ----------------------------------------------------------- 13. SHIPPING REGULATIONS ------------------------------------------------------------ Not regulated for transportation by the United States Department of Transportation (DOT), International Maritime Organization (IMO), or International Air Transport Association (IATA). May be subject to state and/or local transportation requirements. ----------------------------------------------------------- 14. OTHER INFORMATION ----------------------------------------------------------- REVIEWED BY: Health and Safety Regulatory Affairs DISCLAIMER: The MSDS information is believed to be correct but should only be used as a guide. The Upjohn Company disclaims any express or implied warranty as to the accuracy of the MSDS information and shall not be held liable for any direct, incidental or consequential damages resulting from reliance on the information. ----------------------------------------------------------- 15. LABELING ----------------------------------------------------------- This drug is subject to FDA labeling requirements; therefore, it is exempt from the labeling requirements of the OSHA Hazard Communication Standard. ----------------------------------------------------------- DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representation as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose(B) . A request has been made to the manufacturer to approve the contents of this material safety data sheet. Upon receipt a new MSDS will be made available. ----------------------------------------------------------- COMPAS Code: 41SO0123 NAC Approved Date: 6/09/99------------------------------------------------------------------------------------------------------------------- MWI VETERINARY SUPPLY 4914667 NORTHWEST VET CLINIC/STANWOOD Page 2 of 2 A-54 mBrican Veterinary Distributors Association SECTION Ill-PHYSICAL DATA t,.,0-CIDE L.A.` AVDA MSDS No.:MS 18 Allergroom Shampoo Bolling Point ff):GT 212^. Allerderm,Inc.,P.O.Drawer 277i Hurst,TX 76053. Enter- Continued Specific Gravity(H,0-1):@ 25°C: 1.04 gency Telephone: (817)589.1700. Vapor Pressure(mm Hg.): NIA I SECTION 1-PRODUCT IDENTIFICATION Evaporation Rate: N/A Percent,Volatile by Volume(%)Water: 56 Trade Names/Synonyms: Duo-Cide LA. Solubility In Water: Miscible Vapor Density(Air-1): N/A Chemical Nome and Synonyms: Residual Insecticidal Flea Appearance and Odor: Clear yellow liquid Evaporation Rate: N/A 8 SECTION IV-FIRE AND EXPLOSION HAZARD DATA Solubility In Water: Miscible Tick Spray for Dogs with Pyrelhrin end Permethrin Special Fire Fighting Procedures; Use conventional fire Appearance and Odor: Blue clear/hazy liquid with Chemical Family: Pyrethroids extinguisher. characteristic menthol odor. Formula: Finished Product SECTION V-HEALTH HAZARD DATA SECTION IV-FIRE AND EXPLOSION HAZARD DATA SECTION II-HAZARDOUS INGREDIENTS Effects of Overexposure: Discontinue use or wear rubber Special Fire Fighting Procedures: Use convenllei fire Nothing listed In this section gloves if irritation develops. extinguisher. SECTION/it-PHYSICAL DATA Emergency and First Aid Procedures: Contact physician. SECTION V-HEALTH HAZARD DATA Specific Gravity(H20-1):1.2 SECTION VI-REACTIVITY DATA Effects of Overexposure: Discontinue use if irritation SECTION IV-FIRE AND EXPLOSION HAZARD DATA Nothing noted in this section. develops. Nothing noted in this section SECTION VII-SPILL OR LEAK PROTECTION SECTION VI-REACTIVITY DATA SECTION V-HEALTH HAZARD DATA Steps to be taken In case material Is released or spilled: Nothing listed In this section. Effects of Overexposure: Skin Irritation study Contain all spills. Spilled material Is slippery. SECTION VII-SPILL OR LEAK PROTECTION (rabbits): not a primary irritant;Eye Irritation study SECTION Vill-SPECIAL PROTECTION INFORMATION Steps to be taken In case material Is released or (rabbits): minimal transient toxicity;Acute oral Nothing noted in this section. spilled: Contain all spills, toxicity(rats):LD.>5g/Kg. SECTION IX-SPECIAL PRECAUTIONS SECTION Vlll-SPECIAL PROTECTION INFORMATION SECTION VI-REACTIVITY DATA Nothing noted in this section. Nothing noted In this section Nothing noted in this section SECTION IX-SPECIAL PRECAUTIONS SECTION Vll-SPILL OR LEAK PROTECTION Nothing noted in this section. Nothing noted in this section ALLERSEB-T SHAMPOO , ,y,, SECTION Vlll-SPECIAL PROTECTION INFORMATION Nothing noted in this section AVDA MSDS No.:MS15 DUO-CIDE FLEA& TICK COLLAR SECTION IX-SPECIAL PRECAUTIONS Allerderm,Inc., P.O. Drawer 277,Hurst,TX 76053' Emer- Nothing noted In this section gency Telephone: (817)589-T700. ;FOR DOGS. _ SECTION I-PRODUCT IDENTIFICATION DUO-CIDE SAFETY-STRETCH COLLAR Trade Name/Synonyms: Allereeb-T Shampoo Formula: Salicylic Acid.Sulfur 8 Coal Tar FOR CATS DUO-CIDE SHAMPOO SECTION II-HAZARDOUS INGREDIENTS AVDA MSDS No.:MS17 AVDA MSDS No.:MS 20 None listed Allerderm,Inc.,P.O.Drawer 277,Hurst,TX 76053.Emer- Aller\erm,Inc.,P.O.Drawer 277,Hurst,TX 76053.Emergency SECTION III-PHYSICAL DATA gency Telephone: (817)589-1700. Telephone:(817)589-1700. Bolling Point ff): approx 212° SECTION I-PRODUCT IDENTIFICATION SECTION I-PRODUCT IDENTIFICATION Specific Gravity(H,0-1): Trade Namos/Synonyms: Duo-Cide Flea 8 Tick Collar for Trade Names and Synonyms: Duo-Clde Shampoo Vapor Pressure(mm Hg.) N/A Dogs,Duo-Cide Satoty Strelch Collar for Cats Chemical Name and Synonyms: D-Trans Allethrin lL Percent,Volatile by Volume(%):Water/Ethanol 80 Chemical Family:Chlorpyrlfos Sumithrin Vapor Density(Air-1): N/A SECTION H-HAZARDOUS INGREDIENTS Chemical Family: Pyelhroids Chlorpyrifos 8%; TLV(Units)-0.2 mg/m' Formula: Finished Product Evaporation Rate: NIA SECTION H-HAZARDOUS INGREDIENTS Solubility In Water: Partially Soluble SECTION 111-PHYSICAL DATA Bolling Point ff): N/A Nothing noted in this section Appearance and Odor: Viscous opaque tan liquid with coal , SECTION III-PHYSICAL DATA tar odor. Vapor Pressure(mm Hp.):1.87x10 SECTION IV-FIRE AND EXPLOSION HAZARD DATA Specific Gravity(H,0-1):WA Specific Gravity(H,0-1): 1.2 Percent,Volatile by Volume(%):N/A SECTION IV-FIRE AND EXPLOSION HAZARD DATA Special Fire Fighting Procedures: Use conventional fire Nothing noted in this section extinguisher. Vapor Density(Air-1): WA SECTION V-HEALTH HAZARD DATA Solubility In Water: N/A SECTION V-HEALTH HAZARD DATA Evaporation Rate: N/A Effects of Overexposure: Skin irritation Study(rabbits): Effects of Overexposure: Discontinue use or wear rubber Not a me Irritant;Eye irritation S rabbits gloves ff irritation develops. Appearance and Odor: While crystalline solid. Very faint primary Y hY(rabbits): Emergency and First Aid Procedures: Contact physician. merceptan odor, mildly Irritapng;Acute oral fox..5.15 gnVKg slightly SECTION VI-REACTIVITY DATA SECTION IV-FIRE AND EXPLOSION HAZARD DATA toxic. Nothing noted in this section. Flash Point: No fire or explosion hazard SECTION VI-REACTIVITY DATA SECTION Vol-SPILL OR LEAK PROTECTION Extinguishing Media: Use standard fire fighting Nothing noted In this section procedures depending on source of surrounding fire. SECTION Vll-SPILL OR LEAK PROTECTION Steps to be taken In case material Is released or apllled: Nothing noted in this section Contain all spills and leaks to prevent discharge into Contain runoff. environment. Spilled material is slippery. SECTION V-HEALTH HAZARD DATA SECTION Vlll-SPECIAL PROTECTION INFORMATION Nothing noted In this section Waste Dlspoeal Method: Recover material,or dispose In Emergency and First Wash 9 accordance with all appficable federal,slate and local rogula- water after handling. Atropine is antidote. SECTION IX-SPECIAL PRECAUTIONS tions. SECTION VI-REACTIVITY DATA Nothing noted in this section SECTION Vlll-SPECIAL PROTECTION INFORMATION Incompatibility: Strong oxidizers Nothing noted in this section. Hazardous Decomposition Products: Product Is stable. SECTION IX-SPECIAL PRECAUTIONS Poisonous gas is produced In fire. EFA-Z PLUS AVDA MSDS No.:MS21 Nothing noted in this section. SECTION Vll-SPILL OR LEAK PROTECTION Waste Disposal Method: Avoid contamination with water Allerderm'Ino.,P.O. Drawer 277,Hurst,TX 78053. Emer- _ P gency Telephone: (817)589-1700. supplies. Place material in sealed containers and SECTION I-PRODUCT IDENTIFICATION dispose of In accordance with applicable federal,stale Trade Name and Synonyms: EFA-Z PLUS DERMACOOL : AVDA MSDS No.:MS16 and local regulations. Formula: Vegetable oil w/vilamins a zinc sulfate SECTION Vlll-SPECIAL PROTECTION INFORMATION SECTION 11-HAZARDOUS INGREDIENTS Allerderm,Inc., P.O. Drawer 277, Hurst,TX 76053. Emer- WA gency Telephone: (817)589-1700. Nothing noted In this section SECTION I-PRODUCT IDENTIFICATION SECTION IX-SPECIAL PRECAUTIONS SECTION III PHYSICAL DATA Trade Nome/Synonyms: DermaCool N/A Specific Gravity(H,0-1):®25°C: 0.92 Formula: Water-based astringent - Solubility In Water; Mostly Insoluble SECTION It-HAZARDOUS INGREDIENTS Appearance and Odor: Yellow oily liquid with suspended None listed. powders and characteristic odor. 119 L—� FIRE FIGHTING MEASURES FIRE FIGHTING MEASURES ANDLING AND STORAGE Flre/Exploslon/Reactivlty Data Flre/Exploelon Precautions for Safe Handling and Use Flash Point: 63 F T.C.C, Flesh Point: 63 F TC C Precautions to be Taken In Handling and Storing: Wear waterproof Extinguishing Media: Dry chemical,CO=,water spray or foam Extinguiohing Media: Dry chemical,COt,water spray or foam. gloves when handling spills Fire or Explosion Hazards: None known. Fire or Explosion Hazards: None known. Other Precautions: Wash off exposed skin with soap and water. Fire Fighting Procedures: None known. Fire Fighting Procedures: None known. Decomposition Products: None known. Decomposition Products: None known. EXPOSURE CONTROLS/PERSONAL Flammable Limits: Not known. Flammable Limits: Not known. PROTECTION ACCIDENTAL RELEASE MEASURES ACCIDENTAL RELEASE MEASURES Control Measures Spill and Leak Procedures Spill and Leak Procedures Respiratory Protection:None,not volatile. In Case of Leak or Spill: Remove all sources of ignition.Contain spill In Case of Leak or Spill: Remove all sources of ignition.Contain spill Protective Gloves: If handling frequently,wear gloves. with absorbent material and place into a container for disposal. with absorbent material and place into a container for disposal. Eye Protection: Do not spray on humans. To Dispose:Wrap container and discard in trash. Work/Hyglenlc Practices: Wash exposed skin with soap and water. HANDLING AND STORAGE HANDLING AND STORAGE No data provided PHYSICAL AND CHEMICAL PROPERTIES No data provided Physical/Chemical Characteristics EXPOSURE CONTROLS/PERSONAL EXPOSURE CONTROLS/PERSONAL Bolling Point: 212 PROTECTION PROTECTION Specific Gravity(H20=1): C'25'C•104 Special Protection Information Special Protection Information Vapor Pressure(mm Hg): N/A Respiratory Protection: Not generally needed but do not use product Respiratory Protection: Not generally needed but do not use product Malting Point: Water-32 in a confined area. in a confined area, Vapor Density(Air=1):N/A Ventilation:Not generally needed. Ventilation: Not generally needed. Evaporation Rate(BuAc=1): N/A e e Protective Gloves: Not generally needed. Solubility In Water: Miscible Protective Gloves: Not generally needed. ty Eye Protection: Keep away from eyes.If eye contact is probable,wear Eye Protection: Keep away from eyes.If eye contact is probable,wear Appearance and Odor: Blue clear/hazy liquid with characteristic men• ece protection-glasses or goggles. eye protection-glasses or goggles. thol odor. Follow good industrial practice as to housekeeping,personal hygiene and Follow good industrial practice as to housekeeping,personal hygiene and avoidancc of prolonged or repeated contact with skin or eyes. avoidance of prolonged or repeated contact with skin or eyes. STABILITY AND REACTIVITY PHYSICAL AND CHEMICAL PROPERTIES Reactivlty Date PHYSICAL AND CHEMICAL PROPERTIES Stability:Stable Physical/Chemical Characteristics Physlcal/Chemlcal Characteristics Conditions to Avoid: None Description: Walef•clear liquid,alcohol odor Description: Water-clear liquid,alcohol odor Incompatibility(Materials to Avoid): None Reactivity In Water: Not reactive. Reactivity In Water: Not reactive. Hazardous Decomposition or Byproducts: None Solubility in Water: Miscible in water. Solubility In Water: Miscible in water, Vapor Density: Not known. Vapor Density: Not known. Hazardous t Polymerization:None Will not occur Vapor Pressure: Not known. Vapor Pressure: Not known. Conditions to Avoid: None Melling Point: Not applicable to this product. Melting Point: Not applicable to this product. DISPOSAL CONSIDERATIONS Boiling Point: Nut known. Balling Point: Not knows Specific Gravity:0 Waste Disposal Method:Sanitary landfill or incinerator of absorbed Specific Gravity:0.g(10 � y� spill medium. STABILITY AND REACTIVITY STABILITY AND REACTIVITY Stability: Stable. Stability:Stable Conditions to Avoid: Heat or Open Flame. Conditions to Avoid: Heat or open flame. DermaCool With Lidocaine Materials to Avoid: None known Materials to Avoid: None known. MSDS No: MS99705 October 1991 Hazardous Polymerization: Will not occur Hazardous Polymerization:Will not occur. DISPOSAL CONSIDERATIONS CHEMICAL PRODUCT IDENTIFICATION To Dispose: Wrap container and discard in trash. Trade Name and Synonyms: DermaCool with Lidocaine D-F-T Spray Plus Chemical Name and Synonyms: Lidocaine&Hamamelis extract MSDS No: MS3812 January 23, 19F Chemical Family:Astringent/topical anesthetic CHEMICAL PRODUCT IDENTIFICATION t DermaCool HC Formula: Water-based asiringent/topical anesthetic Identification MSDS No: MSX833 October 31,1990 COMPOSITION/INFORMATION ON INGREDIENTS Trade Name: D-F-T Spray Plus Hazardous Ingredients: N/A Product Code: 7045-1 CHEMICAL PRODUCT IDENTIFICATION Identification COMPOSITION/IN HAZARD IDENTIFICATION FORMATION ON INGREDIENTS Product Name: DermaCool HC Health Hazard IDENTIFICATION Hazardous Ingredients Data Occupation Exposure COMPOSITION/INFORMATION ON INGREDIENTS Effects of Overexposure: Discontinue use if irritation develops Ingredient Limits Hazardous Ingredients: Hydrocorlisone TLV•UIM PEL-UIM FIRST AID MEASURES HAZARD IDENTIFICATION No data provided. I Napthyl N methylcarba- TWA:5 mg1m Health Hazard Data mate-carbanl Route(s)of Entry: Inhalation,skin,ingestion. FIRE FIGHTING MEASURES Pyrethrum TWA:5 mg/m3 Health Hazards(Acute and Chronic):Corticosteroid activity. Fire and Explosion Hazard Data Isopropanol TWA:400 ppm STF.L:500 ppm Carcinogenicity: None Flash Point(Method Used):No explosion hazard HAZARD IDENTIFICATION Signs and Symptoms of Exposure: Immunodepression Special Fire Fighting Procedures: Use conventional fire extinguisher Health Hazards FIRST AID MEASURES ACCIDENTAL RELEASE MEASURES Acute: None expected. Emergency and First Aid Procedures: If inhaled,consult physician. Spill or Leak Procedures Chronic: None expected If on skin,wash thoroughly with soap and water. If ingested,induce vomiting and consult physician. Steps to be Taken In Case Materiel Is Released or Spilled:Contain Signs and Symptoms of Overexposure: Constricted pupils,blurred all spills stsion.hypersalivation,dizziness,nausea and vomiting. FIRE FIGHTING MEASURES Listed es Carcinogen or Potential Carcinogen:No. Fire and Explosion Hazard Date HANDLING AND STORAGE FIRST AID MEASURES Flesh Point(Method Used): Not flammable. Special Precautions Emergency and First Ald Procedures Extinguishing Media: Use conventional fire extinguisher Precautions to be Taken In Handling and Storing:Store in tight Ingestion: May be harmful if swallowed.Call a physician immediately. Spoclal Firs Flghling Procoduree: Nonc container Skin Contact:May be absorbed through skin. If on skin: Wash skin Unusual Fire and Explosion Hazards: None EXPOSURE CONTROLS/PERSONAL wnh soap and water. Eye Contact:Can cause eye irritation.If in eyes:Flush eyes with plenty ACCIDENTAL RELEASE MEASURES PROTECTION of water for at least 15 minutes. Contact physician immediately. Steps to be Taken In Case Materiel Is Released or Spilled:Contain Special Protection Information Inhalation: May be harmful if inhaled. Remove to fresh air. all spills. Respiratory Protection(Specify Type): N/A �.� .• r. :: 1 �t � Form APProved U.S. DEPARTMENT OF LABOR OMB No. 44•R1387 October, 1992 �cupational Safety and Health Admini, -`lion MATERIAL SAFETY DATA SHEET Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917) ALLERDERM/VIRBAC IN I P 0 BOX 162059 EMERGENCY TELEPHONE NO. FORT WORTH TX 76161 800-338-3659 s CH MICAL N E AND SYNONYMS TRADE NAME AND SYNONYMS IIConazoye Dermazole Shampoo CHEMICAL FAMILY FORMULA Oxidizer 2% Miconazole SECTION 11 - HAZARDOUS INGREDIENTS PAINTS,PRESERVATIVES,III SOLVENTS % T�V ALLOYS AND METALLIC COATINGS % TLV (Units) PIGMENTS None VA BASE METAL CATALYST None ALLOYS VEHICLE Water 55 N/A METALLIC COATINGS N/A FILLER MAL SOLVENTS PLUS None NG OR CORE FLUX ADDITIVES OTHERS NIA OTHERS Miconazole HAZARDOUS MIXTURES OF OTHER LIQUIDS,SOLIDS,OR GASES % (Units) N/A SECTION III - PHYSICAL DATA BOILING POINT(OF.) N/A SPECIFIC GRAVITY(H20-1) 1.025 VAPOR PRESSURE(mm Hy.) N/A BY VOLUME (xATILE N VAPOR DENSITY (AIR-1) N/A EVAPORATION RAT N/A f SOLUBILITY IN WATER I miscible APPEARANCE AND ODOR Milky liquid with mild odor SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) Not flammable FLAMMABLE LIMITS Lel Uel EXTINGUISHING MEDIA Conventional extinguisher SPECIAL FIRE FIGHTING PROCEDURES None UNUSUAL FIRE AND EXPLOSION H ARDS PAGE (1) (Continued on reverse side) Form OSHA-20 Rev. May 72 T�a`, SECTION V - HEALTH HAZARD D..,TA TIA&fSHOLD LIMIT VALUE EFFECTS OF OVEREXPOSURE None known E RGENCY AND FIRST IO PROC UR ` ontact appropriate meca? attention -SECTION VI - REACTIVITY DATA STABILITY UNSTABLE CONDITIONS TO AVOID Material is stable STABLE X INR8q ATABILITY (Materials to avoid) HA ARO U DECPOSITION PRODUCTS Gl�hen �leSa OMted to decomposition may emit toxic fumes CONDITIONS TO AVOID HAZARDOUS MAY OCCUR POLYMERIZATION WILL NOT OCCUR X 1K�ggfryy !!�� SECTION VII - SPILL OR LEAK PROCEDURES STEOIItain Sp1111 andSsweepRupL IS RELEASED OR SPILLED W TE DISPOSAL METHOD bs ose accordin to local environmental SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specify type) Self-contained breathing apparatus when fightinv fir VENTILATION LOCAL EXHAUST SPECIAL MECHANICAL(General) OTHER PROTECTIVE GLOVES EYE PROTECTION Rubber Go les O HER PR N PROTECTIVE EQUIPMET Mash exposed skin 55��EE 7p g I� I� SECTION IX - SPECIAL PRECAUTIONS PJ Lore10iII L1ght co tainerSLING AND STORING °XqbjSRSA`�a°c�'Swith eyes, wash exposed skin PAGE (2) Form OSMA-20 GPO 93D.541 Rev.May 72 r '' r , 101 3M General Off Ices EXPOSURE CONTROLS/PERSONAL c FIGHTING MEASURES PROTECTION Fire and Explosion Hazard Data 3M Center No data provided. Flash Point: NA PHYSICAL AND CHEMICAL PROPERTIES Flammable Limits: LEL-NA;UEL-NA St. Paul, MN 55144-1000 AutoignitionTemperature: N/D Physical Data Extinguishing Media:NA Information # (612) 733-1110 Boiling Point:212.00 F Special Fire Fighting Proceduree:NA The information on this Data Sheet represents our current and best Vapor Pressure: 17(X 0 mm fig Unusual Fire and Explosion Hazards: NA opinion as to the proper use in handlingof this product under normal Vapor Density: 060 Air= I P P � P Evaporation Rate: N/D NFPA-Hazard-Codes: Health-I;Fire-0;Reactivity-0 conditions Any use of the product which is not in conformance with this Unusual Reaction Hazard: None Data Sheet,or which involves using the product in combination with any Solubility In Water: complete other product or any other process is the responsibilty of the user. Sp.Gravity: 1 240 Water= I Percent Volatile:85.00% ACCIDENTAL RELEASE MEASURES Volatile Organics: N/D Spill Response:Observe precautions from other sections Ventilate 1425 Vellerinn.,ry,X-Ray Film Manual, Voc Less H2O A Exempt Solvent' N/D area.Cover with absorbant material.Collect spilled material. Place in a PH: 1060 U.S.D.O.T.•approved metal container and seal.Clean up residue with peveloper Replenleher Viscosity:N/D water,with Federal,Slate and local effluent laws taking precedence MSDS No: MS99748 March 1989 Malting Point: N/D CHEMICAL PRODUCT IDENTIFICATION Appearance and Odor: Liquid,colorless,odorless HANDLING AND STORAGE Precautionary Information Product: 1425 Veterinary X•Ray Film Manual Developer Replenisher STABILITY AND REACTIVITY Other Precautionary Information:Avoid skin and eye contact.Do not 3M I.D.Number: 70-2004-1710.6 Reactivity Data ingest. Use in well ventilated area. Keep out of reach of children,avoid COMPOSITION/INFORMATION ON INGREDIENTS Stability:Stable unnecessary personal contact and wash thoroughly after handling Ingredient Incompatibility-Materials to Avoid: Mineral Acids Exposure Limits INGREDIENT C.A.S.NO, PERCENT Hazardous Polymerizatlon: Will not occur Ingredients Value Unit Type AUTH Abbreviations: N/D-Not Determined N/A-Not Applicable Ammonium Thiosulfatc None None None None Sodium Sulfite 7757-83-7 150-90.0 Hazardous Decomposition Products: Sulfur Dioxide P Sodium Sulfite None None None None Hydroquinone 123-31.9 5.0-10.0 Acetic Acid 10 ppm TWA ACGIH Potassium Hydroxide 1310-58.3 I.0•5.0 ECOLOGICAL INFORMATION Acetic Acid 25 mg m3 TWA ACGIH 'Sodium Carbonate 497-19.8 2.0-50 Environmental Information Environmental Data: ND Acetic Acid 15 ppm STEL ACGIH HAZARD IDENTIFICATION SARA Hazard Class: Fire Hazard-No;Pressure-No;Reactivity No; Acetic Acid 37 mg/m' STEL ACGIH Health Hazard Data Acute-Yes;Chronic-Yes Acetic Acid 10 ppm TWA OSHA Eye Contact: Causes eye irritation on contact. DISPOSAL CONSIDERATIONS Acetic Acid 25 mg/ma TWA OSHA Skin Contact: May cause skin irritation. Sodium Telraborate 5 m m� TWA ACGIH Inhalation: No adverse health effects expected Recommended Disposal:Since regulations vary, consult applicable €/ If Swallowed: May cause irritation and/or burns to GI tract,mouth. regulations or authorities before disposal. Neutralize with sulfamic acid Sodium Telraborate 10 mg/m'[ TWA OSHA or vinegar. Flush to sewer with large amounts of water with Federal, FIRST AID MEASURES Slate and local effluent laws taking precedence. Aluminum Sulfate 2 as Al mg/m TWA ACGIH Aluminum Sulfate 2 as Al mgjin'[ TWA OSHA Suggested First Aid REGULATORY INFORMATION Eye Contact: Immediately Bush eyes with plenty of water.Call a physi- This product contains the following toxic chemical or chemicals subject EXPOSURE CONTROLS/PERSONAL `tan to the reporting requirements of section 313 of Tille III of the superfund Skin Contact: Wash affected area with plenty of soap and water amendments and Reauthorization Act of 1986 and 40 CFR Pan 372: PROTECTION Inhalation: NA Hydroquinone No data provided. If Swallowed: Do not induce vomiting If person is conscious give one to two glasses of water. Immediately call a physician. PHYSICAL AND CHEMICAL PROPERTIES FIRE FIGHTING MEASURES 1426 Veterinary X-Ray Film Manual Fixer Physical Data Fire and Explosion Hazard Data Replenisher Bolling Point:21200 F Flash Paint: N/A Vapor Pressure: 17.0000 min Hg Flammable Urnits: LEL-N/A;UEL•N/A MSDS No: MS199OR Mafch 1989 Vapor Density:060 Air=I Autolgnlllon Temperature: N/D Evaporation Rate: N/A Extinguishing Media: NA CHEMICAL PRODUCT IDENTIFICATION Solubility In Water; Complete Special Fire Fighting Procedures:NA Product: 1426 Veterinary X-Ray Film Manual Fixer Replenisher Sp,Gravity: 1,270(Water= 1) Unusual Fire and Explosion Hazards: NA 3M I.D.Number: 70-2004.1711.4 Percent Volatile;46.00 17, NFPA•Hazard-Codes: Health-2;Fire-0;Reactivity-0 COMPOSITION/INFORMATION ON INGREDIENTS Volatile Organics: N/D Unusual Reaction Hazard: None Voc Less H2O&Exempt Solvent: N,'D ACCIDENTAL RELEASE MEASURES INGREDIENT C.A.S.NO. PERCENT pH:4.85 Vlscoslty: N/D Spill Response:Observe precautions from other sections, Cover with Ammonium Thiosulfate 7783.18-H 30.0-50.0 absorbent material. Collect spilled material and flush area with water,if Melling Point: N/D Sodium Sulfite 7757-83.7 4.0-6.0 necessary Place in a U S.DOT approved container and seal Neutralize Appearance and Odor: Liquid,colorless,acetic acid odor with sulfamic acid or vinegar and flush with large volumes of water to Acetic Acid 64-19.7 3.0 sewer Sodium Tetraborate 1303.96-4 1.0.3.0 STABILITY AND REACTIVITY HANDLING AND STORAGE Aluminum Sulfate 10043-01.3 1.0.2.0 Reactivity Dale Precautionary Information Stability:Stable Other Precautionary Information: Wear protective clothing and imper• HAZARD IDENTIFICATION Incompatibility-Materials to Avoid:Strong Alkalis vious gloves as necessary. Avoid eye and skin contact. Do not ingest. Health Hazard Data Hazardous Polymerization: Will not occur Complaints of burning or irritation of the eyes and mucous membranes as Eye Contact:Causes severe eye irritation. May cause permanent dam- Hazardous Decomposition Products:Ammonia well as the development ofskin irritation or dermatitis with exposure.The age. routine use of a non-alkaline hand cleaner will minimize the possibility Skin Contact: May cause skin irritation upon contact. Mildly acidic. ECOLOGICAL INFORMATION of allergic skin reaction Inhalation: large amounts may cause severe irritation. Exposure Limits If Swallowed:Acid nature will cause minor burns of GI tract and mouth. EnVlronmental Information Ingredients Value Unit Type AUTH Environmental Data:NA Sodium Sulfite None None None None FIRST AID MEASURES SARA Hazard Class:Fire Hazard-No;Pressure.No;Reactivity-No; Eydroqutnone 2 mg/m3 TWA ACGIH Suggested First Aid Acute-Yes;Chronic-No Eye Contact: Immediately flush eyes with plenty of water.Call a physi- H:droquinone 2 mg/m' TWA OSHA elan. DISPOSAL CONSIDERATIONS Pot[ssium Hydroxide mg/ma CEIL ACGIH Skin Contest: Wash with plenty of water Recommended Disposal: Because regulations vary,consult applicable Potssium Hydroxide .' mg/m' CEIL OSHA Inhalation: Remove person to fresh air.Call a physician. regulations or authorities before disposal. Dilute with large amounts of Sodtvm Carbonate None None None None If Swallowed:Give one to two glasses of water. Immediately call a water and flush to sewer(Federal,State and local effluent laws take physician. precedence). L- 12 American Veterinary Distributors Association L050:384 mg/Kg intramuscular-rat SECTION VI-HEALTH HAZARD DATA Diazepam>r Signs 8 Symptoms of Overexposure:Eye,skin,and/or res. Primary Routes of Exposure: Inhalation,ingestion,and Skin piratory tract irritation,dizziness vertigo,linnnus,roaring in the Absorption. Continued. ears,hearing loss,numbness,skin tingling,muscle twitching, Chemical Listing as Carcinogen: and convulsions. Eyes: Safely goggles. enc Emer &First Aid Procedures: National Toxicology Program-No. � Emergency Gloves: Disposable surgical latex gloves. Inhalation.Remove to fresh air Remove contaminated /ARC Monographs•No. clothing,Seek medical attention OSHA-No. Clothing: Disposable protective apparel (protect exposed skin). Ingestion-Flush mouth out with water. Seek medical atten- Toxicity Data: tion. Signs III,Symptoms of Overexposure: Acute—Eye,skin, SECTION Vlll-STORAGE AND HANDLING DATA Skin Contact-Remove contaminated clothing. Flush area and/or respiratory tract irritation. Impaired blood coagulation. Precautions:As a general rule when handling pharmaceutical with water. Seek medical attention. Chronic —Possible hypsrsensi6zalion. Products avoid all contact and inhalation of dust,fumes,mists, andror vapors associated with the product. Eye Contact-Flush with water. Seek medical attention. Emergency 6 First Aid Procedures: SECTION/X•ACCIDENTAL SPILL PROCEDURES/WASTE SECTION VII-PROTECTIVE EQUIPMENT DATA Inhalation-Remove person to fresh air. Remove conlami- D/SPOSAL DATA Ventilation: Local exhaust recommended nated clothing.Seek medical attention, es ContainmenVCleanup:Wear recommended personal protac• Respiratory: NI Ingestion-Flush mouth out with water.Seek medical attention P Y� OSH approved respirator five equipment.Vacuum spillage with a vacuum cleaner having Eyes: Safely gaggles Skin Contact-Remove contaminated clothing, Flush area a high efficiency particulate(HEPA)Idler,or absorb liquid with with water. Seek medical attention, Paper towels. Wipe workingsurfaces to dryness,then wash Gloves: Disposable surgical latex gloves ry Eye Contact-Flush with water. Seek medical attention. with soap and water. Clothing: Disposable protective clothing (protect exposed SECTION VI/-PROTECTIVE EQUIPMENT DATA Waste Disposal:Though not EPA regulated,waste should be skin) SECTION Ventilation: Local exhaust recommended VIII-STORAGE AND HANDLING DATA disposed of in accordance with federal,state and local ragula- Respiratory: tions. Precautions: As a general rule,when handling pharmaceuti- P ry' NIOSH approved respirator cal products avoid all contact and inhalation of dust,fumes, Eyes: Safety goggles mists,and/or vapor associated with the product. Gloves: Disposable surgical latex gloves SECTION IX-ACCIDENTAL SPILL PROCEDURES/WASTE Clothing: Disposable protective apparel (protect exposed GENTAMICIN-SULFATE DISPOSAL DATA skin). AVDA MSDS No.: MS2200 Containment/Cleanup:Wear recommended personal protec- SECTION Vlll-STORAGE AND HANDLING DATA LyphoMed, Inc., 10401 W. Touhy Avenue, Rosemont, IL tive equipment. Vacuum spillage with a vacuum cleaner having Precautions: As a general rule,when handling articulate(HEPA)filter, pharmaceuti- a high efficiency p ) ter,or absorb liquid with 60018 Emergency telephone: 312-450.7569 (weekdays B cal products avoid all contact and inhalation of dust,fumes, a.m.•S p.m.);other limes:312.450.7500. paper towels. Wipe working surfaces to dryness,then wash mists,andtor vapor associated with the product. with soap and water- Dale of MSDS: February 22,1988 Waste Disposal:THough not EPA regulated,waste should be SECTION IX-ACCIDENTAL SPILL PROCEDURES/WASTE SECTION I-IDENTIFICATION disposed of in accordanco with federal,slate,and local regula- DISPOSAL DATA Common Name: Gentamicin Sulfate tions, Containment/Cleanup:Wearrecommendedpersonalprotec- five equipment.Vacuum spillage with a vacuum cleaner having Chemical Name: Gentamicin Sulfate a high efficiency particulate(HEPA)filter,or absorb liquid with Chemical Family: Aminoglycoside;Antibiotic,Antibacterial paper towels. Wipe working surfaces to dryness,then wash Chemlpal Formula: Cz,H'°Ns Or Hz cza SO; Hu Ns or.Hx So,; HEPARIN SODIUM AVDA MSDS No.: MSP201 with soap and water. C„Hs N O.H S0,+ > z Waste Disposal:Though not EPA regulated,waste should be CAS No.: 1405-41-0 LyphoMed, Inc., 10401 W. Touhy Avenue, Rosemont, IL disposed of in accordance with federal,state,and local regula- 60018. Emergency telephone: 312.450-7569 (weekdays 8 lions. RTECS No.: LY2625000 a.m.-5 p.m.);other limos:312 450.7500, SECTIONII-HAZARDOUSINGREDIENTS/ACTIVEINGREDI- Dale of MSDS: February 24,1988 ENTS - SECTION I-IDENTIFICATION Component OSHA PEL ACGIH TLV Common Name: Heparin Sodium STERILE WATER FOR INJECTION Gentamicin Chemical Name: Heparin Sodium Sulfate Not established Not established Chemical Family: Anlicoagulant AVDA MSDS No.: MS2202 SECTION III-PHYSICAL&CHEMICAL CHARACTERISTICS Chemical Formula: LyphoMed, Inc., 10401 W. Touhy Avenue, Rosemont, IL Description: Gentamicin Sulfate Injection,USP,is a sterile 60018. Emergency telephone: 312-450.7569 (weekdays 8 solution of Gentamicin Sulfate in Water for Injection for paren• CAS No.: 9041-OB-1 a.m.-5 p.m.);other Hines:312-450-7500. total use. (pH 3.0-5.5) RTECS No.: N/A Date of MSDS: March 1,1988 Appearance and Odor: Clear,colorless solution;odorless SECTIONII-HAZARDOUS INGREDIENTS/ACTIVEINGREDI- SECTION/-IDENTIFICATION BoilingPoint: N/A ENTS Common Name: Sterile water for injection SolubilityIn Water: Soluble Component OSHA PEL ACGIH TLV Chemical Name: N/A Vapor Pressure: N/A Heparin Sodium Not established Not established Chemical Family: Water Vapor Density: NIA SECTION Ill-PHYSICAL&CHEMICAL CHARACTERISTICS P Y� Description: He Chemical Formula: Hz0 SECTION IV-FIRE&EXPLOSION DATA P pann Sodium Injection, USP, is a sterile CAS No.: None solution of Heparin Sodium derived from animal tissue(porcine Flash Point: WA intestinal mucosa or beef lung)for use as an antivosgulanl in RTECS No.: NIA Extinguisher Media: Water spray,dry chemical,carbon diox- water for injection. 11 has a pH of 5.0.7.5 and is administered SECTIONII-HAZARDOUS INGREDIENTS/ACTIVEINGREDI- ide,or loam as appropriato for surrounding lire and materials. by intravenous or deop subcutaneous routes. Heparin Lock ENTS Flammable Limits: N/A Flush Solution,USP is a sterile solution of Heparin Sodium There are no hazardous ingredients in this product. (porcine),with water for sodium chloride to make l tionnlonic is in- SECTION Ill-PHYSICAL&CHEMICAL CHARACTERISTICS Unusual Fire and Explosion Hazards: Emits toxic fumes. with blood,in water for Injection(pH 5.0•7.5).Solution U in- Hazardous Decomposition Products: Gentamicin sulfate landed for maintenace of palency of intravenous injection de- Description: Sterile water for injection,USP emits toxic fumes when healed to decomposition. vices only and are not to be used for anticoagulant therapy. Appearance and Odor: Clear,colorless liquid,odorless Special Fire Fighting Procedures: Firelighters should use Appearance and Odor: Clear,colorless to slightly straw Bolling Point: 100°C seat-cemained breathing apparatus and protective clothing. colored solution;odorless SECTION V-REACTIVITY DATA Boiling Point: N/A Solubility In deter: N/A Stability: Stable Solubility in Water: Soluble Vapor Pressure: 760mm @ 25,C Conditions/Materials to Avoid: None, Vapor Pressure: N/A Vapor Density: N/A Hazardous Polymerization: Will not occur Vapor Density: N/A SECTION IV-FIRE&EXPLOSION DATA SECTION VI-HEALTH HAZARD DATA SECTION IV-FIRE&EXPLOSION DATA Flash Point: N/A Primary Routes of Exposure: Inhalation,Ingestion, Flash Point: N/A Extinguisher Media: WA and Skin absorption. Extinguisher Media: Water spray,carbon dioxide,dry chemi- Flammable Limits: N/A Chemical Listing as Carcinogen: cal,or foam as appropriate for surrounding fire and materials. National Toxicology Program-NO Flammable Limits: N/A Unusual Fire end Explosion Hazards: None IARC Monographs-NO Unusual Fire and Explosion Hazards: Emits toxic turn Hazardous Decomposition Products: None es. Special Fire Fighting Procedures: None OSHA-NO Hazardous Decomposition Products:Heparin Sodium emits SECTION V-REACTIVITY DATA Toxicity Data: toxic fumes when heated to decomposition. LD50:565 mg/Kg intraperitoneal-mouse; Special Fire Fighting Procedures: Firefighters should use Stability: Stable self contained breathing apparatus and protective clothing, Conditions/Materiels to Avoid: N/A LD50:50 mg/Kg intravenous-mouse; SECTION V-REACTIVITY DATA Hazardous Polymerization: Will not occur LD50:283 mg/Kg intramuscular-mouse; Stablllt LD50:630 ng/Kg intraperitoneal-rat; y' Stable SECTION VI-HEALTH HAZARD DATA Conditions/Materials to Avoid: None Primary Routes o1 Exposure: Inhalation,Ingestion,and Skin LD50:108 mg/Kg intravenous-rat; Hazardous Polymerization: Will net occur absorption. :: -.. - ._ �.ti �� . �� I I I American Veterinary Distributors Association -^ R -3 Special Fire Fighting Procedures: Firelighters should be SECTION It-HAZARDOUS INGREDIENTS SECTION Ill•PHYSICAL DATA equipped with sell-contained breathing apparatus. Hazardous Ingredients % Bolling Point ff): 760 mm Hg,Degrees C--WA Unusual Fir(sillUploslon Hazards:Harsh Iodine fumes are N.N-diethyl•4-melhyl•l-piperazinecarboxamide, Vapor Pressure(mm Hg): 40.000040 mm Hg(carbaryl) emitted when'producl is heated to greater than 1761F(WC). citrate min 99% r SECTIONV-REACTIV/TYDATA CAS-No:1642.54-2 Vapor Density(AIR-1): N/A Stability:Stable SECTION Ill-PHYSICAL DATA pH: 4.0-6.5(5g/100ml water) Conditions to Avoid:N/A Solubility In Water: 55% Solubility In Water: Dispersible Incompatibility(Materials to Avoid):The elemental Iodine is Appearance and Odor:White odorless crystalline powder,mp Appearance and Odor:White to light tan powder,mild pheno- corroslve to some metals(e.g.Iron)but is not corrosive to slain- 137°C lic odor less steel as found In healthcare facilities. Percent,Volatile by Volume(%): 0 Specific Gravity(H2O-1): N/A Hazardous Decomposition or Byproducts:N/A SECTION IV-FIRE AND EXPLOSION HAZARD DATA SECTION IV-FIRE AND EXPLOSION HAZARD DATA Hazardous Polymerization: Will not occur Flesh Point(Method Used): 150°C(Closed cup) Flash Point(Method Used): 193°C 380°F Carbaryl Cleveland Conditions to Avoid:WA Flammable Limits:WA Open Cup SECTION VI-HEALTH HAZARD DATA Extinguishing Media: Water Flammable Limits:Let-0.02;Uel- Not known ExtinRouta(a)of Entry:Skin,Ingestion by accidental or intentional SECTION V-HEALTH HAZARD DATA small fires. U Media: Use carbon dioxide m(a or dry chemical for small tires. Use water spray or loam(alcohol, polymer, or misuse. Threshold Limit Value: Not set.LD,0,1400 rii(oral,rat) ordinary)for large fires. Health Hazards(Acute and Chronic):Acute Oral Toxicity:Rats Effects of Overexposure:The powder can be Irritant for eyes Special Firs Fighting Procedures: LD50®24 hours:750 mg available Iodine/kg. Extrapolation:A and skin. Avoid breathing dust of the powder 150#adult would have to drink one gallon of product to reach 1)Provide for the protection of employees and residents: lethal does 50. Overexposure may occur If excessive amounts Emergency and First Aid Procedures; If powder has gotten a.Evacuate residents who are downwind of fire. are absorbed through broken skin,burns,or deep wounds. Into eyes,Immediately wash out with water for several minutes. b.Prevent unauthorized entry to fire area. Signs and Symptoms o}Exposure:Skin:It Irritation,redness, Remove soaked clothing immediately and wash affected skin pain or swellingSymptoms occurs,f Exposure: is or Increases,disco,trednInue use with plenty of water. c. Persons who may have been exposed to contaminated SECTION VI-REACTIVITY DATA smoke should be examined by a physician and treated appro- and consult physician. Operand Iodine Scrub should not be priately. used by personnel or patients with skin sensitivity or allergy to Stability: Stable Iodine. d. Dike area to prevent runoff and contamination of water Hazardous Polymerization: Will not occur sources. Medical Conditions Generally Aggravated by Exposure: SECTION VII-SPILL OR LEAK PROCEDURES Overexposure symptoms reflect iodine overexposure. Severe 2)Notify local authorities that firemen should: hypematremia and acidosis have been reported as well as In- Steps to be Taken In Case Material Is Released or Spilled: creased serum Iodine levels. Sweep up spilled powder and remove to a safe place.If powder a.Wear protective clothing and use self-contained breath- has entered a water course or sewer or contaminated soil or ing apparatus. Emergency grid Flral Aid Procedures: Ingestion: If swel- lowed,do not induce vomiting.Drink large quantities of water or vegetation-advice police. b.Be Immediately relieved from duty,it exposed to contami- mllk and call a physician immediately. Waste Disposal Method: Incinerate noted smoke,and checked for symptoms of poisoning. These Eyes:Flush with water for 15 minutes and seek medical atten- SECTION Vlll-SPECIAL PROTECTION INFORMATION should not be mistaken for heat exhaustion or smoke Inhalation. See Health Hazard Data for symptoms of poisoning,first aid Wn it Irritation occurs or persists. Respiratory Protection: Dust mask procedures and notes to physician. SECTION VII-PRECAUTIONS FOR SAFE HANDLING AND Ventilation:Local exhaust-Yes;Mechanical(General)-Ac- Unusual Fire and Explosion Hazards: Thermal decomposi- USE ceptable tlon products may be hazardous. These may include oxides of Steps to be Taken In Come Malarial Is Released or Spilled: Protective Gloves: Plastic or rubber gloves nitrogen,carbon and sulfur, and methyl Isocyanale. Avoid Large Spills:(55 gallon drums) Spills should be contained and Eye Protection: Goggles giving complete protection to eyes, dispersion of dust In air to reduce potential explosion hazard. taken up with absorbent material. Do not discharge Into water- SECTION IX SPECIAL PRECAUTIONS Use electrical equipment suitable for atmospheres that may - ways or sewer systems. Small spills: Take up with absorbent contain combusubte ducts, material or flush with water to sewer system. None listed SECTION V-HEALTH HAZARD DATA Waste Disposal Method:Spilled material and empty contain- General Information:Illness may occur rapidly afleroverexpo- ers must be disposed of In accordance with Institutional,local, sure to this product. The principle hazard of this product is re- slate,and federal regulations. versible cholinesterase inhibition.Symptoms are dose depend- Precautions to be Taken In Handling and Storing:Avoid ent,rapid In onset and reversible in time. The main symptoms storing at excessive heat(greater than 104°F). Manufacturer are listed below. Other Precautions:Contact manufacturer for disposition of ex- Existing Medical Conditions Aggravated By Exposure:Skin pared product. Rhone-Poulenc AG Company Irritation may be aggravated in persons with existing skin SECTION Vlll-CONTROL MEASURES lesions. Breathing vapors,dust or sprays(mists)may aggra- Resplralory Protection: For hospital and professional use: P.O. Box 12014 vate asthma and inflammatory or fibrotic pulmonary disease. Not required. For industrial use: II product is misted during Overexposure may aggravate existing chronic cardiovascular manufacture, employees should wear dusVis m respirators T.W. Alexander Drive or respiratory disease leading to respiratory difficulty,pulmo- W nary edema and cyanosis unless adequate ventilation Is provided. . Research Triangle Park, NC 27709 Toxicology Data: Ventilation:Local exhaust-Acceptable;Mechanical(General) -Acceptable;Special-N/A;Other-N/A Emergency Telephone: Oral LD50(rats): 281 ri body weight Protective Gloves: WA (800) 334-7577 Dermal LD50(rabbits): >2,000 mi body weight Eye Protection:Avoid contact with eyes.Protective equipment Inhalation LC50(rats-4 hour exposure): No information Is not necessary. available Other Protective Equipment:N/A Skin effects(rabbits): Minimal Irritation Work/Hygenic Practices: Indications: A microbicidal SEVIN BRAND 80S CARBARYL INSEC- Eye effects(rabbits): Slight Irritation cleanser for pre-and postoperative scrubbing or washing by TIC/DE AVDA MSDS No.:MS2583 Effects of Overexposure: Carbaryl,when administered by hospital operating personnel and for general use In the physi• various routes,at doses toxic to the maternal animals,has been clan's office. Rhone-Poulenc AG Company,P.O.Box 12014,T.W.Alexan- shown to produce developmental toxicity a number of species. der Drive, Research Triangle Park, NC 27709 Emergency Carbaryl produces no teratogenid effect In the absence of Telephone: 800 334-7577 or Cherti 800 424.9300 maternal toxicity. In addition, the balance of the evidence Dale of MSDS: August 20,1987 supports the conclusion that the active Ingredient and its pos- Manulaclurer slble metabolites do not represent a quantifiable mutlgenic risk SECTION I-IDENTIFICATION to humans. Carcinogenicity studies in animals have been Rexolln Chemicals AB Trade Name/Synonyms: Carbaryl shown to be negative. Chemical Name/Synonyms: 1-Naphthyl N-methylcarbamate Swallowing: May be lalal II swallowed. (See Toxicology Box 622, 251 06 Chemical Family:CAS#:63-25.2 CAS Name:1-Naphthyl N- Date.) May lead to rapid onset of nausea,vomiting,abdominal melhylcarbamale pain,diarrhea,pinpoint pupils,blurred vision,proluss sweating, Helsin bon Sweden salivation,tremor,muscly twitching and temporary paralysis. In 9 g� Formula:C,,H„NO2 severe poisoning respiratory depression and convulsions may SECTION If-HAZARDOUS INGREDIENTS occur. Hazardous Ingredients Weight% Skin Absorption: Harmful it absorbed through skin. (See D/ETHYLCARBAMAZINE CITRATE Carbaryl,(1-Naphthyl Toxicology Data.) Symptoms as desctibed above for swallow- N-melhylcarbamale) 80 Ing. AVDA MSDS No.:MS2579 Other Ingredients (Trade Secret) Inhalation: No Information available,but it Is expected to be Rexolln Chemicals AB,Box 622,251 06,Helsingborg,Swe- harmful If inhaled,with symptoms described above. May be den Allowable Exposure Limits: Irritating to respiratory tract. SECTION 1-,IDENTIFICATION Carbaryl:5 mg/cubic meter of air TLV-TWA(ACGIH)and PEL- Eyes: Causes eye Irritation,seen as tearing and redness. TWA(OSHA) (See Toxicology Data.) Vapors or sprays(mists)may be irritat- Trade HamelSynonyms: Dielhylcarbamazine Ciliate Ingredient: Nuisance dust ing to the eyes. Chemical Name/Synonyms: N,N-diethy-4methyl-l-piperazl- 5 mg/cubic meter air respirable dust(ACGIH) Effects of Repealed Overexposure: This product causes re- necarboxamide/cltrale verslble cholinesterase Inhibition. Repealed overexposure Chemical Family: Plperazine derivative 10 mg/cubic meter air total dust(ACGIH) may cause more severe choflnesterase inhibition with the signs Formula:C,s H,,N,O, C,H,Or 5 mg/cubic meter air respirable dust(OSHA) and symptoms described for single overexposures being more 15 mg/cubic meter air total dust(OSHA) pronounced. - - --- 629 STABILITY AND REACTIVITY PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL AND CHEMICAL PROPERTIES Reactivity Data Physical Data Physical Data Stability:Stable under ordinary conditions of use and storage Appearance: Red liquid Appearance; Dark blue liquid. Hazardous Decomposition: Incomplete combustion may produce car. Odor:None. Pow P Y P Odor:None. t'I, bon dioxide and/or carbon monoxide. Solubility In Water: Incomplete Solubility In Water: Incomplete. Hazardous Polymerization: Will not occur. Bolling Point:No information found. Bolling Point:No information found. Incompatibilities:Avoid contact with oxidizers.Avoid sources of igni. Melting Point: No information found. Matting Point: No information found. tion.such as heat,sparks and flames Specific Gravity:No information found. Specific Gravity:No information found. Vapor Density(alr=1): No information found. DISPOSAL CONSIDERATIONS Vapor Pressure(mm Hg):No information found Vapor Density(air=1):No information found. Waste Disposal: Ensure compliance with local,state and federal regu- Evaporation Rate(butyl acelate=l): No information found. Vapor Pressure(mm Hg):No information found lations. Percent Volatile by Volume(%):No information found. Evaporation Rate(butyl scstate=l): No information found. Percent Volatile by Volume(%): No information found. TRANSPORT INFORMATION STABILITY AND REACTIVITY DOT Hazard Class: Flammable Liquid Reactivity Data STABILITY AND REACTIVITY Stability:Stable under ordinary conditions of use and storage. Reactivity Data Hazardous Decomposition:No information found Stability:Stable under ordinary conditions of use and storage Hazardous Polymerization:Will not occur Hazardous Decomposition:No information found. Dip Quick Stain Solution#2 (Eosin) Incompatibilities:No incompatability data found Hazardous Polymerization: Will not occur. MSDS No: MS8532.N October 1991 DISPOSAL CONSIDERATIONS Incompatibilities:No incompalability data found. Waste Disposal: Ensure compliance with local,state and federal regu- CHEMICAL PRODUCT IDENTIFICATION lotions. DISPOSAL CONSIDERATIONS Waste Disposal: Ensure compliance with local,state and federal regu. Identification TRANSPORT INFORMATION Product Name: Dip Quick Stain Solution N 2(Eosin) lotions DOT Hazard Class:Not regulated. COMPOSITION/INFORMATION ON INGREDIENTS TRANSPORT INFORMATION Ingredients: Eosin;Buffer Solution;Sodium Azide,0.01% Dip Quick Stain Solution # 3 (Thiazine) DOT Hazard Class:Not regulated. HAZARD IDENTIFICATION MSDS No: MS8531.N October 1991 Health Hazard Data CHEMICAL PRODUCT IDENTIFICATION Immersion Oil (Cargille's Type "A") Exposure/Hearth Effects: Identification Inhalation:No special precaution required. Product Name: Dip Quick Stain Solution I i(Thiazine) MSDS No: MS8219.SGM October 1991 Ingestion: Poisonous! Maybe fatal if swallowed. Skin Contact: May cause irritation Will stain skin and clothing. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL PRODUCT IDENTIFICATION Eye Contact: May cause irritation Ingredients:Thiazine Dye Mixture;Buffer Solution Identification Precautionary Measures: POISONOUS! HARMFUL IF SWAL- HAZARD Product Name: Immersion Oil(Cargille's Type;4) D ID LOWED. As part of good industrialipersonal hygiene and safety Health DID Data procedure,avoid all unnecessary exposure to the chemical substance and COMPOSITION/INFORMATION ON INGREDIENTS ensure prompt removal from skin,eyes and clothing(will stain skin and Exposure/Health Effects: Ingredients:Immersion Oil clothing) Inhalation: No special precaution required WARNING:This reagent contains sodium azide.Sodium azide may react Ingestion: May be harmful if swallowed. HAZARD IDENTIFICATION with lead and copper plumbing to form highly explosive metal azides. If Skin Contact: May cause irritation. Will stain skin and clothing. discarded into sink,flush with a large volume of water to prevent azide Eye Contact: May cause irritation Health Hazard Data buildup. Precautionary Measures:As pan of good induslriallpersonal hygiene Exposure/Hearth Effects: and safety procedure,avoid all unnecessary exposure to the chemical Inhalation:No special precaution required FIRST AID MEASURES substance and ensure prompt removal from skin,eyes and clothing(will Ingestion:Harmful if swallowed May cause irritation First Aid Procedures: stain skin and clothing) Skin Contact: May cause irritation. Inhalation:Remove to fresh air if effects occur. FIRST AID MEASURES Eye Contact:May cause irritation. Ingestion: Induce vomiting and get medical attention immediately First Aid Procedures: Skin Exposure: In case of contact,wash with mild soap and water.Get Inhalation: Remove to fresh air if effects occur FIRST AID MEASURES medical advice if irritation develops. Eye Exposure: Wash eyes with plenty of water for at least 15 minutes. Ingestion: Induce vomiting and get medical advice, First Aid Procedures If irritation develops,get medical attention Skin Exposure: In case of contact,wash with mild soap and water-Get Inhalation: Remove to fresh air if effects occur, medical advice if irritation develops. Ingestion: If swallowed,induce vomiting.Call a physician. FIRE FIGHTING MEASURES Eye Exposure: Wash eyes with plenty of water for at least 15 minutes. Skin Exposure:Wash exposed area with soap and water Get medical If irritation develops,get medical attention advice if irritation develops. Fire and Explosion Data Eye Exposure: Wash eyes with plenty of water for at least 15 minutes Flash Point: Noncombustible FIRE FIGHTING MEASURES If irritation develops,get medical attention. Fire and Explosion; Not considered to be a fire or explosion hazard. Fire and Exploslon Data Fire Extinguishing Media: Use any means suitable for extinguishing Flash Point: Noncombustible FIRE FIGHTING MEASURES surrounding fire. Fire and Explosion: Not considered to be a fire or explosion hazard, Special Information: No information found Fire Extinguishing Media: Use any means suitable for extinguishing Fire and Explosion Data surrounding fire. Flash Point:Noncombustible. ACCIDENTAL RELEASE MEASURES Special Information: No information found. Fire and Explosion:Not considered to be a fire or explosion hazard Lesk/Splll Disposal Information:Small quantities may he disposed of ACCIDENTAL RELEASE MEASURES urndinguiehing Media: Use any means suitable for extinguishing B in the sewer Large quantities should be disposed of according to local surrr ouunding fire. requirements for non-hazardous material. Leak/Spill Disposal Information:Small quantities may be disposed of Special Information: Use protective clothing and breathing equipment in the sewer, large quantities should be disposed of according to local appropriate for the surrounding fire. requirements for non-hazardous material. HANDLING AND STORAGE Precautions for Safe Handling and Use HANDLING AND STORAGE ACCIDENTAL RELEASE MEASURES Handling and Storage:Keep in a tightly closed container,stored in a Precautions for Safe Handling and Use Leak/Splll Disposal Information:Small quantities may be disposed of cool,dry,ventilated area. Handling and Storage: Keep in a tightly closed container,stored in a in the sewer. Large quantities should be disposed of according to local cool,dry,ventilated area away from sources of ignition and flame. requirements for non-hazardous material. EXPOSURE CONTROLS/PERSONAL EXPOSURE CONTROLS/PERSONAL HANDLING AND STORAGE PROTECTION PROTECTION Precautions for Sale Handling and Use Occupational Control Measures Occupational Control Measures Alrboms re Limb: No information found. Handling and Storage: Keep in a tightly closed container,stored in a �w Althorns Exposure Limits:No information found. cool,dry,ventilated area. Ventilation:General room ventilation is usually adequate. Ventilation:General room ventilation is usually adequate. Precautionary Measures:As part of good industrialipersonal hygiene Skin Protection: Wear resistant gloves. Skin Protection:Wear resistant gloves. and safety procedure,avoid all unnecessary exposure to the chemical Eye Protection: Use chemical safety goggles. Eye Protection: Use chemical safety goggles. substance and ensure prompt removal from skin,eyes and clothing. kw 54 R sr r _L Baxter S/P Diff-Quik Material Safety Data Sheet Fixativf;, ,pltion Identity(Trade Name As Used On Label) Baxter Healthcare Corporation 10224E Dadevision80Addm -1 CAS Number, P.0 Box 520672 paAugPust d1989 Minr% FL 33152-0672 CoSert. CCDEES MP -! 9TY]OS�`l S tiW Florida) Prepared By 0)-327-2616 in U S ) Note: Blank spaces are not permitted. If any item is not applicable,or no Emergency Phone Number(800)-424-9300 Telex" information is available,the space must be marked to indicate that. SECTION 1 - MATERIAL IDENTIFICATION AND INFORMATION COMPONENTS —Chemical Nama R Comnwn Names OSHA ACGIH OTHER LIMITS (Hazardous Components 1% or meter: Carcinogens 0.1% orgreater) °J(s• PEL TLY RECOMMENDED Methyl alcohol 99.99 260mg/my 260mg/rk 3 310mg/m3 STE Triarylmethane dye <0.01 none none none Non•Husrdous Ingrediefft min 100 SECTION 2 - PHYSICAL / CHEMICAL CHARACTERISTICS Boiling Specific Gravity Point 65C (H,o - 1) 0.79 Vapor Pressure Melting -90C (mm Hg and Temperature) 96 Point Vapor Density Evaporation Rate (Air - 1) 1. 11 ( - 1) 4.6 Solubility Complete water in Reactive None Appearance and Odor Clear, blue, with characteristic pungent odor. SECTION 3 - FIRE AND EXPLOSION HAZARD DATA Flash Point and I Auto-ignition Flammability Limits in LEL UEL _Method Used 11C Temperature -- Air% Volume 7.3x 36% Extinguisher Media Use alcohol foam, dry chemical or carbon dioxide. Special Fire FigMinq Procedures Firefighters should wear proper protective equipment and self-.contained breathing apparatus with full face piece operated in positive pressure mode. Unusual Fire and E: los,on Hazards p ya ors may flow along surfaces to distant ignition sources and flashbac., - — Closed containers exposed to heat may explode. 400tional F- 17 6 5 SECTION 4 • REACTIVITY.,AZARD DATA Y ITY Conditionsflame. ble ToAvoid Heat, sources of ignition,stable Incompatability (Materials to Avoid) Strona oxidizina agents. r Hazardous Detomporsition Products HAZARDOUS POLYMERIZATION Conditions g flame. ❑ May Occur To Avoid Heat, sources of ignition,ion, ® Will Not Occur SECTION 5 - HEALTH HAZARD DATA PRIMARY ROUTES Inhalation Ingestion CARCINOGEN ❑ NTP ❑ OSHA OF ENTRY Skin Absorption Not Hazardous LISTED IN ❑ [ARC Monograph E% Not Listed HEALTH HAZARDS Acute Vapors may be irritating to skin, eyes, nose and throat; inhalation may be harmful or fatal, ingestion may cause blindness. Signs and Symptoms de of Exposure Irritation of skin eyes, nose and throat, Medical Conditions Generally Ag&rzyated by Exposure EMERGENCY FIRST AID PROCEDURES-Seek medical assistance for further treatment, observation and support if necessary. Eye Contact Flush eyes with plenty of water for 15 minutes, get medical help. Skin Contact Wash skin with soap and water. Inhalation Remove to fresh air, if not breathing, give artificial respiration. Ingestion If swallowed immediately induce vomiting. SECTION 6 - CONTROL AND PROTECTIVE MEASURES Respiratory Protection Respiratory protection required if airborne concentration exceeds TI,V. At (SpecifyTO) Eye Protection Protective Gloves Rubber loves Chemical o les ❑ Spatial VENTILATION Q Local Exhaust [I Mechanical (general) TO BE USED LB Other(specify)Ventilation should be adequate to meet TLV requirements. Otter Protective Clothingand EOuipment Face shield, uniform or protective su t. Hygienic work Practices Avoid contact with skin. SECTION 7 - PRECAUTIONS FOR SAFE HANDLING AND USE / LEAK PROCEDURES Steps to be Taken If Material Use full face respirator with organic vapor cartridge. Shut off Is Spilled Or Released ignitor sources. a e up wit sari or of er non—co usti e a sor ant. Waste Disposal Incineration. Methods Precautans to be Taken Store in a cool. dry well—ventilated, flammable liquid storage area. in Handling and Stora e Other Precautions and/or Special Hazards HMIS 3 Reactive 1 Personal Protection X Rating*NFPA Health 3 Flammabili 3 Reactivi 1 Special= Rating* Health 3 FlammaDli ac) Coovri4ht 1986. Science Related Materials, Inc. All Rights Reserved. Reorder No. 2217 1 ` Crystal Violet (Gram's Stain Solution # 1) Dip Quick Stain Solution,#1 (Flxative) Jorgensen Laboratories, Inc. continued MSDS No: MS8221.SGM October 1991 MSDS No: MS8220,SGM 'October 1991 CHEMICAL PRODUCT IDENTIFICATION Identification CHEMICAL PRODUCT IDENTIFICATION ICohol: Acetone Decolorizer (Gram's Product Name:Crystal Violet(Gram's Slain Solution*1) Identification Stain Solution #3) continued COMPOSITION/INFORMATION ON INGREDIENTS Product Name: Dip Quick Stain Solution N 1(Fixative) Ingredients:Crystal Violet,Ammonium Oxalate,Reagent Alcohol COMPOSITION/INFORMATION ON INGREDIENTS FIRE FIGHTING MEASURES HAZARD IDENTIFICATION Ingredients:Methyl Alcohol(Methanol) Fire and Explosion Data Health Hazard Data Flash Point: Isopropyl Alcohol: 53'F(Tag closed cup method);Ace. Exposure/Health Effects: HAZARD IDENTIFICATION tone:-4 F. Inhalation: No special precautions required. Health Hazard Data Fire and Explosion: Flammable liquid. Vapors are heavier than air and Ingestion: Harmful if swallowed. May cause irritation of the mouth, Exposure/Health Effects: travel along the ground to an ignition source and flash back to vapor esophagus and stomach. Inhalation: Inhalation of vapors can cause drowsiness,headaches,res. Skin Contact: No adverse effects expected.Will slain skin and clothing. source. piratory irritation,fatigue,nausea,passible unconsciousness,and even Eya Contact:Can cause irritation,redness,tearing and blurred vision. asphyxiation. Fire Extinguishing Media: Use dry chemical or carbon dioxide for small Preeautiona Measures: HARMFUL IF SWALLOWED. MAY fires. Use alcohol type foam for large fires. ry Ingestion: Ingestion may result in vomiting,nausea,inebriation,blind- fires. IRRITATION. Do not gel in eyes,on skin,or clothing(will mess or central nervous system damage. Special Fire Fighting Information: Do not use ordinary foam Appli- stain skin and clothing). Wash thoroughly after handling. cation of water fog/spray will aid in keeping fire-exposed materials cool. Skin Contact:Short-term,non-repealed contact may cause moderate FIRST AID MEASURES irritation and dryness. First Aid Procedures Eye Contact:Can cause irritation,redness,tearing and blurred vision. ACCIDENTAL RELEASE MEASURES Inhalation: Remove to fresh air if effects occur. Precautionary Measures:HARMFUL IF SWALLOWED OR IN. Leak/Spill Disposal Information: Eliminate all ignition sources(heat, Ingestion: If swallowed,if conscious,give large amounts of water and HALED. MAY CAUSE IRRITATION. Do not get in eyes,on skin, flame including pilot lights,and sparks). Flush with large quantities of induce vomiting.Never give anything by mouth to an unconscious person. or clothing Avoid breathing vapor. Use with adequate ventilation water or absorb with an appropriate absorbent. Small quantities may be Get medical attention disposed of in the sewer. Skin Exposure: In case of contact,wash with mild soap and water.Get FIRST AID MEASURES medical advice if irritation develops. First Aid Procedures Eye Exposure: Wash eyes with plenty of water for at least 15 minutes. Inhalation: Remove to fresh air if effects occur. HANDLING AND STORAGE If irritation develops,get medical attention. Precautions for Safe Handling and Use Ingestion: Induce vomiting and get medical attention immediately. Precautions and Storage: Kee to a g a closed container,stored in a FIRE FIGHTING MEASURES Skin Exposure: In case of contact,wash with mild soap and water Get Handlig P tightly Fire and Explosion Data medical advice if irritation develops. coil,drv,ventilated area away from sources of ignition and flame. Flash Point:No information found. Eye Exposure:Wash eyes with plenty of water for at least IS minutes. Fire and Explosion: Alcohol content is 10%or less. If irritation develops,get medical attention. EXPOSURE CONTROLS/PERSONAL Fire Extinguishing Media: Use dry chemical,carbon dioxide or alcohol PROTECTION foam. FIRE FIGHTING MEASURES Occupational Control Measures Special Information: No information found. Fire and Explosion Data Airborne Exposure Limits: No information found ACCIDENTAL RELEASE MEASURES Flesh Point:52'F(Tag closed cup method). Ventilation: General room ventilation is usually adequate Leak/Splli Disposal Information:Small quantities may be disposed of Fire and Explosion:Flammable liquid.Vapors are heavier than air and in the sewer. Large quantities should be disposed of according to local travel along the ground to an ignition source and flash back to vapor ;kin Protection: Wear resistant gloves. requirements for non-hazardous material. source. Eye Protection: Use chemical safety goggles. Fire Extinguishing Media: Use dry chemical or carbon dioxide for small HANDLING AND STORAGE fires Use alcohol type foam for large fires. Precautions for Safe Handling and Use Special Information: Do not use ordinary foam. Application of wa• PHYSICAL AND CHEMICAL PROPERTIES Handling and Storage: Keep in a lightly closed container,stored in a tct/fog spray will aid in keeping fire-exposed materials cool. Physical Data cool,dry,ventilated area. Appearance: Clear liquid EXPOSURE CONTROLS/PERSONAL ACCIDENTAL RELEASE MEASURES Odor: Characteristic. PROTECTION LeaK/Splll Disposal Information:Eliminate all ignition sources(heat, Solubility In Water: Complete Occupational Control Measures flame including pilot lights,and sparks). Flush with large quantities of Airborne Exposure lJmlte: No information found. water or absorb with an appropriate absorbent. Small quantities may 4e ISOPROPYL ALCOHOL ACETONE disposed of in the sewer. Boiling Point 82.5'C 56'C Ventilation:General room ventilation is usually adequate. Skin Protection:Wear resistant gloves. Melting Point -58.5'C •139'F Eye Protection: Use chemical safety goggles. HANDLING AND STORAGE Specific Gravity 0.79 0.79 Precautions for Safe Handling and Use Vapor Density(air=1) 2.1 1.36 PHYSICAL AND CHEMICAL PROPERTIES Handling and Storage: Keep in a tightly closed container,stored in a Vapor Pressure(mm Hg) 33 Cu,68 F 226 Physical Data cool,dry,ventilated area away from sources of ignition and flame. Evaporation Rate(butyl 1.4 6.0 Appearance: Dark blue/purple liquid. acetate=1) Odor:Alcoholic. EXPOSURE CONTROLS/PERSONAL Solubility In water: Appreciable. PROTECTION Percent Volatile by Volume(°/r) 100% 100% Boollingg Point:No information found. Melting Point: No information found. Occupational Control Measures Specific Gravity:No information found. Airborne Exposure Umfls:No information found. STABILITY AND REACTIVITY Vapor Density(Air=1): No information found. Ventilation:General room ventilation is usually adequate. ReaetivMy Data Vapor Pressure(mm Hg): No information found. Skin Protection:Wear resistant gloves. Stability: Stable under ordinary conditions of use and storage. Evaporation Rate(Butyl Acetate=1): No information found. Eye Protection: Use chemical safety goggles. Hazardous Decomposition: Incomplete combustion may produce car. Percent Volatile by Volume(%):No information found, bon dioxide and/or carbon monoxide. STABILITY AND REACTIVITY PHYSICAL AND CHEMICAL PROPERTIES Hazardous Polymerization: Will not occur. Physical Data Reactivity Data Incompatibilities:Avoid contact with oxidizers. Avoid sources of ign• Stability:Stable under ordinary conditions of use and storage. Appearance:Clear liquid. lion,such as heat,sparks and flames. Hazardous Decomposition:No information found. Odor:Characteristic. Hazardous Polymerization: Will not occur. Solubility In Water:Complete. DISPOSAL CONSIDERATIONS Incompatibilities: No incompatibility data found. Bolling Point:64.5 C Melting Point: •144'F Waste Disposal: Ensure compliance with local,state and federal regu• DISPOSAL CONSIDERATIONS Speelflc Gravity:0.79 lauons Waste Disposal: Ensure compliance with local,state and federal re u- Po P g Vapor Density(Air=1): I.1 lations, Vapor Pressure(mm Hg):%.0 TRANSPORT INFORMATION TRANSPORT INFORMATION Evaporation Rate(Butyl Acetate=1):5.91 DOT Hazard Class: Flammable Liquid. DOT Heard Class: Not Regulated. Percent Voiable by Volume(%): 100% J � I 8 _ _ h. LING AND STORAGE Avoid contact with skin,eyes,or clothing. Use adequate ventilation to Flueort Solution Syntex (U.S.A.) Inc. continued minimize exposure. Wash thoroughly after handling. Store in a cool, MSDS No: MSX3889 May 15,1992 well-ventilated area. EXPOSURE CONTROLS/PERSONAL CHEMICAL PRODUCT IDENTIFICATION DrnOSO$OIUt' PROTECTION Company and Material Identification 'lon" Eye Protection: Wear safety glasses with side shields or a full face shield Product Name: Flacon Solution MSDS No: MS807.1-;.JJ' May 1992 if eye contact is likely.The choice of protection is based on the job activity and potential for contact with eyes and face. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL PRODUCT IDENTIFICATION Respiratory Protection: When handling bulk quantities or for long du. Product Composition rations where aerosolization of material is likely,wear a NIOSHIMSHA- t Product Name: Domoso Solution approved half-face air-purifying respirator. Component CAS k Formula PareeM COMPOSITION/INFORMATION ON INGREDIENTS Skin Protection: Wear gloves if skin contact is likely.Wear coveralls or Flumethasone 2135-17-3 CzrH�O< 0.05% Product Composition other protective overgarment if necessary.The choice of skin protection Polyethylene glycol 400 2352-26.83 N/Aa 4045% should be based on the job activity and potential for skin contacL Water 7732.18.5 H2O 50.60%r Component CAS N Formula Percent Engineering Controls:When handling bulk quantities or for long du- n,+ i sulfoxide 67.68-5 C2H60S 90% rations where aerosolization of material is likely,local exhaust ventilation Commponents less than I%not listed unless pharmacologically active or \4T � 77J2-18-5 H70 10% may be necessary. Proper equipment design may he necessary to reduce carcinogenic. the opportunity for skin and eye contact. 2 Pharmacologically active. HAZARD IDENTIFICATION Other: Wash hands immediately after handling material(especially be. rNot Available fore eating,drinking or smoking).Wash protective equipment thoroughly Health Hazards aher each use. HAZARD IDENTIFICATION Warning Statement:CAUTION: Excessive contact may irritate skin PHYSICAL AND CHEMICAL PROPERTIES Health Hazards and eyes. Excessive exposure may damage red blood cells,kidney,and liver.Avoid skin contact,eye contact ingestion,and inhalation. Material Note:These property values arc foI DMSU Warning Statement:CAUTION:Contains synthetic corticosteroid.Ex• intended for animal use only. Bolling Point: 189'C. cessive exposure may Interfere with adrenal gland function and related Potential Routes of Exposure: Skin and eye contact,accidental inges- Melting Point: 1$5'C. hormones,e.g.,cortisol,resulting in such effects as edema(water reten• tion.inhalation, Molecular Weight:78.11 tion)and weight gain.Avoid excessive skin contact,eye contact,ingestion, and inhalation. Material intended for animal use only. Eye: Excessive contact may irritate eyes. Repeated high doses from oral Solubility In Water: Soluble. Potential Routes of Exposure: Skin and eye contact,accidental inges- or skin exposure of DMSO caused lens alterations in laboratory animals Vapor Pressure:0.37 mm @ 20'C tion,inhalation but not in humans. Specific Gravity: 1.10 g/cm3 Skin: Excessive contact may-cause redness,burning,itching and scaling. PH: Not available. Eye: Direct contact is not expected to cease eye irritation. expected DMSO readily penetrates through the skin and may result in systemic Percent Volatile: Not available. Skin: Direct contact is not ted to cause skin irritation. effects. Garlic odor on the breath and skin may develop after excessive Systemic: Acute:Acute exposure may affect adrenal gland function and DMSO exposure.' Vapor Density,2.7- related hormones,e.g.,conisol.Chronic:Excessive chronic exposure may Systemic:Acute•Acute exposure is considered relatively nontoxic.The Evaporation: 4.3. produce effects observed in patients on long-term conicosteroid therapy, oral LDw (dose that kills 50%of the test animals)in rodents is approxi• Appearance,Color,Odor:Clear,hygroscopic liquid;faint ripe olive or such as edema(water retention),weight gain,high blood pressure,fatigue, mately 15 to 20 gfkg body weight,corresponding approximately to 1000 to vegetable odor. emotional changes,peptic ulcers,and bone demineralization.In addition, 1400 gr150 lb person,assuming equal sensitivity;1000 g of DMSO is con• individuals who have been continually ovetexposed to eordcosteroids and tamed in approximately 1100gof Domoso Solution.Signs ofacute toxicity STABILITY AND REACTIVITY then removed from exposure,withdrawal symptoms,such as weakness, may include nausea,vomiting,chills,cramps and lethargy;Chronic-Re- Stability:Stable. muscle aches,gastrointestinal symptoms, dehydration, and low blood peated exposure to DMSO in laboratoy animals resulted in destruction Incompatibility:Copper wool+trichiocoacetic acid;potassium perman- pressure,may result. of red blood cells,kidney damage,and liver damage. ganate,acid halides,cyanuric chloride,silicon tetrachloride,phosphorus Reproductive and Developmental Toxicity:Conicosteroids have been Reproductive and Development Toxicity:Oral or topical doses have trichloride and Irioxide thionly chloride,magnesium perchiorate,silver shown to cause birth defects in laboratory animals. •ot caused reproductive or birth defects in rats,mice and hamsters. fluoride,methyl bromide,iodine pentafluoride,nitrogen periodate,dibo• Carcinogenicity:None of the components in Flucon Solution are listed 3reinogenichy: None of the components in Domoso Solution are listed fine,sodium hydroxide,perchioric and periodic acids. by NTP,[ARC,or OSHA as carcinogenic. o)NTP,[ARC,or OSHA as carcinogenic. Hazardous Decomposition Products: Emits sulfur oxides, mercap- Medical Conditions Aggravated by Exposure: None known or re- Medical Conditions Aggravated by Exposure: DMSO enhances the tans,formaldehyde,carbon monoxide,and carbon dioxide when heated ported. to decomposition, occupational Exposure Limit:Syntex has not established an Occu skin absorption of many chemicals,including drugs,which may enhance P Po Y IN' their pharmacologic or toxicologic effects. Hazardous Polymerization:Will not occur. tiunal Exposure Limit(OEL)(of Flucon Solution.Syntex has established Occupational Exposure Limit: Syntex has not established an Occupa• an DEL for llumciltimne of 0,05 microgtartts/m3 of air.The OEL is an TOXICOLOGICAL INFORMATION 8-hour time-we hied averse airbome chemical concentration. OSHA, Ronal Exposure Limit(OEL)for Domoso Solution,OSHA,NIOSH,and i8 B ACGIH have not established a Permissible Exposure Limit(PEL),Rcla• See"Hazards Identification" NIOSH,and ACGIH have not established a Permissible Exposure Limit ove Exposure Limit(REL),or Threshold Limit Value(TLV),respectively, (PEL),Relative Exposure Limit(REL),or Threshold Limit Value(TLV), for any of(lie components in Domoso Solution. ECOLOGICAL INFORMATION respectively,for any of the components in Flacon Solution. Environmental Information FIRST AID MEASURES Persistence and Degradability: No data. FIRST AID MEASURES Aquatic Toxicity: No data. Eye Contact: Immediately flush eyes tho hl with weler for at least Eye Contact: Immediately flush eyes thoroughly with water for at least Y Y' Y �i Y 15 minutes. If redness or irritation develops,notify medical personnel DISPOSAL CONSIDERATIONS 15 minutes. If redness or irritation develops,notify medical personnel and supenisor. and supervisor. Waste Disposal Methods:All wastes containing the material should Skin Contact: Immediately wash thoroughly with soap and water for IS Skin Contact: Immediately wash thoroughly with soap and water for IS be properly labeled and stored prescribed from other wastes. Dispose minutes. If a rash or irritation develops,notify medical rsonnet and minutes. If a rash or irritation develops,notify medical personnel and of waste materials according to prescribed Federal,Slate,and local rag- �' � � supervisor. uiations,e.g.,appropriately permitted chemical landfill or appropriately supervisor. Inhalation: Immediately move to fresh air and notify medical personnel Permitted chemical waste incinerator. Rinsewaters resulting from spill Inhalation: Immediately move to fresh air and notify medical personnel and supenisor. cleanups should be discharged in an enviromentally safe manner,e.g.,to and supervisor. Ingestion: Drink a moderate amount(8.12 oz)of water and immediately an appropriately permitted wastewater treatment facility. Ingestion: Drink a moderate amount(8.12 oz.) of water and immedi- notify medical personnel and supervisor. TRANSPORT INFORMATION ately notify medical personnel and supervisor. FIRE FIGHTING MEASURES Transportation Information FIRE FIGHTING MEASURES Fire Protection DOT Hazard Class: Not regulated Fire Protection Flash Point: >95'C. UN Number: Not assigned Flesh Point:Not applicable. Explosivlty: Auto-ignition temperature for DMSO is 214'C REGULATORY INFORMATION Expioslvity:Not applicable. Extinguishing Media:Alcohol foam,CO multipurpose dry chemical Extinguishing Media: Foam, alcohol foam, COz, multipurpose dry g g Z. P � chemical or halon•fire extinguisher, label, o D Information: h addition a the product identity or halon•fire extinguisher. label,containers of Domoso Solution should be labeled according to FDA Special Fire Fighting Procedures: Wear full protective clothing and Special flue Fighting Procedures:Wear full protective clothing and requirements.The above information is based on data available to us and NIOSH/MSHA-a roved,positive pressure.self-contained breathing a NIOSM,ISHA-approved,positive pressure,self-contained breathing ap- PP I'os P B P is believed to on correct. Since the information may be applied under aratus.Wash all equipment thorou thoroughly after use we Wash all equipment thoroughly after use. conditions beyond our control and with which we may be unfamiliar, PB Y we do not assume any responsibility for the results of its use and all ACCIDENTAL RELEASE MEASURES ACCIDENTAL RELEASE MEASURES persons receiving it shall make their own determination of the effects Spill and Release Measures: If material is released or spilled,take properties,and protections which pertain to their particular conditions. Spill end Release Measures:If material is released or spilled,lake proper precautions to minimize exposure by using appropriate persona[ No representation,warranty,or guarantee,express or implied(including proper precautions to minimize exposure by using appropmte personal protective equipment. Cordon off spill area and minimize the spreading a warranty of fitness or merchantability for a particular purpose),is made protective equipment.Cordon off spill area and minimize the spreading 4 spilled material. Soak up material with absorbent,e.g.,paper towels. with respect to the material,the accuracy of this information,the results of spilled material. Soak up spilled material with aWrbcnl,e.g,paper Nash spill area thoroughly wilt soap and water. Collect spilled mate- to be obtained from the use thereof,on the hazards connected with the towels. Wash spill area thoroughly with soap and water. Collect spilled rial. absorbent,and rinsewater into suitable containers for disposal in use of the material. Caution should be used in the handling and use of matenal,absorbent,and rinsewater into suitable containers for proper accordance with applicable waste disposal regulations. the material. disposal in accordance with applicable waste disposal regulations. 967 EXPOSURE CONTROLS/PERSONAL .APOSURE CONTROLS/PERSONAL PROTECTION ' Domoso Gel PROTECTION ' Eye Protection; Wear safety glasses with side shields or full face shield if MSDS NO: MSX3887 May 15,1992 Eye Protection:Wear safety glasses with side shields or a full-face shield eve contact is likely.The choice of protection is based on the job activity if eye contact is likely The choice of protection is based on the job activity and potential for contact with eyes and face. CHEMICAL PRODUCT IDENTIFICATION and potential for,contact With eyes and face, Respiratory Protection:When handling bulk quantities or for long du- Company and Material Identification Respiratory Protection:When handling bulk quantities or for long du- rations where aerosolization of material is likely,wear a NIOSH/MSHA- Product Name: Domoso Gel rations where aerosolization of material is likely,wear a NIOSH/MSHA- approved half-face air purifying respirator. approved half-face air-purifying respirator. Skin Protection: Wear gloves if skin contact is likely.Wear coveralls or COMPOSITION/INFORMATION ON INGREDIENTS Skin Protection:Wear gloves if skin contact is likely. Wear coveralls or other protective overgarment if necessary.The choice of skin protection Component CAS# Formula Percent other protective overgarment if necessary.The choice is skin protection is based on the job activity and potential for skin contact. Qatathvl suffoltide(AMSG) 67-68-5 C2H6OS 90% should be based on the job activity and potential for skin contact- Engineering Controls: When handling bulk quantities or for long dura- t Engineering Controls: When handling bulk quantities or for long du- tions where aerosolization of materials is likely,local exhaust ventilation Carbomer 934 NIA N/A' I% rations where aerosolization of material is Jikely,local exhaust ventilation may be necessary. Proper equipment design may be necessary to reduce Water 7732.18.5 N/A' >5% may be necessary Proper equipment design may be necessary to reduce the opportunity for skin and eye contact. t Not Available. the opportunity for skin and eye contact Other: Wash hands immediately after handling material(especially be. Other: Wash hands immediately after handling material(especially be- fore eating,drinking,or smoking).Wash protective equipment thoroughly HAZARD IDENTIFICATION fore eating,drinking or smoking).Wash protective equipment thoroughly after each use. Health Hazards after each use Warning Statement: CAUTION: Excessive contact may irritate skin PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL AND CHEMICAL PROPERTIES and eyes. Excessive exposure may damage red blood cells,kidney,and liver.Avoid skin contact,eye contact,ingestion,and inhalation.Material Note:These property values are for DMSO. Physleel/Chemical Properties intended for animal use only. Boiling Point: 189'C. Bolling Point:Not applicable. Potential Routes of Exposure:Skin and eye contact,accidental inges- Melting Point: I85'C Melting Point: Not applicable. tion,inhalation. Molecular Weight: 78.13. Solubility In Water!Not available. Eye: Excessive contact may irritate eyes.Repeated oral or skin exposure Solubility In Water:Soluble. to high doses of DMSO caused lens alterations in laboratory animals but Vapor Pressure:Not available. not in humans. Vapor Pressure:0.37 mm @ 20'C. Specific Gravity: Not available. Skin: Excessive contact may cause redness,burning,itching and scaling. Specific Gravity: 1.10 g/cma PH: Not available. DMSO readily penetrates through the skin and may result in systemic pH: Not available Percent Volatile: Nil effects. Garlic odor on the breath and skin may develop after MDSO Percent Volatile: Not available exposure.Vapor Density: Nil. Vapor Density:2.7. Systemic:Acute:Acute exposure is considered relatively nontoxic.The Evaporation: Nil. oral LDss (dose that kills 50%of the test animals)in rodents is approx- Evaporation:4.3 Appearance,Color,Odor: Syrupy liquid. imately 15 to 20 g/kg body weight,corresponding approximately to 1000 Appearance,Color,Odor:Gel;faint ripe olive or vegetable odor to 1400 g/150 lb person,assuming equal sensitivity; I000 g of DMSO is contained in approximately 1100 g of Domoso Gel.Signs of acute toxicity STABILITY AND REACTIVITY STABILITY AND REACTIVITY may include nausea,vomiting,chills,cramps and lethargy.Chronic: Re- Stability: Stable peated exposure to DMSO in laboratory animals resulted in desctruction Stability:Stable. Incompatibility: Not known or reported. of red blood cells,kidney damage,and liver damage. Incompatibility:Copper wool+trichloroacetic acid;potassium perman- Reproductive and Developmental Toxicity:Oral or topical doses have ganate,acid halides,cyanuric chloride,silicon tetrachloride,phosphorus Hazardous Decomposition Products: Emits sulfur oxides when heated not caused reproductive or birth defects in rats,mice and hamsters. trichloride and trioxide,thionyl chloride,magnesium Perchlorate,silver to decomposition Carcinogenicity:None of the components in Domoso Gel are listed by fluoride,methyl bromide,iodine pentafluohde,nitrogen periodate,dibo- Hazardous Polymerization: Will not occur NM IARC,or OSHA as carcinogenic. rane,sodium hydroxide,perchloric and periodic acids Medical Conditions Aggravated by Exposure: DMSO enhances the Hazardous Decomposition Products: Emits sulfur oxides, mercap. TOXICOLOGICAL INFORMATION skin absorption of many chemicals,including drugs,which may enhance tans,formaldehyde,carbon monoxide,and carbon dioxide when heated shier pharmacologic and toxicologic effects. to decomposition See"Hazards Identification" Occupational Exposure Limit:Syntex has not established an Occupa- Hazardous Polymerization: Will not occur. lional Exposure limit (OEI.) for Domoso Gel. OSHA,NIOSH,and ECOLOGICAL INFORMATION ACG1H have not established a Permissible Exposure Limit(PEL),Rel- TOXICOLOGICAL INFORMATION alive Exposure Limit(REL),or Threshold Limit Value(TLV)for any of Environmental Information the components in Domoso Gel. See"Hazards Identification" Persistence and Degradablllty: No data. Aquatic Toxicity:No data. FIRST AID MEASURES ECOLOGICAL INFORMATION Eye Contact: Immediately flush eyes thoroughly with water for at leas[ Environmental Information 15 minutes. If redness or irritation develops,notify medical personnel Persistence and Degradablllty: No data DISPOSAL CONSIDERATIONS and supervisor. Skin Contact: Immediately wash thoroughly with soap and water for 15 Aquatic Toxicity: No data. Waste Disposal Methods:All wastes containing the material should y g v p be properly labeled and stored separately from other wastes. Dispose minutes. If a rash or irritation develops,notify medical personnel and of waste materials according to prescribed Federal,State,and local reg- supervisor DISPOSAL CONSIDERATIONS ulations,e.g.,appropriately permitted chemical waste incinerator. Rin- Inhalation: Immediately move to fresh air and notify medical personnel Waste Disposal Methods: All wastes containing the material should sewaters resulting from spill cleanups should be discharged in an envi- and supervisor. be properly labeled and stored separately from other wastes Dispose ronmentally safe manner,e.g.,to an appropriately permitted wastewater Ingestion: Drink a moderate amount(8-12-oz.)of water and immedi- of waste materials according to prescribed Federal,State,and local reg- treatment facility. ately notify medical personnel and supervisor. ulations,e,g.,appropriately permitted chemical landfill or appropriately permitted chemical waste incinerator. Rinsewaters resulting from spill FIRE FIGHTING MEASURES cleanups should be discharged in an environmentally safe manner,a g, TRANSPORT INFORMATION Fire Protection to an appropriately permitted wastewater treatment facility. DOT Hazard Class: Not regulated. Flash Point: >95'C UN Number: Not assigned Exploslvhy:Autoignition temperature for DMSO is 214'C. TRANSPORT INFORMATION Extinguishing Media: Foam, alcohol foam COz, multipurpose dry DOT Hazard Class: Not regulated. chemical or halon-fire extinguisher. UN Number:Not assigned. REGULATORY INFORMATION Special Fire Fighting Procedures: Wear full protective clothing and Labeling/Regulatory Information: In addition to the identity label,con- NIOSH/MSHA-aproved,positive pressure,self-contained breathing ap- tainenofDiamino4X should have the following label affixed:CAUTION: paratus.Wash all equipment thoroughly after use. REGULATORY INFORMATION Avoid skin contact,eye contact,inhalation or excessive ingestion. Ma- ACCIDENTAL RELEASE MEASURES Labeling/Regulatory Information: In addition to the product identity terial intended for animal use only. Read and understand the Material label,containers of Domoso Gel should be labeled according to FDA Safery Data Sheet before using this product. The above information is Spill and Release Measures: If material is released or spilled,take requirements.The above information is based on data available to us and based on data available to us and is believed to be correct. Since the proper precautions to minimize exposure by using appropriate personal is believed to be correct. Since the information may be applied under information may be applied under conditions beyond our control and protective equipment.Cordon off spill area and minimize the spreading conditions beyond our control and With which we may be unfamiliar, with which we may be unfamiliar,we do not assume any responsibility of spilled material. Soak up material with absorbent,e.g.,paper towels. we do not assume any responsibility for the results of its use and all for the results of its use and all persons receiving it shall make their own Wash spill area thoroughly with soap and water. Collect spilled male- persons receiving it shall make[heir own determination of the effects, determination of the effects,properties,and protections which pertain to rial,absorbent,and rinsewater into suitable containers for disposal in properties,and protections which pertain to their particular conditions their particular conditions. No representation,warranty,or guarantee, accordance with applicable waste disposal regulations. No representation,warranty,or guarantee,express or implied(inluding express or implied(including a warranty of fitness or merchantability for a warranty of fitness or merchantibility,fora particular purpose),is made a particular purpose),is made with respect to the material,the accuracy HANDLING AND STORAGE with respect to the material,the accuracyof this information,the results of this information,the results to be obtained from the use thereof,or Avoid contact with skin,eyes,or clothing. Use adequate ventilation to to be obtained from the use thereof,or the hazards connected with the the hazards connected with the use of the material. Caution should be minimize exposure. Wash thoroughly after handling. Store in a cool, use of the material. Caution should be used in the handling and use of used in the handling and use of the material. well-ventilated area. the material. - -- -- -- -- - - - - - -- --- - -- - MATERIAL SAFETY DATA SHEh - ---------------------- Phoenix Pharmaceutical I BRINE; ----------------------------------------------------------------------------------------------------�"'__---�P_--- _' At the present time there is no Material Safety Data Sheet available for Epinephrine. The following Safety Sheets apply to the ingredients of this product: --------------------------------------------—------------- INGREDIENT COMPAS CODE ------------------------------------------------------------- Epinephrine Injection 28200011 Epinephrine/Adrenaline 46701000 ----------------------------------------------------------- For more information contact the manufacturer of Epinephrine: PHOENIX PHARMACEUTICAL, INC. 4621 EASTON ROAD ST. JOSEPH, MO 64503 ------------------------------------------------------------- DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representation as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpoee(s). A request has been made to the manufacturer to approve the contents of this material safety data sheet. Upon receipt a new MSDS will be made available. ----------------------------------------------------------- COMPAS Code: 12390290 NAC Approved Date: / / 1/23/96------------------------------------------------------------------------------------—------------—--------------- MWI VETERINARY SUPPLY 2363186 NORTHWEST VET CLINIC/STANWOOD Page 1 of 3 Phoenix Phan------- MATERIAL SAFETY DATA SHz_r ----------------------- EPINEPHRT=d' --------------------------------------------------------------------------------------------------------------------------- Anthony EPINEPHRINE INJECTION --------------------------------------------------------------------------------------------------------------------------- ----------------------------------------------------------- ----------------------------------------------------------- SECTION I SECTION VIII - SPECIAL PROTECTION INFORMATION ----------------------------------------------------------- ----------------------------------------------------------- MANUFACTURER'S NAME: ANTHONY PRODUCTS CO. RESPIRATORY PROTECTION (Specify type): Masks. 5600 PECK ROAD VENTILATION: ARCADIA, CA 91006 LOCAL EXHAUST: EMERGENCY TELEPHONE NO.: (818) 357-8711 MECHANICAL (General): SAM TO 4PM MON TO FRI. SPECIAL: CHEMICAL NAME AND SYNONYMS: C9H13NO3 OTHER: 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, PROTECTIVE GLOVES: Yee (R)-• EYE PROTECTION: Glasses (-)-3,4-Dihydroxy-alpha-[(methylamino)methyl] benzyl OTHER PROTECTIVE EQUIPMENT: None alcohol [51-43-4] . ----------------------------------------------------------- TRADE NAME AND SYNONYMS: Epinephrine Injection SECTION IX - SPECIAL PRECAUTIONS ----------------------------------------------------------- ----------------------------------------------------------- SECTION II - INGREDIENTS AND HAZARDS PRECAUTION TO BE TAKEN IN HANDLING AND STORING: N/A ----------------------------------------------------------- OTHER PRECAUTIONS: Ingredient Name: Percent: Exposure Limit: ----------------------------------------------------------- ----------------------------------------------------------- The information contained herein is believed to be complete Epinephrine N/A and accurate. However, it is the user's responsibility to ----------------------------------------------------------- determine the suitability of the information for their SECTION III - PHYSICAL DATA particular purpose. Anthony Products Company assumes no ----------------------------------------------------------- additional liability or responsibility resulting from the BOILING POINT (deg F.): 100 deg C use of, or reliance on this information. VAPOR PRESSURE (mm Hg.): N/A ----------------------------------------------------------- VAPOR DENSITY (AIR = 1): N/A COMPAS Code: 28200011 NAC Approved Date: SOLUBILITY IN WATER: Miscible SPECIFIC GRAVITY (H2O = 1) : EVAPORATION RATE ( - 1): APPEARANCE AND ODOR: Clear, colorless, solution ----------------------------------------------------------- SECTION IV - FIRS AND EXPLOSION HAZARD DATA ----------------------------------------------------------- FLASH POINT (Method used) : N/A FLAMMABLE LIMITS: N/A LEL: N/A UEL: N/A EXTINGUISHING MEDIA: CO2, foam and dry powder SPECIAL FIRE FIGHTING PROCEDURES: N/A UNUSUAL FIRE AND EXPLOSION HAZARDS: N/A ----------------------------------------------------------- SECTION V - HEALTH HAZARD DATA ----------------------------------------------------------- THRESHOLD LIMIT VALUE: LD50 rat, oral (24 mg) or 24 ml of injection per kg. of body wt. EFFECTS OF OVEREXPOSURE: Possible symptoms of poisoning: headache, tachycardia, cardiac arrythmiae, restlessness, anxiety, tremors. EMERGENCY AND FIRST AID PROCEDURES: After contact with skin, wash immediately with plenty of water. Seek medical advice immediately. ----------------------------------------------------------- SECTION VI - REACTIVITY DATA ----------------------------------------------------------- STABILITY: Unstable CONDITIONS TO AVOID: Keep away from light and heat. INCOMPATIBILITY (Materials to avoid) : N/A HAZARDOUS DECOMPOSITION PRODUCTS: In case of burning, fumes may develop which can be dangerous. HAZARDOUS POLYMERIZATION: CONDITIONS TO AVOID: ----------------------------------------------------------- SECTION VII - SPILL OR LEAK PROCEDURES ----------------------------------------------------------- STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Wash with generous amount of water. WASTE DISPOSAL METHOD: Do not empty into drains. In compliance with local regulations left over products must be handed over to the person responsible for their disposal. 1/23/96------------------------------------------------------------------------------------------------------------------- MWI VETERINARY SUPPLY 2363186 NORTHWEST VET CLINIC/STANWOOD Page 2 of 3 _ i! I I I l - - - - - -- -- - - - -- - - - - - -- - MATERIAL SAFETY DATA S. .ET --- - ---- - - - -- - - - - - --- - - Phoenix Pharmaceutical EPINEPHRINE -------------------------------------------------------------------------------------------------------------------------- Boehringer Ingelheim Kg EPINEPHRINE/ADRENALINE --------------------------------------------------------------------------------------------------------------------------- COMPANY: BOEHRINGBR INGELHEIM KG 5.5 DISPOSAL: In compliance with the local regulations left DATE: 11.02.86 over products must be handed over to the person COMMERCIAL PRODUCT NAME: (-)-Epinephrine, (-)-Adrenaline responsible for their disposal or given back to the 1.1 CHEMICAL CHARACTERIZATION: (-)-1-(3,4-Dihydroxyphenyl)- producer. Disposal possibilities: Suitable combustion 2-methylamino-ethanol plants. 1.2 FORM: Powder ----------------------------------------------------------- 1.3 COLOUR: White 6 MEASURES IN CASE OF ACCIDENTS AND FIRES 1.4 ODOUR: Odourlese ----------------------------------------------------------- 6.1 AFTER SPILLAGE/LEAKAGE/GAS LEAKAGE: Take up by 2 PHYSICAL DATA AND SAFETY DATA mechanical means, avoiding duet formation. ----------------------------------------------------------- 6.2 EXTINGUISHING MEDIA: Suitable: CO2, foam, dry powder, 2.1 CHANGE IN PHYSICAL STATE: Tested in accordance with: water spray jet Melting point: about 212 deg C (decomposition) 6.3 FIRST AID: In case of accident of if you fell unwell, 2.2 DENSITY: BULK DENSITY: About 400 kg/m3 seek medical advice immediately (show the label where 2.3 VAPOUR PRESSURE: N/A possible). In case of contact with eyes, rinse 2.4 VISCOSITY: N/A immediately with plenty of water and seek medical 2.5 SOLUBILITY IN WATER: About 1 g/l (20 deg C) advice. After contact with skin, wash immediately with 2.6 pH VALUE: About 9 (1 g/l, 20 deg C) plenty of water and soap. 2.7 FLASH POINT: N/A 6.4 FURTHER INFORMATION: Possible symptoms of poisoning: 2.8 IGNITION TEMPERATURE: N/A Headache, tachycardia, cardiac arrhytmias, 2.9 EXPLOSION LIMITS: restlessness, anxiety, tremors. 2.10 THERMAL DECOMPOSITION: --------------------------------------------------- 2.11 HAZARDOUS DECOMPOSITION PRODUCTS: In case of burning 7 INFORMATION OF TOXICITY fumes may develop which can be dangerous to health. ----------------------------------------------------------- 2.12 HAZARDOUS REACTIONS: RTECS DO 26250000: LD50 mouse, oral: 50 mg/kg; 2.13 FURTHER INFORMATION: Up to 188 deg C no exothermic LDLO man, sc: 0.74 mg/kg dec. (DTA) ----------------------------------------------------------- ----------------------------------------------------------- 8 INFORMATION ON ECOLOGICAL EFFECTS 3 TRANSPORT --------------------------------------------------------- -------------------------------------------- Do not empty into drains. GGV SEE/IMDG CODE: cl. 6.1 p.6339 (D), p. 6154-2 (E) ---------------------------------------------------------- GGVE/GGVS: cl. 6.1, 90a 9 FURTHER INFORMATION UNNO.: 2811 ___________________________________».----------------' RID: cl. 6.1, 90a (-)-Epinephrine is an active ingredient. All precautionary ADR: cl. 6.1, 90a measures required for drugs have to be observed ICAO/IATA-DGR: cl. 6.1, UN2811/I, poison analogously. All information given herein is based on the ADNR: current statue of our knowledge and is not a guarantee OTHER INFORMATION: for certain properties. AIR TRANSPORT: Packing group 1, p.instr.p.: 606 (Skg), ----------------------------------------------------------- p.instr.c.: 607 (50kg) . COMPAS Code: 46701000 NAC Approved Date: NAVAL TRANSPORT: Packing group I, EMS-NO.: 1.1-04 (RM 002), MFAG: A, 4.2. LAND TRANSPORT: Packing group a). ----------------------------------------------------------- 4 REGULATIONS ----------------------------------------------------------- CHEMG/ARBSTOFFV (recommended classification): CAS-Nr. 51-43-4 DANGER SYMBOL: T Very toxic R-PHRASES: 26/27/28 Very toxic by inhalation, in contact with skin and if swallowed. S-PHRASES: 1-37/39-45 Keep locked up. Wear suitable gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). ----------------------------------------------------------- 5 PROTECTIVE MEASURES, STORAGE AND HANDLING ----------------------------------------------------------- 5.1 TECHNICAL PROTECTIVE MEASURES: Keep locked up. Store in original package only. Protect from light. 5.2 PERSONAL PROTECTIVE EQUIPMENT: RESPIRATORY PROTECTION: Duet mask HAND PROTECTION: Gloves BYE PROTECTION: Dustproof glasses OTHER: 5.3 INDUSTRIAL HYGIENE: When using do not eat, drink or smoke. Avoid contact with eyes. 5.4 PROTECTION AGAINST FIRE AND EXPLOSION: With organic powders the danger of a duet explosion is generally to be expected. Dust explosion danger-class (modified Hartmann-tube): ST 2. 1/23/96----------------------------------------------------------------------------------------------------------------- MWI VETERINARY SUPPLY 2363186 NORTHWEST VET CLINIC/STANWOOD Page 3 of 3 -------------------- - MATERIAL SAFETY DATA SH --``T ----- - - - - - - - ------- ---- Virbac ��EPI-OTIC DRYING EAR CLEANSER, -------------------------------------------------------------------------------------------------------------------------- IDENTITY: EPI-Otic Drying Ear Cleanser EMERGENCY AND FIRST AID PROCEDURES: MSDS #: VB0030 SKIN CONTACT: Wash exposed skin with soap and water. If ----------------------------------------------------------- irritation develops, contact a physician. SECTION I EYE CONTACT: Flush eyes with plenty of water. Get medical ----------------------------------------------------------- attention, if irritation develops. SUPPLIER INFORMATION: VIRBAC, INC. INGESTION: Not applicable. P.O. BOX 162059 INHALATION: Not applicable. FORT WORTH OTHER INFORMATION: TX76161 ----------------------------------------------------------- EMERGENCY TELEPHONE NUMBER: Contact the POISON CONTROL SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE CENTER ----------------------------------------------------------- TELEPHONE NUMBER FOR INFORMATION: 800/338-3659 STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: DATE PREPARED: 04/10/95 Dike and contain spill. Clean with inert absorbent OTHER INFORMATION: PIC 0030-04, PIC 0030-08, PIC 0030-16 material and collect for disposal. ----------------------------------------------------------- WASTE DISPOSAL METHOD: Dispose of in accordance with all SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION applicable federal, state, and local laws. ----------------------------------------------------------- PRECAUTIONS TO BE TAKEN IN HANDLING OR STORAGE: Store in a Hazardous Components (Spec. OSHA ACGIH % tightly closed container in a cool, dry area. Chem. Ident.; Common Name) PEL TLV (opt.) OTHER PRECAUTIONS: Keep out of the reach of children. None SECTION VIII - CONTROL MEASURES CAS#: ----------------------------------------------------------- ----------- ------------------------------- RESPIRP_TORY PROTECTION (Specify Type) : SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS VENTILATION: ----------------------------------------------------------- LOCAL EXHAUST: BOILING POINT: 212 deg F (GT) MECHANICAL (General) : VAPOR PRESSURE (mm Hg) : SPECIAL: VAPOR DENSITY (AIR = 1) : OTHER: SOLUBILITY IN WATER: Complete PROTECTIVE GLOVES: Rubber Gloves, if necessary SPECIFIC GRAVITY (H20 = 1) : 1.04 EYE PROTECTION: MELTING POINT: OTHER PROTECTIVE CLOTHING OR EQUIPMENT: EVAPORATION RATE (Butyl Acetate = 1) : WORK/HYGIENIC PRACTICES: APPEARANCE AND ODOR: Light blue, clear to slightly hazy OTHER INFORMATION: liquid with a characteristic odor. ----------------------------------------------------------- OTHER INFORMATION: SECTION IX - ADDITIONAL INFORMATION SECTION IV - FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------- ------------------------------—--—----------------------- FLASH POINT (Method Used) : Not Flammable DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: Although FLAMMABLE LIMITS: reasonable care has been taken in the preparation of this LEL: document, we extend no warranties and make no UEL: representation as to the accuracy or completeness of the EXTINGUISHING MEDIA: Water spray, dry chemical, carbon information contained therein, and assume no responsibility dioxide, or foam suitable for surrounding fire and regarding the suitability of this information for the materials. user's intended purposes or for the consequences of its SPECIAL FIREFIGHTING PROCEDURES: use. Each individual should make a determination as to the UNUSUAL FIRE AND EXPLOSION HAZARDS: suitability of the information for their particular OTHER INFORMATION: purpose(s) . A request has been made to the manufacturer to ----------------------------------------------------------- approve the contents of this material safety data sheet. SECTION V - REACTIVITY DATA Upon receipt a new MSDS will be made available. ----------------------------------------------------------- ----------------------------------------------------------- STABILITY: Stable COMPAS Code: 12610680 NAC Approved Date: CONDITIONS TO AVOID: INCOMPARABILITY (Materials to Avoid) : HAZARDOUS DECOMPOSITION OR BYPRODUCTS: HAZARDOUS POLYMERIZATION: Will Not Occur CONDITIONS TO AVOID: OTHER INFORMATION: ----------------------------------------------------------- SECTION VI - HEALTH HAZARD DATA ----------------------------------------------------------- ROUTES OF ENTRY: INHALATION? No SKIN? No INGESTION? No HEALTH HAZARDS (Acute and Chronic) : CARCINOGENICITY: NTP? No IARC MONOGRAPHS? No OSHA REGULATED? No SIGNS AND SYMPTOMS OF EXPOSURE: MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: 3/27/96------------------------------------------------------------------------------------------------------------------- ProVet*Seattle 176325 NORTHWEST VET CLINIC Page 1 of 1 i; �� � ------------------- -- MATERIAL SAFETY DATA S')ET - - - - - - - - - ----- - - - - -- - - - Agfa FIXER CONC 2-PART At the present time there is no Material Safety Data Sheet available for Fixer Conc 2-Part. The following Safety Sheets apply to the ingredients of this product: ----------------------------------------------------------- INGREDIENT COMPAS CODE ----------------------------------------------------------- G-353C Fixer for Gevamatic(R) 60 Part A 25870091 G-353C Fixer for Gevamatic(R) 60 Part B 25870100 G-353C Fixer for Gevamatic(R) 60 25870110 Working Strength ----------------------------------------------------------- For more information contact the manufacturer of Fixer Conc 2-Part: AGFA DIVISION BAYER CORPORATION 100 Challenger Road Ridgefield Park, NJ 07660 ----------------------------------------------------------- DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representation as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose(s) . A request has been made to the manufacturer to approve the contents of this material safety data sheet. Upon receipt a new MSDS will be made available. ----------------------------------------------------------- COMPAS Code: 25870081 NAC Approved Date: 12/17/96-------------------------------------------------------------------------------------------------------- -- ProVet•Seattle 212390 NORTHWEST VET CLINIC Page 1 of 7 ------- - - ---- - - -- - -I - - MATERIAL SAFETY DATA ° )ET - - - - - - - - - - - - - - - - - - - - - - - Agfa FIXER CONC 2-PART ------------------------------------------------------- -- ------------------------------------------------------------- Agfa G-353C FIXER FOR GEVAMATIC(R) 60 PART A #203A ---------------------------------------------- MANUFACTURER: AGFA DIVISION SECTION 4: FIRST AID MEASURES BAYER CORPORATION ----------------------------------------------------------- 100 CHALLENGER ROAD EYES: Immediately flush with plenty of running water for at RIDGEFIELD PARK, NJ 07660 least 15 minutes. Obtain medical attention. NON-EMERGENCY TELEPHONES: SKIN: Flush affected areas promptly with water for 15 NJ (201) 440-2500 minutes. Remove contaminated clothing. In case of ----------------------------------------------------------- continued irritation consult physician. SECTION 1: CHEMICAL PRODUCT IDENTIFICATION INHALATION: For over-exposure, remove to fresh air. ----------------------------------------------------------- INGESTION: Obtain immediate medical attention. PRODUCT NAME: G-353C Fixer for GEVAMATIC(R) 60 Part A ----------------------------------------------------------- PRODUCT DESCRIPTION: Aqueous Acidic Solution SECTION 5: FIRE FIGHTING MEASURES REVISION: 1 --------------------------------------- ----------- BUSINESS GROUP: Technical Imaging Systems FIRE AND EXPLOSION DATA: Noncombustible CATALOG NUMBER: FYIH0076 (FV5A1) to make 2.5 liters FIRE AND EXPLOSION HAZARDS: None MEDICAL EMERGENCY TELEPHONE (Poison Center) : (303) 623-5716 EXTINGUISHING MEDIA: Any applicable to primary cause of TRANSPORTATION EMERGENCY TELEPHONE (Chemtrec) : 1-800-424- fire. 9300 SPECIAL FIRE FIGHTING PROCEDURES: Evacuate personnel to a ----------------------------------------------------------- safe area. Keep personnel removed and upwind of fire. SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS Wear self-contained breathing apparatus. (Typical Values) UNUSUAL FIRE & EXPLOSION HAZARDS: When heated to ----------------------------------------------------------- decomposition emission of toxic fumes of. S02 is possible. HAZARDOUS INGREDIENTS WT ACGIH(TLV) OSHA(PEL) ----------------------------------------------------------- ----------------------------------------------------------- SECTION 6: ACCIDENTAL RELEASE MEASURES Ammonium Thiosulfate 50-55 25 ppm as 50 ppm as ----------------------------------------------------------- CAS NO.: 7783-18-8 ammonia ammonia SPILL OR LEAK PROCEDURES: NOTE: Review Sections 5 and 8 OTHER IMPORTANT INGREDIENTS: before proceeding with clean up. Use appropriate PERSONAL Water 35-40 *NE *NE PROTECTIVE EQUIPMENT during clean up. Dike Spill. Prevent CAS NO.: 7732-18-5 liquid from entering sewers, waterways or low areas. Soak Sodium Sulfite 1-5 *NE *NE up with sawdust, sand, oil dry or other absorbent CAS NO.: 7757-83-7 material. Sodium Acetate 1-5 *NE *NE ----------------------------------------------------------- CAS NO.: 127-09-3 SECTION 7: HANDLING AND STORAGE BoricAcid 1-5 *NE *NE ----------------------------------------------------------- CAS NO.: 10043-35-3 Avoid eye and skin contact, and store in well-ventilated *None Established area. Keep container tightly closed. Do not store with ----------------------------------------------------------- incompatible materials (see Section 10) . Do not store or SECTION 3: HAZARDS IDENTIFICATION consume food, drink or tobacco in area where they may ----------------------------------------------------------- become contaminated with this material. EMERGENCY OVERVIEW: Keep unnecessary people away and upwind ----------------------------------------------------------- of fire. Toxic gases may be emitted when heated to SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION decomposition. Some of these materials may burn but none ----------------------------------------------------------- of them ignites readily. Follow Section 5 for fire RESPIRATORY PROTECTION: None needed with working mixtures fighting measures and Section 6 for accidental release and normal room ventilation (10 changes of air per hour). measures. In case of contact with material, immediately VENTILATION: Room ventilation is sufficient. Avoid use of flush eyes with running water for at least 15 minutes. product in unventilated areas. Always control airborne See ERG Guide # 31 levels below the exposure guidelines when reported in POTENTIAL HEALTH EFFECTS: Section 2 (use 50% of the TLV) . ROUTES OF ENTRY: Eye, Skin, Inhalation, Ingestion SKIN AND EYE PROTECTION: Splash protection required for A. ACUTE EXPOSURE EFFECTS (NOTE: Pertains to Finished eyes, e.g., eye glasses with side shields or goggles. For Product) skin protection use chemical resistant gloves and aprons. EYE CONTACT: May cause irritation. Disposable coveralls are optional, and discard after use. SKIN CONTACT: May cause irritation. ----------------------------------------------------------- INHALATION: Normally no problem, but inhalation of SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES mist could cause respiratory irritation. Asthmatics ----------------------------------------------------------- and sensitive individuals may experience a reaction BOILING POINT: Approx. 212 deg F to low levels of Sulfur Dioxide. MELTING POINT: Not Applicable INGESTION: May cause irritation of the mucous VAPOR PRESSURE: Not Estimated membranes or digestive tract. Sulfite sensitive VAPOR DENSITY (AIR=1) : Not Estimated individuals may experience an allergic reaction. EVAPORATION RATE: Not Estimated B. CHRONIC HEALTH EFFECTS (NOTE: Pertains to each VOLATILE FRACTION BY WEIGHT: Not Estimated ingredient listed in Section 2 per 29 CFR Sect. SOLUBILITY IN WATER (By Weight %) : 100% 1910.1200) : A computerized literature search of SPECIFIC GRAVITY (H2O=1) : 1.347 national databases did not yield any chronic effects pH: 5.35 associated with these materials. APPEARANCE: Clear and colorless liquid CARCINOGENICITY LISTING: ODOR: Slight sulfur dioxide odor NTP: No ----------------------------------------------------------- IARC: No SECTION 10: STABILITY AND REACTIVITY OSHA: No ----------------------------------------------------------- STABILITY: Stable INCOMPATIBILITY: Strong alkali HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of sulfur, CO2, carbon monoxide, ammonia HAZARDOUS POLYMERIZATION: Will not occur 12/17/96------------------------------------------------------------------------------------------------------------------- ProVet*Seattle 212390 NORTHWEST VET CLINIC Page 2 of 7 ------------------- MATERIAL SAFETY DATA SH7 ----------------------- Agfa FIXER CONC 2-PART --------------------------------------------------------------------------------------------------------------------------- ----------------------------------------------------------- SECTION 11: TOXICOLOGICAL INFORMATION ---------------------------------------------------------— Toxicological properties of this substance have not been fully investigated. ----------------------------------------------------------- SECTION 12: ECOLOGICAL INFORMATION ----------------------------------------------------------- GENERAL: Not expected to present any significant ecological problems. ----------------------------------------------------------- SECTION 13: DISPOSAL CONSIDERATIONS ----------------------------------------------------------- WASTE DISPOSAL: Recover nonusable free liquid and/or contaminated water, and dispose of in an approved and permitted treatment system. Incineration is recommended. Remove nonusable solid material and/or contaminated soil, for disposal in an approved and permitted landfill. Discharge to sewer requires approval of permitting authority and may require pretreatment. ----------------------------------------------------------- SECTION 14: TRANSPORTATION INFORMATION ----------------------------------------------------------- DOT, IMO, ICAO, TRANSPORT CANADA: Non-Regulated NFPA: HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0 SPECIAL: None 4=Extreme 3=High 2=Moderate 1=Slight O=Insignificant ----------------------------------------------------------- SECTION 15: REGULATORY INFORMATION ----------------------------------------------------------- U.S. FEDERAL REGULATION: OSHA: This product is hazardous under the criteria of the federal Hazard Communication Standard, 29CFR1910.1200. TSCA: All ingredients in this finished product are listed on the EPA TSCA Inventory (see Section 2) . CERCLA HAZARDOUS SUBSTANCE (40 CFR 302) : not listed SARA TITLE III: Superfund Amendments and Reauthorization Act of 1986 (SARA Title III) requires submission of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313) . SARA HAZARD CATEGORIES: IMMEDIATE (see Section 3, Acute Health Effects) . Components present in this product at a level which could require reporting under the statute are: Ammonia ----------------------------------------------------------- SECTION 16: OTHER INFORMATION ----------------------------------------------------------- This information is furnished without warranty, expressed or implied, except that it is accurate to the best of the knowledge of AGFA DIVISION of BAYER CORPORATION. The data on this sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. AGFA DIVISION of BAYER CORPORATION assumes no legal responsibility for use or reliance upon this data. The information herein is provided solely for your consideration, investigation, and verification. FOR TECHNICAL INFORMATION CONTACT: Technical Imaging Systems Agfa Division Bayer Corporation 100 Challenger Road Ridgefield Park, NJ 07660 (201) 440-2500 COMPAS Code: 25870091 12/17/96-------------------------------------------------------------------------------------------------------------------- ProVet*Seattle 212390 NORTHWEST VET CLINIC Page 3 of 7 1 ---- --- ------------ - - MATERIAL SAFETY DATA SH" r - - - ---------------- -- - - Agfa FIXER CONC 2-PART --------------------------------------------------------------------------------------------------------------------------- Agfa G-353C FIXER FOR GEVAMATIC(R) 60 PART B --------------------------------------------------------------------------------------------------------------------------- #203B ----------------------------------------------------------- MANUFACTURER: AGFA DIVISION SECTION 4: FIRST AID MEASURES MILES INC. --------------------—------------------------------------- 100 CHALLENGER ROAD EYES: Immediately flush with plenty of running water for at RIDGEFIELD PARK, NJ 07660 least 15 minutes. Obtain medical attention. NON-EMERGENCY TELEPHONES: SKIN: Flush affected areas promptly with water for 15 NJ (201) 440-2500 minutes. Remove contaminated clothing. In case of NY (212) 971-0260 continued irritation consult physician. ----------------------------------------------------------- INHALATION: For over-exposure, remove to fresh air. SECTION 1: CHEMICAL PRODUCT IDENTIFICATION INGESTION: Obtain immediate medical attention. - ------------------------- ----------------------------------------------------------- PRODUCT NAME: G-353C Fixer for GEVAMATIC(R) 60 Part B SECTION 5: FIRE FIGHTING MEASURES PRODUCT DESCRIPTION: Aqueous Acidic Solution ----------------------------------------------------------- FORMULA: 8100/010E1(B) FIRE AND EXPLOSION DATA: Noncombustible BUSINESS GROUP: Technical Imaging Systems FIRE AND EXPLOSION HAZARDS: None CATALOG NUMBER: FYlHO076 (HVSA1) to make 2.5 liters EXTINGUISHING MEDIA: Any applicable to primary cause of MEDICAL EMERGENCY TELEPHONE (Poison Center) : (303) 623-5716 fire. TRANSPORTATION EMERGENCY TELEPHONE (Chemtrec) : 1-800-424- SPECIAL FIRE FIGHTING PROCEDURES: Evacuate personnel to a 9300 safe area. Keep personnel removed and upwind of fire. ----------------------------------------------------------- Wear self-contained breathing apparatus. SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS UNUSUAL FIRE & EXPLOSION HAZARDS: When heated to (Typical Values) decomposition emission of toxic fumes of S02 !s possible. ----------------------------------------------------------- ----------------------------------------------------------- HAZARDOUS INGREDIENTS WT % ACGIH(TLV) OSHA(PEL)+ SECTION 6: ACCIDENTAL RELEASE MEASURES ----------------------------------------------------------- ----------------------------------------------------------- Aluminum Sulfate 1-5 2mg/m3 *NE SPILL OR LEAK PROCEDURES: NOTE: Review Sections 5 and 8 CAS NO.: 10043-01-3 before proceeding with clean up. Use appropriate PERSONAL Acetic Acid 1-5 10 ppm 10 ppm PROTECTIVE EQUIPMENT during clean up. Dike spill. Prevent CAS NO.: 64-19-7 liquid from entering sewers, waterways or low areas. Soak OTHER IMPORTANT INGREDIENTS: up with sawdust, sand, oil dry or other absorbent Water 90-95 *NE *NE material. Spill may be neutralized with powdered Sodium CAS NO.: 7732-18-5 Carbonate. Polyethylene Glycol 1-5 *NE *NE ----------------------------------------------------------- Mono/(nonylphenyl) SECTION 7: HANDLING AND STORAGE ether CAS NO.: 9016-45-9 Avoid eye and skin contact, and store in well-ventilated +The PEL limit values listed above are published figures area. Keep container tightly closed. Do not store with from the 1989 Title 29, CFR 1910.1000, Z list using incompatible materials (see Section 10) . Do not store or transitional limits. consume food, drink or tobacco in area where they may *None Established become contaminated with this material. ----------------------------------------------------------- ----------------------------------------------------------- SECTION 3: HAZARDS IDENTIFICATION SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ----------------------------------------------------------- ----------------------------------------------------------- EMERGENCY OVERVIEW: Amber or clear solution with a vinegar RESPIRATORY PROTECTION: None needed with working mixtures odor. During a fire, irritating and toxic gases can be and normal room ventilation (10 changes of air per hour). generated by thermal decomposition which can cause severe VENTILATION: Room ventilation is sufficient. Avoid use of irritation to eyes, skin and mucous membranes. Follow product in unventilated areas. Always control airborne Section 5 for fire fighting procedures. Always move levels below the exposure guidelines when reported in victim to fresh air and call for emergency medical care. Section 2 (use 50% of the TLV) . See ERG Guide # 60 SKIN AND EYE PROTECTION: Chemical goggles, chemical POTENTIAL HEALTH EFFECTS: resistant gloves and aprons are mandatory. Disposal ROUTES OF ENTRY: Eye, Skin, Inhalation, Ingestion coveralls are optional and discard after use. A. ACUTE EXPOSURE EFFECTS (NOTE: Pertains to Finished ----------------------------------------------------------- Product) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES EYE CONTACT: May cause severe irritation and burning. ----------------------------------------------------------- SKIN CONTACT: May cause severe irritation and burning. BOILING POINT: Approx. 221 deg F INHALATION: Normally no problem, but inhalation of MELTING POINT: Not applicable mist could cause respiratory irritation. VAPOR PRESSURE: Not estimated INGESTION: May cause severe irritation or burning of VAPOR DENSITY (AIR=1) : Not estimated the mucous membranes or digestive tract. EVAPORATION RATE: Not estimated B. CHRONIC HEALTH EFFECTS (NOTE: Pertains to each VOLATILE FRACTION BY WEIGHT: Not estimated ingredient listed in Section 2 per 29 CFR Sect. SOLUBILITY IN WATER (By Weight %) : 100% 1910.1200) : A computerized literature search of SPECIFIC GRAVITY (H2O=1) : 1.050 national databases did not yield any chronic effects pH: 2.5 associated with these materials. APPEARANCE: Clear and colorless CARCINOGENICITY LISTING: ODOR: Strong vinegar odor NTP: No IARC: No OSHA: No 12/17/96---`--------------------------------------------------------------------------------------------------------------- ProVet*Seattle 212390 NORTHWEST VET CLINIC Page 4 of 7 ------------------- -- MATERIAL SAFETY DATA S'__)ET ------------ - - --------- Agfa FIXER CONC 2-PART --------------------------------------------------------------------------------------------------------------------------- ----------------------------------------------------------- ----------------------------------------------------------- SECTION 10: STABILITY AND REACTIVITY SECTION 16: OTHER INFORMATION ----------------------------------------------------------- --------------------------------------------------------- STABILITY: Stable This information is furnished without warranty, expressed INCOMPATIBILITY: Strong alkali, oxidizers or implied, except that it is accurate to the best of the HAZARDOUS DECOMPOSITION PRODUCTS: CO2, carbon monoxide, knowledge of AGFA DIVISION of MILES INC. The data on this oxides of sulfur sheet relates only to the specific material designated HAZARDOUS POLYMERIZATION: Will not occur herein and does not relate to use in combination with any ----------------------------------------------------------- other material or in any process. AGFA DIVISION of MILES SECTION 11: TOXICOLOGICAL INFORMATION INC. assumes no legal responsibility for use or reliance ----------------------------------------------------------- upon this data. The information herein is provided solely Toxicological properties of this substance have not been for your consideration, investigation, and verification. fully investigated. FOR TECHNICAL INFORMATION CONTACT: --------------------------------------------------------- Technical Imaging Systems SECTION 12: ECOLOGICAL INFORMATION Agfa Division ----------------------------------------------------------- Miles Inc. GENERAL: Not expected to present any significant ecological 100 Challenger Road problems. Ridgefield Park, NJ 07660 ----------------------------------------------------------- (201) 440-2500 SECTION 13: DISPOSAL CONSIDERATIONS ----------------------------------------------------------- ----------------------------------------------------------- COMPAS Code: 25870100 WASTE DISPOSAL: Recover nonusable free liquid and/or contaminated water, and dispose of in an approved and permitted treatment system. Incineration is recommended. Remove nonusable solid material and/or contaminated soil, for disposal in an approved and permitted landfill. Discharge to sewer requires approval of permitting authority and may require pretreatment. ----------------------------------------------------------- SECTION 14: TRANSPORTATION INFORMATION ----------------------------------------------------------- DOT, IMO, ICAO, TRANSPORT CANADA: Non-Regulated NFPA: HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0 SPECIAL: None 4=Extreme 3=High 2=Moderate 1=Slight O=Insignificant ----------------------------------------------------------- SECTION 15: REGULATORY INFORMATION ----------------------------------------------------------- U.S. FEDERAL REGULATION: OSHA: Hazard Communication Rule, 29 CFR, 1910.1200: Section 2, Acetic Acid TSCA: All ingredients in this finished product are listed on the EPA TSCA Inventory (see Section 2) . CERCLA HAZARDOUS SUBSTANCE (40 CFR 302) : Acetic Acid (Reportable Quantity - 5,000 lbs.) SARA TITLE III: Superfund Amendments and Reauthorization Act of 1986 (SARA Title III) requires submission of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313) . SARA HAZARD CATEGORIES: IMMEDIATE (see Section 3, Acute Health Effects) . Components present in this product at a level which could require reporting under the statute are: None ----------------------------------------------------------- CHEMICAL CAS NO. CONCEN- A B C D E F SUBSTANCE TRATION ---------------------------------------------------------- Aluminum Sulfate 10043- X X 01-3 Acetic Acid 64-19-7 X X X X ----------------------------------------------------------- FEDERAL STATE REGULATIONS INTERNATIONAL REGULATIONS ---------------------------------------------------------- A - SARA B = California E = EINECS Proposition 65 F = WHMIS (Canada) C = Florida D = Rhode Island 12/17/96---------------------------—-------------------------------------------------------------------------------------- ProVet-Seattle 212390 NORTHWEST VET CLINIC Page 5 of 7 - - - -- - -- - - - -- - - - -- -- MATERIAL SAFETY DATA '7,ET ----- - - - -- - - - - - - -- ----- Agfa FIXER CONC 2-PART --------------------------------------------------------------------------------------------------------------------------- Agfa G-353C FIXER FOR GEVAMATIC(R) 60 WORKING STRENGTH --------------------------------------------------------------------------------------------------------------------------- #203WS ---- ------------------------------------------- MANUFACTURER: AGFA DIVISION SECTION 5: FIRE FIGHTING MEASURES MILES INC. 100 CHALLENGER ROAD FIRE AND EXPLOSION DATA: Noncombustible RIDGEFIELD PARK, NJ 07660 FIRE AND EXPLOSION HAZARDS: None NON-EMERGENCY TELEPHONES: EXTINGUISHING MEDIA: Any applicable to primary cause of NJ (201) 440-2500 fire. NY (212) 971-0260 SPECIAL FIRE FIGHTING PROCEDURES: Evacuate personnel to a ----------------------------------------------------------- safe area. Keep personnel removed and upwind of fire. SECTION 1: CHEMICAL PRODUCT IDENTIFICATION Wear self-contained breathing apparatus. ----------------------------------------------------------- UNUSUAL FIRE & EXPLOSION HAZARDS: When heated to PRODUCT NAME: G-353C Fixer for GEVAMATIC(R) 60 Working decomposition emission of toxic fumes of S02 is possible. Strength PRODUCT DESCRIPTION: Aqueous Acidic Solution SECTION 6: ACCIDENTAL RELEASE MEASURES FORMULA: 81OO/OlEl ----------------------------------------------------------- BUSINESS GROUP: Technical Imaging Systems SPILL OR LEAK PROCEDURES: NOTE: Review Sections 5 and 8 MEDICAL EMERGENCY TELEPHONE (Poison Center) : (303) 623-5716 before proceeding with clean up. Use appropriate PERSONAL TRANSPORTATION EMERGENCY TELEPHONE (Chemtrec) : 1-800-424- PROTECTIVE EQUIPMENT during clean up. Dike spill. Prevent 9300 liquid from entering sewers, waterways or low areas. Soak ----------------------------------------------------------- up with sawdust, sand, oil dry or other absorbent SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS material. Spill may be neutralized with powdered Sodium (Typical Values) Carbonate. ----------------------------------------------------------- ----------------------------------------------------------- HAZARDOUS INGREDIENTS WT %- ACGIH(TLV) OSHA(PEL)+ SECTION 7: HANDLING AND STORAGE ----------------------------------------------------------- ----------------------------------------------------------- Ammonium Thiosulfate 10-15 25 ppm as 50 ppm as Avoid eye and skin contact, and store in well-ventilated CAS NO.: 7783-18-8 ammonia ammonia area. Keep container tightly closed. Do not store with OTHER IMPORTANT INGREDIENTS: incompatible materials (see Section 10) . Do not store or Water 85-90 *NE *NE consume food, drink or tobacco in area where they may CAS NO.: 7732-18-5 become contaminated with this material. +The PEL limit values listed above are published figures ----------------------------------------------------------- from the 1989 Title 29, CPR 1910.1000, Z list using SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION transitional limits. ----------------------------------------------------------- *None Established RESPIRATORY PROTECTION: None needed with working mixtures -------------------------------------------- ------ and normal room ventilation (10 changes of air per hour) . SECTION 3: HAZARDS IDENTIFICATION VENTILATION: Room ventilation is sufficient. Avoid use of ----------------------------------------------------------- product in unventilated areas. Always control airborne EMERGENCY OVERVIEW: Keep unnecessary people away and upwind levels below the exposure guidelines when reported in of fire. Toxic gases may be emitted when heated to Section 2 (use 50% of the TLV) . decomposition. Some of these materials may burn but none SKIN AND EYE PROTECTION: Splash protection required for of them ignites readily. Follow Section 5 for fire eyes, e.g., eye glasses with side shields or goggles. For fighting measures and Section 6 for accidental release skin protection use chemical resistant gloves and aprons. measures. In case of contact with material, immediately Disposable coveralls are optional, and discard after use. flush eyes with running water for at least 15 minutes. ----------------------------------------------------------- See ERG Guide # 31. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES POTENTIAL HEALTH EFFECTS: ----------------------------------------------------------- ROUTES OF ENTRY: Eye, Skin, Inhalation, Ingestion BOILING POINT: Approx. 221 deg F A. ACUTE EXPOSURE EFFECTS (NOTE: Pertains to Finished MELTING POINT: Not applicable Product) VAPOR PRESSURE: Not estimated EYE CONTACT: May cause irritation. VAPOR DENSITY (AIR=1) : Not estimated SKIN CONTACT: May cause irritation. EVAPORATION RATE: Not estimated INHALATION: Normally no problem, but inhalation of VOLATILE FRACTION BY WEIGHT: Not estimated mist could cause respiratory irritation. SOLUBILITY IN WATER (By Weight %) : 100% INGESTION: May cause irritation of the mucous SPECIFIC GRAVITY (H2O=1) : 1.086 membranes or digestive tract. pH: 4.50 B. CHRONIC HEALTH EFFECTS (NOTE: Pertains to each APPEARANCE: Clear and colorless liquid ingredient listed in Section 2 per 29 CFR Sect. ODOR: Slight sulfur dioxide odor 1910.1200) : A computerized literature search of ----------------------------------------------------------- national databases did not yield any chronic effects SECTION 10: STABILITY AND REACTIVITY associated with these materials. ----------------------------------------------------------- CARCINOGENICITY LISTING: STABILITY: Stable NTP: No INCOMPATIBILITY: Strong alkali IARC: No HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of sulfur, CO2, OSHA: No carbon monoxide, ammonia --------------------—------------------------------------- HAZARDOUS POLYMERIZATION: Will not occur SECTION 4: FIRST AID MEASURES ----------------------------------------------------------- ----------------------------------------------------------- SECTION 11: TOXICOLOGICAL INFORMATION EYES: Immediately flush with plenty of running water for at ----------------------------------------------------------- least 15 minutes. Obtain medical attention. Toxicological properties of this substance have not been SKIN: Flush affected areas promptly with water for 15 fully investigated. minutes. Remove contaminated clothing. In case of continued irritation consult physician. INHALATION: For over-exposure, remove to fresh air. INGESTION: Obtain immediate medical attention. 12/17/96------------------------------------------------------------------------------------------------------------------- ProVet*Seattle 212390 NORTHWEST VET CLINIC Page 6 of 7 ', 1 ---- ---------------- - MATERIAL SAFETY DATA SH �T - - - - ------------------- Agfa FIXER CONC 2-PART ------------------------------------------------.-. - - - --- -- - -------------------------------- FOR TECHNICAL INFORMATION CONTACT: SECTION 12: ECOLOGICAL INFORMATION Technical Imaging Systems ---------------------------------------------------- -- Agfa Division GENERAL: Not expected to present any significant ecological Miles Inc. problems. 100 Challenger Road ----------------------------------------------------------- Ridgefield Park, NJ 07660 SECTION 13: DISPOSAL CONSIDERATIONS (201) 440-2500 ------------- ------------------------------- WASTE DISPOSAL: Recover nonusable free liquid and/or COMPAS Code: 25870110 contaminated water, and dispose of in an approved and permitted treatment system; incineration is recommended. Remove nonusable solid material and/or contaminated soil, for disposal in an approved and permitted landfill. Discharge to sewer requires approval of permitting authority and may require pretreatment. ----------------------------------------------------------- SECTION 14: TRANSPORTATION INFORMATION ----------------------------------------------------------- DOT, IMO, ICAO, TRANSPORT CANADA: Non-Regulated NFPA: HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0 SPECIAL: None 4=Extreme 3=High 2=Moderate 1=Slight O=Insignificant ----------------------------------------------------------- SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATION: OSHA: Hazard Communication Rule, 29 CFR, 1910.1200: Ammonia TSCA: All ingredients in this finished product are listed on the EPA TSCA Inventory (see Section 2) . CERCLA HAZARDOUS SUBSTANCE (40 CFR 302) : None listed SARA TITLE III: Superfund Amendments and Reauthorization Act of 1986 (SARA Title III) requires submission of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313) . SARA HAZARD CATEGORIES: IMMEDIATE (see Section 3, Acute Health Effects). Components present in this product at a level which could require reporting under the statute are: Ammonia ----------------------------------------------------------- CHEMICAL CAS NO. CONCEN- A B C D E F SUBSTANCE TRATION ----------------------------------------------------------- Ammonium 7783-18- 2.25 as X X X Thiosulfate 8 ammonia FEDERAL STATE REGULATIONS INTERNATIONAL REGULATIONS A - SARA B = California E - EINECS Proposition 65 F = WHMIS (Canada) C = Florida D = Rhode Island ---------------------—------------------------------------ SECTION 16: OTHER INFORMATION -------------------------------------------------------------- This information is furnished without warranty, expressed or implied, except that it is accurate to the best of the knowledge of AGFA DIVISION of MILES INC. The data on this sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. AGFA DIVISION of MILES INC. assumes no legal responsibility for use or reliance upon this data. The information herein is provided solely for your consideration, investigation, and verification. 12/17/96--------------------------------------------------------------------- ---------------- ------- - ----------------------- --- ProVet•Seattle 212390 NORTHWEST VET CLINIC Page 7 of 7 I ------- --------- --- ---- MATERIAL SAFETY DATA SL.AET ----------------------- 3M Health Care Group 1426 VETERINARY .X-RAY FILM MANUAL ' FIXER;.REPLENISHER ----------------------------- ----------------------------------------------------------------------------------------- MANUFACTURER'S NAME: ANIMAL CARE PRODUCTS ----------------------------------------------------------- 3M HEALTH CARE GROUP 5. ENVIRONMENTAL INFORMATION 3M CENTER ----------------------------------------------------------- ST. PAUL, MINNESOTA 55144-1000 SPILL RESPONSE: Observe precautions from other sections. 612/733-1110 Ventilate area. Contain spill. Cover with absorbent DUNS NO.: 00-617-3082 material. Collect spilled material. Clean up residue with DIVISION: Animal Care Products Project water. Place in a U.S. DOT-approved container and seal. TRADE NAME: 1426 Veterinar/ X-Rav Film Manual Fixer DISPOSAL ALTERNATIVE: Carefully, with stirring and Re lenisher P cooling, add waste product to a solution of soda ash 3M I.D. NUMBER: 70-2004-1711--I (sodium carbonate) and slaked lime (calcium hydroxide). ISSUED: Mav 31, 1993 Confirm neutrality. SUPERSEDES: August 9, 1991 RECOMMENDED DISPOSAL: Flush spent solutions and small DOCUMENT: 10-2-i>2-0 quantities (lose than 5 gal./19L) to a wastewater ------------------------------ ------------------- treatment system. Discharge neutralized waste product to 1. INGREDIENTS a wastewater treatment system. Dispose of waste product ----------------------------------------------------------- in a facility permitted to accept chemical waste. INGREDIENTS c'.;s.:l. NO. PERCENT ENVIRONMENTAL DATA: No data available. ----------------------------------------------------------- REGULATORY INFORMATION: U.S. EPA Hazardous Waste Number = Ammonium thiooulfate 7783-18-8 30.0 - 50.0 None (Not U.S. EPA Hazardous) . Since regulations vary, Sodium sulfite •7757-83-7 4.0 - 6.0 consult applicable regulations or authorities before Acetic acid 64-19-7 3.0 disposal. Sodium tetraborate 1303-96-4 1.0 - 3.0 SARA HAZARD CLASS: Aluminum sulfate 10043-01-3 1.0 - 2.0 FIRE HAZARD: No ----------- - ------------------------------- PRESSURE: No 2. PHYSICAL DATA REACTIVITY: No ------------------------ ------------------ ACUTE: Yes BOILING POINT: 212.00 F CHRONIC: Yee VAPOR PRESSURE: 17.0000 mmHg ----------------------------------------------------------- VAPOR DENSIT':: 0.60 Air = . 6. SUGGESTED FIRST AID EVAPORATION IL�,TE: N/A ----------------------------------------------------------- SOLUBILITY IN WATER: Complete EYE CONTACT: Immediately flush eyes with large amounts of SP. GRAVITY: 1.270 Water = 1 water for at least 15 minutes. Get immediate medical PERCENT VOLATILE: 46.00% attention. VOLATILE ORGANICS: N/D SKIN CONTACT: Flush skin with large amounts of water. If VOC LESS H2O ,, EXEMPT SOLVENT: N/D irritation persists, get medical attention. pH: 4.85 INHALATION: If signs/symptoms occur, remove person to fresh VISCOSITY: N/D air. If signs/symptomS continue, call a physician. MELTING POINT: N/D IF SWALLOWED: Do not induce vomiting. Drink two glasses of APPEARANCE AND ODOR: Liquid, clear, slight vinegar odor water. Call a physician. ------------------------------------------------------------ 3. FIRE AND EXPLOSION HAZARD DATA 7. PRECAUTIONARY INFORMATION ------------ - ------------ ------------------------- ----------------------------------------------------------- FLASH POINT: IJ :`_ EYE PROTECTION: Avoid eye contact. Wear safety glasses with FLAMMABLE LIMITS: side shields. LEL: N/A SKIN PROTECTION: Avoid skin contact. Wear appropriate UEL: N/A gloves when handling this material. AUTOIGNITION TEMPERATURE: N/D VENTILATION PROTECTION: Use in a well-ventilated area. EXTINGUISHING MEDIA: Non-combustible. Choose material Provide sufficient ventilation to maintain emissions suitable for surrounding lira, below recommended exposure limits. SPECIAL FIRE FIGHTING PROCEDURES: Not applicable RESPIRATORY PROTECTION: Avoid inhalation of airborne UNUSUAL FIRE A14D EXPLOSION HF_Z T<DS: See Hazardous material. Decomposition section for products of combustion. PREVENTION OF ACCIDENTAL INGESTION: Wash hands after NFPA-HAZARD-CODES: handling and before eating. Do not ingest. HEALTH: 1 RECOMMENDED STORAGE: Store away from areas where product FIRE: 0 may come into contact with food or pharmaceuticals. Store REACTIVITY: 0 at temperatures above 32 degrees F (0 degrees C). Keep UNUSUAL REACTION HAZARD: None out of the reach of children. ----------- --------- ------------------------- FIRE AND EXPLOSION AVOIDANCE: Not applicable. 4. REACT,-.L7'Y DATA ----------------------------------------------------------- STABILITY: Stah.le INCOMPATIBILITY - MATERIALS TO AVOID: Strong Bases HAZARDOUS POLYMERIZATION: Will Nor_ Occur HAZARDOUS DECOMPOSITION PRODUCTS: carbon Monoxide and Carbon Dioxide, Oxides of Sulfur, Ammonia, Ammonium Salts, Hydrogen Sulfide 3/28/95------------------------------------------------------------------------------------------------------------------- MWI VETERINAk'i :SUPPLY 1748018 NORTHWEST VET CLINIC/STANWOOD Page 1 of 2 -- - - - - - - - - - - - - MATERIAL SAFETY DATA SRAT ----------------------- 3M Health Care Group 1426 VETERINARY X-RAY FILM MANUAL a F I7($R. .-RRPLEN I S=R ------------ - ---------------------------------------------------------------------------------------- -------- ------ - ------------------------ WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR EXPOSURE LIMITS MORE OF THE INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND INGREDIENTS VALUE UNIT TYPE AUTH SKIN* ARE REQUIRED TO BE INCLUDED ON THE MSDS BY THE U.S. OSHA ------------ ---------------- •------------------------ HAZARD COMMUNICATION STANDARD, THEY ARE NOT EXPECTED Ammonium None None None None EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT. thiosulfate KIDNEY EFFECTS: Signs/symptoms can include reduced Sodium Sulfite None None None urine volume, blood in urine and back pain. Acetic acid 10 TWA ACGIH CENTRAL NERVOUS SYSTEM DEPRESSION: Signs/symptoms can Acetic acid 15 STEL ACGIH include headache, dizziness, drowsiness, muscular Acetic acid 10 TWA OSHA weakness, incoordination, slowed reaction time, Sodium tetraborate 5 mg,/m., TWA ACGIH fatigue, blurred vision, slurred speech, giddiness, Sodium tetraborate 10 uig/m; TWA OSHA tremors and convulsions. Aluminum sulfate 2 mg/m3 TWA ACGIH REPRODUCTIVE/DEVELOPMENTAL TOXINS: Sodium tetraborate as Al decahydrate (1303-96-4) is a potential reproductive Aluminum sulfate 2 mg/m7 TWA OSHA hazard causing male reproductive effects and fetal growth as Al retardation by the oral route of exposure in laboratory * SKIN NOTATION: Listed substance:; indicated with "Y" under studies. There is not evidence of such effects in humans. SKIN refer to the potential aa:cribution to the overall --------------------------------------------------------—- exposure by Li-, cutaneous rcur, i:.cluding mucous membrane SECTION CHANGE DATES and eye, either by airborne e.r, more particularly, by ----------------------------------------------------------- direct contact a,ith the subst,mnce. Vehicles can alter Skin HEADING: Section Changed Since August 9, 1991 Issue absorption. FIRE & EXP. DATA: Section Changed Since August 9, 1991 SOURCE OF EXPOSURE LIMIT DATA: Issue - ACGIH: American Conference of Governmental Industrial REACTIVITY DATA: Section Changed Since August 9, 1991 Ieeue Hygienist ENVIRON. DATA: Section Changed Since August 9, 1991 Issue - OSHA: Occupational Safety and Health Administration FIRST AID: Section Changed Since August 9, 1991 Ieeue - NONE: None Established PRECAUT. INFO.: Section Changed Since August 9, 1991 Issue ---------------------------------------------—------------ HEALTH HAZD. DATA: Section Changed Since August 9, 1991 8. HEALTH HAZARD DATA Issue ---------------------------------------------------------- ----------------------------------------------------------- EYE CONTACT: The information in this Data Sheet represents our current SEVERE EYE IRRITATION: Signs/symptoms can include data and best opinion as to the proper use in handling of redness, swelling, pain, tearing, cloudy appearance of this material under normal conditions. Any use of the the cornea, impaired vioi.,i and possible permanently material which is not in conformance with this Data Sheet impaired -anion. or which involves using the material in combination with SKIN CONTACT: any other material or any other process is the MILD SKIN REACTION: Signs,'s%-mptoms can include redness, responsibility of the user. Swelling, and itching. Mai be absorbed through the ----------------------------------------------------------- Skin. ABBREVIATIONS: N/D - Not Determined N/A - Not Applicable PROLONGED OR REPEATED EXPOSURE NAY CAUSE: ----------------------------------------------------------- ALLERGIC SF.IN IRRITATION: signs/symptoms can include DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: Although redness, swelling, blistering, and itching. reasonable care has been taken in the preparation of this INHALATION: document, we extend no warranties and make no IRRITATION (upper respiratory) : Signs/symptoms can representation as to the accuracy or completeness of the include soreness of the nose and throat, coughing and information contained therein, and assume no responsibility sneezing. regarding the suitability of this information for the WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR user's intended purposes or for the consequences of its MORE OF THE INDIVIDUAL INGR,E,DIENTS IN THIS PRODUCT AND use. Each individual should make a determination as to the ARE REQUIRED TO BE INCLUDED ON THE MSDS BY THE U.S. OSHA suitability of the information for their particular HAZARD COMMUNICATION STAND..!tU, THEY ARE NOT EXPECTED purpose(s). A request has been made to the manufacturer to EFFECTS DURIN,; FORESEEABLE U:;1 )F THIS PRODUCT. approve the contents of this material safety data sheet. ASTHMATIC-LIP_E REACTION: ,,ign:.,symptoms can include Upon receipt a new MSDS will be made available. difficult,.- breathing, whe---ins;, tightness of chest, and ----------------------------------------------------------- respirato r,- failure. COMPAS Code: 93800120 NAC Approved Date: IF SWALLOWED: IRRITATION OF GASTROINTESTINAL TISSUES: Signs/symptoms can include pain, vomiting, n.yusea, abdominal tenderness, nausea, blood in vomitus, and blood in feces. ASTHMATIC-LIKE REACTION: Signs/symptoms can include difficulty breathing, wheezing, tightness of chest, and respiratory failure. INGESTION MAY CAUSE: DAMAGE TO GASTROINTESTINAL TISSUES: Signs/symptomB can include pain, vomiting, nausea, abdominal tenderness, burns •nf mouth, difficult}- ❑wallowing, blood in vomitus,, blood in feces, an.l ulceration. ESOPHAGEAL BURNS: Signs/symptoms can include pain in throat, difficult swall--win(j and blood in sputum. BURNS OF THE ORAL TISSUES: Signs/symptoms can include pain, burns of tongue and inside of mouth, redness and tissue lose. 3/28/95-------------- ---------------------------------------------------------------------------------------------- MWI VETERINARY SUPPLY 1748018 NORTHWEST VET CLINIC/STANWOOD Page 2 of 2 --� =. -� �i N E y b �� L • ORMALDEHYDE SECn N I Pltyllcal palR sEenoN T Reactivity Dal■ Appeannoe Clcar,babrkas liquid. Stablllly: )DUCT 1 D E NM FI CA-n O N: Stable under ordinary coodlllons of use sad storage. Odor. PuntcaL Synonym+: Formaldehyde solution;Formaldehyde JIM Formalin; Solubilltye Infinite Is rarer. Hazardous Decompaslllan Products: Morlsacid Acid If involved in a fare,irritating gaseous formaldehyde and carbon Boiling Point: WC(7IIf'l) Mermaids may be rglcascd. Formula CAS No.: 30-00-0 Melling Point: -LS*C(S'P) Hazardous PolymerisalloLl Molecular Weight:3003 Specific Gravity(wamrw l):1.01 Trioryrecihylent p(Wf;uAate can tts formed on long u.ndtng aI Vapor(cattily(At&-I):: L04 very low tempcntuccu Nookssardovi polymcnsat000 may occur al Chemical Formula:CH.O lour icmpe"tutct,forming pan(orou Wch)dc,a white(did Vapor Pressure(man HO No informallon found. Hazardous Ingredients: evaporstiaa Bale: No la(ormation found. Inrnmpatlblllllev CAS f 67.56-1 Methanol(10-13%) Incompatible rein oodiung agents and dkaliea. Rucu 50.004 Formaldehyde(77%) SIECTION 2 Flre and trulaslan Informetlort caplotivcly nth nilrogcs doi"c at ca.IWC(IM'F).Rcaas PRECAO'nQNARY MEASURES v"cnily n,h perchlore hod.pe rthlone aced-+relit se ml<t—, Floe: .cad nuromc(h.nt.R,"locas nth Aydrochlonc acid may form FOTIENTIAL CANCIL lu3AAD. Combustible Liquids biashbrometfoys other,as OSIIA regulated omiaogea oANr.X^f AIAV as FATAL if SJVA11AVVL1k I1ARwIFVL IF Flashpaat:60'C(140•P)(10%Methanol) IM«ALAD On Assottl LD'nalta oil SKIN.CAUSLS IItAITATION Awosgnuinn temptreouroC 300'C(ST2'F) r-11()N s ltxk/Solll f)I llui till Infnrmnjln___gr TO SK1N,LyES AND RLSpILATDItV TRACT.SLNSITIZLIL Mentionable limits in air,A by volumes AIAV CAUSi a1JNOleLSS. COAleurnaLL, k1:7.0 wi:73 Vensilale area of kakorspill.RgaOu t all sources at Gas vaporizes readily(ran solution and is flammable in air. Keep away from heat,tparl'a and Dame. ignition.Clean-up peraaend require protective clothing and Avoid breathing vapor- Explosion: resptruory,pmicclw•from"pow Only speaally trained or Keep container closed. Above flash pant,vaposvair minus art explosive within q-1,6cd personnel mould handle the<—rtcr y.Do caw IIuM Use only most adequate venulauon. flammable limits noted above. m,c veer or..'face wain!can to. O—O.d on inert mated Wash thoroughly after handling. and disposed as harardouia w.xrs in a RCRA approved Iaa,ily Or F M R G E NCY/FI R ST A I D Fire Extinguishing Media: dissolved in an■ppr000.ic comovulbk volvenl and.lomued in Water spray oa be used to extinguish Giro and coal ftresuposcd a RCRA approved ckcsccat inrnarasur equipped wills s■ coauiaers. Water spray may be used to keep fire exposed daerbumer. Rcpnnaok Osuiimy(RO)(CWA/C£RCLA):101bL In all czaca can.prey,clan, If r✓adOwed,induct vomrung containers COOL formaldehyde 30110IbL Mssnuaol immediately by giving two gla"c4 of otter and atKk,ng finger down into•(, Never give anyining by mouth to an uncOrucwua person. If Special Infannallaa: inhaled,remove to fresh air. If not breathing,give artificial In the event of a fare,wear fun protective clothing and Ps+tire compliance silty brat slats and federal regulation! ,tap,rauon.If breathing is difficult,give oaytcn. In case of NIOS11-approved self-abauined breathing apparels with full coma,immediately flush skin or cyc.can h plenty of water for as facepiecei operated In the pressure demand or other positive least IS miou cs. pfcaaurt mode. Water may t<used to(lu.h split&away from SEE SECTION S. crposures and todiluse(pills to now-i1xmnrable mwurra. DOT Hazard Class: ORM-A �'QN S S[talihllsatdln[unmdu❑ B. FIRSTAID Ventilation Systern: A"%,am of meal and/or gtaeraf css•via a recommended to keep _eJ�QSC7RE/HEALTH EFFECT$ Inhalation: employee crposeres below t►e Airborne Faposure limit! Local The perctptioL of formaldehyde by odor And eye iraritslion Remove to fresh sir. If not breathing.give anlfkiml the emissions sionvent aWn a gencrany potency bceaute it can control becomes test tensll1w nth lime so cont adapts to formaldehyde. respiration.If breathing la diMcuk give oxygen,Calla the er ion Of t><the contsmwant o ill foi.ree,preventing This can lead so overeapaure if a worker ls relying on physician. dispersion c it iota the gtnc(al work arts. Please refer I1 she formaldehyde's waming properties to alto him or her to the ACGIII document,9nd ditnal Ventilatun,A Maraud of Recommended Ingestion: Practices',molt recent editiorti for deleil! potential for erposum. If swallowed,induce vomiting iamedialely by giving two Inhalnllon: glasses a(otter.or milt w i( aiMie end tucking finger Personal Respirators: (NIOSII Approvedl down ihrosi. Call a physician Immediately. Never give If the P[il.is exceeded,a fulFfacepiece respiutor with cartridges May cause sore Ihroat,coughing,and shortness of breath.Causes anything b mouth to an uneonaioua non. irnistion to the respiratory Iran.Concenmtiotx of 25 to 50 r t 1 Pe formaldehyde canisters e a y be approved for praeelion against ppm cause severe resptntory tract injury leading 10 pulmonary Skin Expoeure: formaldehyde maybe worn it a con«nirations of 10 ppm(IOX Pf:L). edema and pneumomus..May be foul in high coneentreuont, In case of comae/,immadinely flush skin wish plenty of wile r See US[LA Standard for Additional Information. fur at least IS minutes while removing contaminated clothing Skln Protection: Ingestion: and shoes. Wash clothing before reuse Thorougbly clean shoes Can cause severe abdominal pain,violent vomiting,headache,and before reuse.Get medical mention immediately. Wear impervious protective clothing•including boots•gloves,lab diarrhes.I-irger doses may produce decrcaaed body temperature, coal,apron or coveralls to prevent skin contact. lain in the digestive Ina,shallow respiration•weak irr guiar Eye Exposurv: Eye Protectinn: gulse,unconscuousmcas and death.Methanol component alfcns the Wash ctcs—th plenty 0(water for at least IS minutes,lifting y optic nerve and may cause blindness lower and upper eyelids oeauonatly. Get medical attention Use chemical safety goggles and/or a full face shield where immediately. splashing is possible. Contact knsa should not be worn when ,kin Contact: working wnlh this malarial. Mainuin eye wash foumain end fosic May cause imlation to skin nth redness,pain.and C. TOXICITY DATA (RTECS,1996) qutckdrench(■cililicl in work area po,,,bly horn,.Skin abwrpaon nuv OCeur—In Iymptonn Formaldehyde:Oral rat LD5Q 1100 mg/kg. Skin See OSI IA Standard for mom Information On Personal proteclow parallcimg;nose from mgcst,an.1'ormatdanyoe u a tcvcrc skin ration L050 2'0 mg/kg- Inhaiuwn rat LC&.590 equipment,engmeenng and work pnautcc<onlroh,medical ,r-unt and t<nsq,ter.Conuci causes wnoc discoloration tng/mi titulelwn references cited Rc rodud,ve F surveillance,record kecpmg,and reponmg requirements.(29 CFR smarting,cracking and scaling• elfecil cited_ Tumong<mc caw$ales. Camnogenle 191010481 determination(Formaldehyde (Sufficienl evidence in gas Eye Cirnlatl: animet&-Inadequ.tc rndence is humans (IARC Supplement d, SECTION 7 Slornet and Spot.(Infnrmnilon Vapon cause irnealion to the eyes with redness•pain,and 1982 Category 10)bated In she NU fin nnual Report on blurred vision.I ligher concennauoix or splashes may cause Camnokens:May reason•osy be an icipaled to be■ Keep in a ugh4ly closed container. Protect agamsi i—eweniblc eye damage. carcnnotcn. An OSIIA rcpialedoranogen Methanol:Mutslion physical damage. Outside or detached storage is preferred. Inside Chronic Exposure: and reproducirw effects cited. storage should be in a standard flammahle liquids storage room tor Frequent or prolonged erposure to formaldehyde may cause SECTION 5 Qccunsdonsl Conlrgi hlensure3 cabinet. Separate from onduing materials.Storage and use areas hypersensit—ly lending to conucl dermiuus. Repeated or Airboshould be No Smoking In aL Wear spenal protective equipment prolonged s►m contact wish formaldehyde may cause an a0ugic -OSILrne Expose Limits:U (See 61 for mainis,nence break m orwhere erposures may exceed reaeinsn m some people.Vision impairment and enlargement of OSIU Pennmible Pspoaure Limit(P2L): established erposure IeveLL Wash hands,face•fam.rma and neck liver may occur from methanol component.Formaldehyde is a 1 ppm(TWA).2 ppm(STU)formaldehyde when erling resincied areas.Shower,dispose of ouler clothing, suspected carcinogen(positive animal inhalation studies). 200 ppm(TWA),ISO ppm(STEL)skin(or methanol change to clean garments at the end of the day Avoid -ACGIII Threshold Urnil Value(TI.Vx crosstantam,nallaro O(street combes.Wash hands before tatting and ALereratlon of Preng ski di Conditions:o ores: I ppm(TWA)2 ppm ISM)farmaldehTds �4.rein pnsetsting skin disorders or<vt proolcros,or do nos cot,drink,or croaks in workplace. Protect from(feeling— listed In Appendix Al as Industrial Substances ••••••••••••••.....•••.••••..•••.••.•....•..•.••.•.•••FORMA a,cd liv<Q kidney of reaPlrelOry fYOCIiOn cosy be more �.quble lathe chess of the substance.Prcvnou,iy exposed Suspect of Ctsremogemc Paettsial for Met! peraom may haw an alkrfie reaction to(uturc crtsosurcL -00 ppm(TWA)250 ppm(S7EL)skin for methanol NFPA RaUnts: Itc■Ith: 2 Plannabdiiy- 2 Rucnvliy: 0 Effective Date:04-00-89 Superscdcs01-20-88 FORMALDEHYDE PAGE 2 OF 5 SAGT14 a FIRS AND EXPLOSION DATA. FLASH POINT NON-FLAMMABLE ' LbWER. EXPLQSIVE LIMIT UPPER EXPLOSIVE LIMIT N% N/A EXTINGUISHING MEDIA CO2, FOAM, WATER UNUSUAL FIRE AND EXPLOSION HAZARDS WEAR SELF-CONTAINED BREATHING APPARATUS IF MATERIAL IS PRESENT IN A FIRE. EVACUATE AFFECTED AREA. SPECIAL FIRE FIGHTING PROCEDURES WEAR SELF-CONTAINED BREATHING APPARATUS SECTION 5 HEALTH HAZARD DATA HEALTH HAZARDS (ACUTE & CHRONIC) CAUSES EYE BURNS. HARMFUL IF INHALED OR ABSORBED THROUGH SKIN. CAUSES GENERAL TISSUE DAMAGE. CAUSES SKIN, NOSE, THROAT AND LUNG IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED. CANNOT BE MADE NON-POISONOUS. -INHALATION 4-HOUR LC50...478 PPM RATS; -SKIN ABSORPTION LD50...270 MG/KG IN RABBITS; -ORAL LD50...500 MG/KG IN RATS. PRIMARY ROUTES OF EXPOSURE EYES, SKIN, INHALATION AND INGESTION. SIGNS AND SYMPTOMS OF EXPOSURE -THE PRODUCT IS CORROSIVE TO THE EYE, IS A SKIN IRRITANT AND IS LIKELY TO BE A SKIN SENSITIZER. TOXIC EFFECTS DESCRIBED IN ANIMALS FROM EXPOSURE INCLUDE SEVER IRRITATION OF MUCOSAL SURFACES, IRRITATION OF THE LOWER RESPIRATORY TRACT, LIVER EFFECTS, ACIDOSIS, POSSIBLE BLINDNESS, AND NON-SPECIFIC PRETERMINAL EFFECTS. -HUMAN HEALTH EFFECTS OF OVEREXPOSURE TO FORMALDEHYDE VAPORS MAY INITIALLY INCLUDE EYE IRRITATION WITH DISCOMFORT, TEARING, IRRITATION OF THE UPPER RESPIRATORY PASSAGES, AND DISCOMFORT, SUCH AS NAUSEA, HEADACHE, OR WEAKNESS SKIN CONTACT WITH FORMALDEHYDE SOLUTIONS MAY PRODUCE IRRITAIIOP: WITH DISCOMFORT FORM:M5052 1"59) Continued on Next Page FORMALIN, 10% BUFFERED PAGE 3 OF 5 SECTION 5 - HEALTH HAZARD, DATA (CONTINUED) MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE -PRE-EXISTING DISEASES OF THE LUNGS OR SKIN MAY HAVE AN INCREASED SUSCEPTABILITY TO THE TOXICITY OF EXCESSIVE EXPOSURE. CARCINOGENICITY NTP IARC OSHA Yes No Yes 0 No Yes ❑ No -FORMALDEHYDE IS LISTED BY THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER AS PROBABLY CARCINOGENIC TO HUMANS ON THE BASIS OF ANIMAL EVIDENCE BUT HUMAN DATA IS INADEQUATE. LISTED BY THE NATIONA TOXICOLOGY PROGRAM AS REASONABLY ANTICIPATED TO BE A CARCINOGEN. LISTED BY ACGIH AS AN A2 INDUSTRIAL SUBSTANCE SUSPECTED TO BE CARCINOGENIC TO HUMANS. EMERGENCY AND FIRST AID PROCEDURES -EYES: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CONTACT A PHYSICIAN. -SKIN: IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CONTACT A PHYSICIAN. -INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CONTACT A PHYSICIAN. -INGESTION: INDUCE VOMITING IMMEDIATELY. GIVE ACTIVATED CHARCOAL SLURRY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON, CONTACT A PHYSICIAN, (NOTE: TO PREPARE AN ACTIVATED CHARCOAL SLURRY, SUSPEND 5C GM OF ACTIVATED CHARCOAL IN 400 MIL WATER AND SHAKE WELL.) THRESHOLD LI-MITS / TOXICITY DATA S-HOUR TIME-WEIGHTED AVERAGE: 1 PPM; -15-MINUTE SHORT-TERM EXPOSURE: 2 PPM. SECTION 6 -- REACTIVITY DATA STABILITY Unstable E3 Stable b CONDITIONS TO AVOID NONE INDICATED INCOMPATIBILITY (MATERIALS TO AVOID) -REACTS WITH MANY COMPOUNDS. REACTIONS WITH PHENOL, STRONG ACIDS OR ALKALIS MAY BE VIOLENT. REACTION WITH HYDROCHLORIC ACID MAY FORM BIS-CHLOROMETHYL ETHER, A CARCINOGEN. ro-M Continued on Reverse Side 1641 PAGE 4 OF 5 5t4CTJC?tV 6 - REACTMt �7ATA (Gt)NTINLJED) HAZARDOUS DECOMPOSITION OR BYPRODUCTS OCCURS SLOWLY AT ELEVATED TEMPERATURES, RELEASING FORMALDEHYDE GAS. HAZARDOUS POLYMERIZATION May Occur 0 Wi11 Not Occur CONDITIONS TO AVOID NONHAZARDOUS POLYMERIZATION MAY OCCUR AT LOW TEMPERATURES, FORMING PARAFORMALDEHYDE, A WHITE SOLID. SECTION 7 '- SPJLI_ LEAK, AND DISPOSAL PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED KEEP UPWIND AND EVACUATE AREA UNTIL GAS HAS DISPERSED. SOAK UP SMALL SPILLS WITH EARTH, SAND OR OTHER NON NON-COMBUSTIBLE ABSORBENT MATERIAL AND REMOVE IN COVERED METAL CONTAINERS. DIKE LARGE SPILLS AND NEUTRALIZE WITH DILUTE SOLUTIONS OF SODIUM SULFITE OR SODIUM BISULF!TE. FLUSH AREA WITH WATER. WASTE DISPOSAL METHOD TO BE PERFORMED IN COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS 5ECTiUN 8 - SPE IAL PRO i E4 i-ION INFORMATION RESPIRATORY PROTECTION USE AIR PURIFYING OR AIR-SUPPLIED RESPIRATOR IF EXPOSURE LIMITS ARE EXCEEDED. LOCAL VENTILATION YES MECHANICAL VENTILATION YES SPECIAL VENTILATION NOT GIVEN FOAM MSOS610019) Continued on Next Page J`P___�-FORMALIN, 10% BUFFERED PAGE 5 OF 5 S>rCTION > SPE£'AL PROTEC'rtON INFORMATION (CONTINUED) OTHER VENTILATION USE ADEQUATE VENTILATION TO KEEP FORMALDEHYDE CONCENTRATIONS BELOW THE INDICATED EXPOSURE LEVELS. IF LIMITS MAY BE EXCEEDED, USE A FULL-FACE AIR PURIFYING RESPIRATOR WITH CARTIOGES APPROVED FOR FORMALDEHYDE OR SUPPLIED-AIR RESPIRATOR. PROTECTIVE GLOVES NEOPRENE OR BUTYL GLOVES. EYE PROTECTION CHEMICAL SPLASH GOGGLES. OTCO R PRLLS WCTIVE CLOTHING OR EQUIPMENT S. SECTION 9 SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE KEEP CONTAINER CLOSED AND STORE AWAY FROM HEAT AND OPEN FLAME. -DO NOT GET IN EYES. -AVOID CONTACT WITH SKIN AND CLOTHING. -AVOID BREATHING MIST OR VAPOR. -WASH THROROUGHLY AFTER HANDLING. SECTION Ip OTHER INFORMATION' MISCELLANEOUS INFO. SIGNS•SYMPTOMS OF EXPOSURE(CONTINUED! MAY INITIALLY INCLUDE ITS IRRITATION WITH DISCOMFORT,TEASING. IRRITATION 0°THE IMPER RESPIRATOPV-ASSAGEE AMC)DISCOMFORT,SUCH AS NAUSEA,HEADACHE OR WEAKNESS SKIN CONTACT WITH FORMALDEHYDE SGUTIONS MAY PRODUCE IMITATION WITH DISCOMFORT 00 RASH EYE CONTACT WITH SOLUTIONS CAN CAUSE SLURRING OR VISION HIGHER CONCENTRATIONS MAY CAUSE CORNEAL OR CONJUNCTIVAL ULCERATION,TEMPORARY LUNG IRRITATION WITH CAUGH DIFFICULTY IN BREATHING OF SHORTNESS OF BREATH GROSS OVEREHPOSURC MAT BE FATAL tlWUhMAHUN, UAIA ANU RECOMMENUA11UNSHEREINC NAMED MANUFACTURFR ON THIS MATERIAL SAFETY DATA SHEET. CMS MAKES NO WARRANTY OF ANY KIND WHATEVER WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON. CMS RESERVES THE RIGHT TO REVISE THIS MATERIAL SAFETY DATA SHEET AS NEW INFORMATION IS PROVIDED TO IT BY ITS MANUFACTURER. 1643 I Section V-Reactivity Data Stability Unstable Conditions to Avoid Stable X Stable under normal conditions of use.No dangerous reaction known under normal conditions of use. Incompatibility(Materials to Avoid) n/a Hazardous Decomposition or Byproducts n/a Hazardous May Occur Conditions to Avoid Polymerization Will Not Occur X Section VI-Health Hazard Data Route(s)of Entry: Eyes? Inhalation? Skin? Ingestion? May cause eye irritation Avoid inhalation of dust Harmful if absorbed through skin. Avoid ingestion Avoid contact with skin,eyes,clothing. Health Hazards(Acute and Chronic) None noted Carcinogenicity: unknown NTP? IARC Monographs? OSHA Regulated? Signs and Symptoms of Exposure In severe cases of overexposure by oral ingestion,lethargy,muscle tremors,and in extreme cases,possibly convulsions,may occur, Medical Conditions Generally Aggravated by Exposure None noted Emergency and First Aid Procedures If swallowed:Give 1 or 2 glasses of water and induce vomiting by touching back of throat with finger. Do not induce vomiting or give anything by mouth to an unconscious person.Call a physician and follow advice. If on skin:Wash with plenty of soap and water.Call a physician if irritation persists. NOTE TO PHYSICIAN:There is no specific antidote.All treatment should be based on observed signs and symptoms of distress in the patient. Administer medicinal absorbent charcoal.Overexposure to materials other than this product may have occurred. Section VII-Precautions for Safe Handling and Use Steps to Be Taken in Case Material Is Released or Spilled Sweep up spilled product,transfer to a marked container and seal.Make arrangements for return to Rhone Merieux for proper disposal.Wear gloves,waterproof clothing,face shield,goggles,mask with cartridge.Recover the product by pumping,suction or absorption using a dry and inert absorbent clay. Absorb the leakage using dry sand or earth.Shovel up and place into a labeled tightly closed container. Waste Disposal Method Container disposal:Completely empty container into application equipment. Dispose of empty container in a sanitary landfill or by incineration,or if allowed by State and Local authorities,by open burning. If container is burned,stay away from and do not breathe or contact smoke. Precautions to Be Taken in Handling and Storing Wear nitrile or latex gloves and face protection(face shield)when handling solutions.Avoid all contact by mouth. Do not eat,drink or smoke when handling product.Wash hands and exposed skin before eating,drinking or smoking and after work.Wash all protection clothing thoroughly after use.Recommeded material for packaging:high density polyethylene. Other Precautions Do not contaminate ponds,waterways and ditches with chemical or used container.Have available equipment to facilitate safe handling of spillages.Dispose of all contaminated materials according to local authority/regulation. Section VIII-Control Measures Respiratory Precaution(Specify Type) None noted Ventilation Local Exhaust normal exhaust Special Mechanical(Generao Other Protective Gloves none noted as required Eye Protection none noted as required Other Protective Clothing or Equipment See Section VII:Precautions to be Taken in Handling and Storing Work/Hygienic Practices See Section VII:Precautions to be Taken in Handing and Storing OTHER ENVIRONMENTAL HAZARD: This product is toxic to aquatic organisms(fish and invertebrates).Do not apply directly to water or to areas where surface water is present or to intertidal areas below the mean high water mark. Runoff from contaminated areas may be hazardous to aquatic organisms in neighboring areas.Cover,incorporate or clean up product that is spilled during loading or are visible on soil surface in turn areas.Do not contaminate water when disposing of equipment wash water. STORAGE REQUIREMENT: Keep unused product in original container only,out of reach of children. ANIMAL TOXICITY:LD50 Oral(rat)mg/kg:>5,000;LD50 Dermal(rat)mg/kg:>2,000;LC5e Inhalation(4 hr)(rat)mg/I:>5.06,Eye irritation:not irritant(rabbit), Skin irritation:not irritant(rabbit);Skin sensitization:not allergen(guinea-pig) TRANSPORTATION: RID/ADR Class:3,Enumeration:3eb), Label:3, MARITIME Class:3.2,UN Num:1219, Label:Flammable liquid,IMDG Page:3244,Marine Pollutant:No AIR Class:3,UN Num 1219,Packaging group:II, Label:3 Flammable liquid The information contained herein is considered to be correct as of the date of this data sheet but does not purport to be all inclusive and shall be used only as a guide No warranty is expressed or-mphr regarding the accuracy of this data or the results to be obtained from the use thereof. Rhone Merieux,Inc.assumes no responsibility for damages caused by the use,storage or disposal of the product in a manner not recommended on the product label. Users assume all risks associate, with such unrecommended use,storage,or disposal of the product Fipspray.doc MATERIAL SAFETY DATA SHEET U.S. Departr '?t of Labor May be used to comply with Occupational Safety...d Health Administration OSHA's Hazard Communication Standard, (Non-Mandatory Form) 29 CFR 1910.1200. Standard must be Form Approved consulted for specific requirements. OMB No. 1218-0072 ENTITY(As Used on Label and List) n/a r rue Name: Fipronil 0.29% w/w Trade Name: Frontline®Spray Treatment Section I Manufacturer's Name Emergency Telephone Number Rhone Metieux, Inc. (800) 934-4447 Address(Number,Shoot City,State and ZIP Code) Telephone Number for Information Transtech Dnve Athens, GA 30601 (706) 548-9292, ext. 265 Date Prepared D9/16/96 Signature of Preparer(opl section 11-Hazardous ingredientsiIdentity information COMPOSITION:Fipronil 0.25%w/v, isopropanol Hazardous Components(Specific Chemical Identity,Common Name(s) OSHA PEL ACGIH TLV Other Limits Recommended %(OPti-4 Isopropanol CAS#67-63-0 80 v/v (73 wAv) Section III-Physical/Chemical Characteristics Boiling Point 82eC(18WF) Specific Gravity(H20=1) 0.859 g/ml Vapor Pressure(mm Hg.) 42.5 hPa @ 200C Melting Point data not required by EPA or Density(AIR=1) data not required by EPA Evaporation Rate data not (Butyl Acetate=1) required by EPA ,Solubility in water Soluble Appearance and Odor clear,colorless to slightly yellow liquid;odor of alcohol Section N-Fire and Explosion Hazard Data Flash Point(Method Used) 64eF(18°C) Flammable Limits LEL UEL (Pensky-Martens Closed Cup Tester) Autoignition temperature 4590C Extinguishing Media r Foam,carbon dioxide,dry powders,water spray Special Fire Fighting Procedures Flammable,danger of toxic gases in smoke:carbon and nitrogen oxides,hydrofluoric and hydrochloric acid.Co;tain the spread of the fire-fighting media.Wear self-contained breathing apparatus.Cool containers exposed to fire with sprayed water.Risk of explosion of containers exposed to fire. Unusual Fire and Explosion Hazards Risk of explosion of containers exposed to fire. Danger of toxic gases in smoke:carbon and nitrogen oxides,hydrofluoric and hydrochloric acids. (Reproduce locally) RHONE MER/EUX OSHA 174,Sept 1955 FIPSPR.DOC Section V-Reactivity Data Stability Unstable Conditions to Avoid - Stable X Stable under normal conditions of use.No dangerous reaction known under normal conditions of use. Incompatibility(Materials to Avoi) n/a - Hazardous Decomposition or Byproducts n/a - Hazardous May Occur Conditions to Avoid Polymerization Will Not Occur X Section VI-Health Hazard Data - Routes)of Entry. Eyes? Inhalation? Skin? Ingestion? May cause irritation Avoid inhalation of spray Avoid contact,may cause irritation Prevent ingestion Health Hazards(Acute and Chronic) None noted Carcinogenicity. unknown NTP? IARC Monographs? OSHA Regulated? Signs and Symptoms of Exposure In severe cases of overexposure by oral ingestion,lethargy,muscle tremors,and in extreme cases,possibly convulsions,may occur. Medical Conditions Generally Aggravated by Exposure None noted Emergency and First Aid Procedures After contact with skin,wash immediately with plenty of water.In case of contact with eyes,rinse immediately with pla'ltty of water and seek medical advice.If swallowed,induce vomiting if victim is conscious,ensuring protection of respiratory passages(risk of solvent pneumopa:liy).If Ingested,administer medicinal absorbent charcoal.In cases of respiratory difficulties,administer oxygenotherapy.Check the victim's state of consc;ojsness, breathing and pulse,administer CPR if Indicated.Seek medical advice immediately(show label)in case of accidental exposure or if victim feels unwall following exposure.NOTE TO PHYSICIAN:There is no specific antidote for ffpronil,the active ingredient;symptomatic treatment. Section VII-Precautions for Safe Handling and Use Steps to Be Taken in Case Material Is Released or Spilled In case of accidental release:Wear gloves,waterproof clothing,face shield,goggles,mask with cartridge. Recover the product by pumping,suction or absorption using a dry and inert absorbent clay.Absorb the leakage using dry sand or earth.Shovel up and place into a labeled,tightly closed container.Dispose of material as noted below. Waste Disposal Method Manufacturer's packaging must be rinsed our after emptying. Incineration in a licensed installation,product and contaminated packaging. Precautions to Be Taken In Handling and Storing Handling-When using do not eat,drink or smoke. Storage:Keep out of reach of children. Keep container tightly closed and in a well ventilated place.Keep away from source of ignition-no smoking.Recommended material for packaging:high density polyethylene. Mar Precautions Do not contaminate ponds,waterways and ditches with chemical or used container.Have available equipment to facilitate safe handlirg of spillages.Dispose of all contaminated materials according to local authority/regulation. Section VIII-Control Measures Respiratory Precaution(spec fy Type) Extract vapors at their point of emission. Ventilation Local Exhaust Provide. Special Mechanical(Generar7 other Provide adequate ventilation. Protective Gloves Should be wom. Eye Protection Face shield and goggles when cleaning a spill. Other Protective Clothing or Equipment Wear mask with cartridge and water proof clothing,in addition to eye protection,when cleaning up a spill. Work/Hygienic Practices When using,do not eat,smoke or drink.Wash hands after use. OTHER ENVIRONMENTAL HAZARD: This product is toxic to aquatic organisms(fish and invertebrates).Do not apply directly to water or to areas where surface water is present or to Intertidal areas below the mean high water mark. Runoff from contaminated areas may be hazardous to aquatic organisms in neighboring areas.Cover,Incorporate or clean up product that is spilled during loading or are visible on soil surface in turn areas. Do not contaminate waterwher°,disposing of equipment wash water. STORAGE REQUIREMENT: Keep unused product In original container only,out of reach of children. ANIMAL TOXICITY:LDso Oral(rat)mg/kg:>5,000; LDso Dermal(rat)mg/kg:>2,000;LCso Inhalation(4 hr)(rat)mgA:>5.06,Rabbit ocular irritancy:t,on-irritant; Dermal irritancy(rabbit):non-irritant. Dermal sensitization:No sensitizing effect on guinea-pig. TRANSPORTATION: RID/ADR Class: 3 Enumeration:3eb) Label:3 MARITIME Class: 3.2 UN Num:1219 Label:3 Flammable liquid IMDG Page:3244 Marine Pollutant:No AIR Class: 3 UN Num:1219 Label:3 Flammable liquid Packaging group:II The information contained herein Is considered to be correct as of the date of this data sheet but does not purport to be all inclusive and shall be used only as a guide No warranty is expressed or Implied regarding the accuracy of this data or the results to be obtained from the use thereof. Rhone Merieux,Inc.assumes no responsibility for damages caused by the use,storage or disposal of the product in a manner not recommended on the product label. Users assume all risks asses with such unrecommended use,storage,or disposal of the product. American Veterinary Distributors Association A-109 nese in the form of its inorganic compounds may cause man- Flammable Limits(STP in air)-Volume%@ 25°C:Lel.N/A; SECTION Ill-PHYSICAL DATA gamsm. Ue!-WA BoilingPoint 760 mm I y Extinguishing g, r ( IMP ,;, ( '• Emergencyand First Aid Procedures:Body Wash conlami- Eztln ulahln Media: Water to foam,CO Melting Point: 135•i3ll nated areas with copious amounts of water.Eyes-Flood with Special Fire Fighting Procedures: Scott Pack to be used water for 15 minutes,holding the eyelids open. Consult physl• inside a building. Specific Gravity(H2O-1): N/A cian immediately. Do NOT attempt to neutralize chemically. Vapor Pressure: WA Internal-Give lemgn or orange Juice to drink,in addition,it m ik Unusual Fire and Explosion Hazards: None Vapor Density(Air-1): WA or sugar solution may be given. II none of these Is availab:e, SECTION V-HEALTH HAZARD DATA Solubility In H O,%b Wt.:15®25°C give large quantities of water to drink. Consult physician. Routes of Exposure:Inhalation,Skin Contact,Eye Contact ty ' y SECTION VI-REACTIVITY DATA • Effects of Chronic or Acute Overexposure:No long term %Volatlles by Vol; 0 Stability: Stable effects expected.The product is only to be used outside. User Evaporation Rate(Butyl Acetate 1):N//A Conditions to Avoid:Exposure to incompatible materials or needs only to walk away it the gases that are generated cause Appearance and Odor: Yellow,odorless powder. heat. any Irritation to the lungs,akin or eyes. SECTION IV-FIRE AND EXPLOSION DATA Incompatibility(Materials to Avoid):Including,but not limited Emergency and First Aid Procedures:Eyes:Flush with water Flash Point: N/A to,alcohols,arsenates,iodides,acids,charcoals,organic sub- Skin:Wash with soap and water;Inhalation: Remove to fresh Autolgnitlon Temperature: WA stances generally,ferrous or mercurous sails,hypophosphiles, air area. Provide oxygen. Flammable Limits In Air,%b Vol.: Lower•WA; hyposulfiles,sulfites,peroxides,oxalates. Notes to Physician:Ingestion of solids would be almost totally y Hazardous Decomposition Products: With hydrochloric harmless.On:,ghtmg the product,SO,and SO,gases are go-- Upper-N/A acid,chlorine is liberated. eraled.They react with water on skin surfacos and with lung Extinguishing Media: Any media suitable for the supporting tissue to form sulfurous and sulfuric acid. fire. Hazardous Polymerization: Will not occur.SECTION Of-SPILL OR LEAK PROCEDURES SECTION VI-REACTIVITY DATA Special Firefighting Procedures: None Steps to be Taken In Case Materiel Is Released or Spilled: Stablljy: Stable Unusual Fire and Explosion Hazard:None Sweep up and remove as much as KMnO4 as possible;do not Environmental Conditions to Avoid: Fire SECTION V-HEALTH HAZARD INFORMATION return contaminated material to original drum,transfer to clean Incompatibility(Materials to Avoid): Oxidizing material Health Hazard Data: A potent neuroleptic agent of value in metal drum and dispose in hazardous landfill;flush floor with Iranqulllzatlon of doge,cats and horses. abundant quantities of water into sewer,if permitted by Federal. Hazardous Decomposition Products: SO,,SO, Threshold Limit Value: Not dolormined. Slate and Local regulations;11 not,treat chemically(see below). Hazardous Polymerization: Will not occur Routes of Exposure: Waste Disposal Method:Reduce KMnO,solution with sodium ' Storage Requirements:In a dry area away from strong oxidiz- Inhalation: Moderate-depressant. Skin Contact: Slight. thiosulfale solution,mix the sludge with soda ash(Na CO)and ing agents and high temperatures. Skin Absorption: Unknown. Eye ant, S: Slight. Ingestion:ight. deposit in an approved landfill. Where permitted,the;judge SECTION VII.SPILL OR LEAK PROCEDURES y 9 can be drained into a sewer with large quantities of water. blodorate-depressant nervoussys)err(.Od•Mus:LDS 9 q Steps to be Taken In Case Material Is Released or Spilled: 257migAg, SECTION Vlll-SPECIAL PROTECTION INFORMATION Sweep up and bury in the soil Wash away small amounts with Effects of Overexposure: Respiratory Protection: For dust,use a NOSH approved water. Acute Overexposure: Marked sedation,prolonged depres- dust mask. Ventilation: Mechanical(general). Ventilation Requirements:None required-Product is used in sion,motor restlessness. Chronic Overexposure: Unknown Protective Gloves:Rubber or plastic gloves. open areas. Emergency and First Aid Procedures: Eye Protectlon;.Goggles/face shield. Respiratory Protective Equipment: Scott Air Pack-for use Eyes: Flush with large quantities of water-obtain medical SECTION IX-SPECIAL PRECAUTIONS only in fire lighting In confined area. help. Skin:Wash with water. Inhalation:Remove to fresh air Precautions to be Taken In Handling and Storing:Store In a Eye Protection:Not normally necessary -Obtain medical help. Ingestion;Obtain medical help immedi- cool, dry area In closed containers separate from organics, Gloves: None ately. concentrated acids,peroxides,ammonium compounds,metal- Other Protective Clothing and Equipment:No special cloth- SECTION VI-REACTIVITY DATA lic powders, elemental sulfur, phosphorous, carbon, metal ing required. Conditions Contributing to Instability:Stable hydrides,hydrazine,hydroxylamines. SECTION/X-SPECIAL PRECAUTIONS OR OTHER COM- Other Precautions:DOT class:oxidizer,reportable quantity- MENTS Incompatibility:Avoid contact with strong oxidizers or acids. 100 lb;RCRA: Oxidizers such as potassium permanganate Hazardous Decomposition Products: None meet the criteria of ignitable waste. Precautionary Statements: Complete Instructions for the Conditions Contributing to Hazardous Polymerization: sale use o1 the product are Included on the back of the mounting W CCill not occur. card. SECTION X-APPLICABLE STATE 8 FEDERAL REGULA- SECTION V11-SPILL OR LEAK PROCEDURES Manufacturer TIONS Steps to be Taken If Materiel Is Released or Spilled: DOT Category:ATRA Tariff No.6D Tablets: Sweep up and place in container to be held for dis- Atlas Chemical Corporation IATA Article No.:WA posal. Hazard Class:N/A Liquid: Absorb on vermiculite and sweep up,or wipe up with 2130 Birchwood Dr., N.E. Flash Point:405°F absorbent cloth using impervious gloves and place in container lot disposal. Cedar Rapids, IA 52406 OSHA Regulations:WA Neutralizing Chemicals:None Emergency Phone: (319) 377-8921 Waste Disposal Method: Incinerate Vlll-SPECIAL PROTECTION INFORMATION Ventilation Requirements: General area exhaust accept- The GIANT DESTROYER Manufacturer able. Local exhaust preferred. AVDA MSDS No.:MS585 Specific Personal Protective Equipment: Atlas Chemical Corporation,2130 Birchwood Dr.N.E.,P.O. Ayerst Laboratories Inc. Respiratory:If effects noticed,use dust-type respirator. Eye: Box 141,Cedar Rapids, IA 52406. Emergency telephone: Safety glasses advised. Gloves: Impervious to liquid. Other 319-377-8921 64 Maple Street Clothing and Equipment: Eye wash and safely shower. Date of MSDS:May 16,1984 Rouses Point NY 12979 IX-SPECIAL PRECAUTIONS , . SECTION I-IDENTIFICATION Precautionary Statements: Do not inhale dust. Handle in Trade Name:The Giant Destroyer Emergency Phone: 212-986-1000 well-ventilated area. General Uses:Rodenticlde Other Handling and Storage Requirements:Store at room SECTION 11-HAZARDOUS INGREDIENTS Ext. 555 temperature. Protect from light. Hazardous Components % Sodium Nitrate N NO, 46.2 Carbon C 8.7 IIHALOTHANE,.USP 4• AVDA MSDS No.:MS65 Sulfur S 34.8 VAr,,., .. Inert 10.3 , ACEPROMAZINE MALEATE, Ayerst Laboratories,Inc.,64 Maple Street,Rouses Point,NY SECTION Ill-PHYSICAL B CHEMICAL CHARACTERISTICS . ' AVDA MSDS No.:MS64 12979.Emergency Phones:(212)986.1000,ext.555(9 a.m:- Ayerst Laboratories,Inc.,64 Maple Street,Rouses Point,NY 5 p.m.);Other hours:(516)883-9145,(203)655-3258. Bolling Point:WA 12979.Emergency Phones:(212)986-1000,ext.555(9 a.m.• SECTION I-PRODUCT IDENTIFICATION Melling Point:(Sulfur)113°C;N,N)308°F 5 p.m.);Other hours:(516)883.9145,(203)655-3258. Trade Name: Halothane,USP Specific Gravity: 2.0 SECTION I-PRODUCT IDENTIFICATION Synonyms: Fluothane Vapor Pressure(mm Hg):N/A Trade Name: Acepromazlne Maleate NFPA HAZARD RATING: Health -1; Fire-0; Reactivity-0; %Volatile by Volume:0 Synonyms: 1 J10-I3-(Dimethylamino)propyl]-10H•phe• Special-0. Vapor Density(AIR-1):N/A nolhiazin-2-yl ethanone. SECTION Il-HAZARDOUS INGREDIENTS Evaporation Rate(Butyl Acetate-1):N/A NFPA HAZARD RATING: Health -3; Fire-0; Reactivity-0; Component Stock No. % TLV Solubility In Water by Wt.:56.5 Special-0. Helothans,USP 81-6157-2 100 2 ppm Appearance and Odor:Medium Gray SECTION 11-HAZARDOUS INGREDIENTS SECTION III-PHYSICAL DATA / SECTION IV-FIRE AND EXPLOSION HAZARD DATA Component Stock No. % TLV Bolling Point(760 mm Hg):49°-51°C;(120.2°.123.8°F) Flash Point:405°F(Closed Cup) Acepromazine 81-6002-0 100 ND A-110 _ American Veterinary Distributors Association IX-SPECIAL PRECAUTIONS PRIMIDONE' AVDA MSDS No.:MS66 Precautionary Statements: Avoid inhaling dust. Avoid Halothane, USP Ayerat Laboratories,Inc.,64 Maple Street,Rouses Point,NY contact with skin. Pr9toct eyes at all limes. Do not take orally Continued 12979.Emergency Phones:(212)986.1000,ext.555(9 a.m.- -thorapeullcally aclive. 5 p.m.);Other hours:(516)883.9145,(203)655.3258. Other Handling and Storage Requirements:Store under SECTION I-PRODUCT IDENTIFICATION ambient conditions. Melting Point: N.D. Trade Name: Prlmidone Specific Gravity(H,0-1):1.872.1.877 Synonyms: 5-elhyldlhydro-5•phenyl-4,6(1H,-5H)-pyrimidine- Manufacturer Vapor Pressure: 243.4 mm Hg at 20°C dione. Vapor Density(Alr-1): �I NFPA HAZARD RATING: Health -1; Fire-1; Reactivity-0; Aztec Chemicals Solubility In H2O,%by Wt.:Slightly Special-0.SECTION 11-HAZARDOUS INGREDIENTS 2190 North Loop West %Volatlles by Vol: 100 Component Stock No. % TLV Evaporation Rate(Butyl Acetate 1):ND Primidone 61-6275-2 100 N,D. Suite 202 Appearance and Odor: Colorless,sweetish odor. SECTION III-PHYSICAL DATA Houston, TX 77018 SECTION IV-FIRE AND EXPLOSION DATA Bolling Point(760 mm Hg): N/A Flesh Point: WA Melting Point: 281-282^C Emergency Phone: 713-682-5300 Auloignillon Temperature:WA Specific Gravity(H,0-1): WA Flammable Limits In Air,%by Vol.: Lower-Ni Vapor Pressure: WA Upper.WA Vapor Density(Air-1): N/A AZTEC BENZOYL PEROXIDE- 77 Extinguishing Media: WA-Non-flammable. Solubility In H2O,%by Wt.:Sparingly(0.05%). AVDA MSDS No.:MS3028 Special Firefighting Procedures: None Volatllae by Vol: N/A Aztec Chemicals,Div,of Dart Industries,Inc,2190 North Loop Unusual Plro and Explosion Hazard:If suoreclud to fire Lem- i Re(Butyl Acetate 1):W/A West,Suite 202,Houston,TX,77018. Emergency Telephone Evaporation uy peratures,may give off acid fumes of bromine,chorine and No.:713-682-5300. fluorocarbons. Appearance and Odor: While,odorless powder. SECTION I-IDENTIFICATION SECTION V-HEALTH HAZARD INFORMATION SECTION IV.FIRE AND EXPLOSION DATA Trade Name/Synonyms: Aztec Benzoyl Peroxide-77 Health Hazard Data:Practically non-toxic by inhalation.Very Flash Point: N/A Chemical Name/Synonyms: Benzoyl Peroxide-77 minor Irritation of skin. OraVRal-LDp:6.75 g/kg. Autolgnitlon Temperature: N/A Threshold Limit Value: 2 m.(Peak of 25 m for 15 chemical Family: Organic Peroxide PP PP Flammable Limits In Air,%by Vol.: Lower•N.D.; Formula: C„111004 minutes). Upper-N.D. SECTION It-HAZARDOUS INGREDIENTS Routes of Exposure: Extinguishing Media: Carbon dioxide,dry powder,halon, Hazardous Ingredients % Inhalation:Slight-LC-50: 224 mgA. (2.8%). Skin Contact., water spray. Slight-not primary skin Inilanl. Skin Absorption: Unknown Benzoyl Peroxide 77% Eye Contact: Slight-Imitating. Ingeslion: High•poisonous II Speclal.Flreflghling Procedures: None sallowed. Unusual Fire end Explosion Hazard:Sensitive to ignition by Water 23% w Effects of Overexposure: electrostatic&,charga,both as a cloud and as a poVdar layer. SECTION III.PHYSICAL DATA Acute Overexposure: SECTION V-HEALTH HAZARD INFORMATION Solubility In Water: Negligible po Dizziness,lethargy,unconsciousness. Chronic Overexposure: Unknown Health Hazard Data:Systemic absorption may cause drowsi- Appearance and Odor: Fine,while granules Emergency and First Aid Procedures: ness,giddiness,difficulty In accommodation and nausea. SECTION IV-FIREAND EXPLOSION HAZARD DATA Eyes:•Flush with plenty of water for at least 15 minutes and Threshold Limit Value: Not determined. Flash Point(Method Used): Decomposes at 103°C. obtain medical attention. Routes of Exposure: Extinguishing Media: Foam,water Skin: Wash thoroughly with mild detergent and water. lnna+al,on: Slight. Skin Contact: Slight. Skin Absorption: Special Fire Fighting Procedures: Do not light any lire with Inhalation: Remove to fresh air-If breathing difficult,give Unknown. Eye Contact: Slight. Ingestion: Moderato.Low- small extinguishers. Evacuate the area and light from behind a oxygen. It breathing stopped,apply artificial respiration. oral,rats:1.5.2.0 gm/kg. barricade using water. White smoke is combustible. Ingestion; Obtain medical attention immediately. Effects of Overexposure: Unusual Fire and Explosion Hazards:Containers near a lire SECTION VI-REACTIVITY DATA Acute Overexposure: Drowsiness,giddiness,nausea. should be cooled with a water spray to prevent contents Irom Chronic Overexposure: Unknown reaching Its decomposition temperature. Conditions Contributing to Instability: Stable SECTION V-HEALTH HAZARD DATA Incompatibility: None Emergency and First Aid Procedures: Eyes: Irrigate thoroughly with water-obtain medical often- Threshold Value: Not determined HazHazardousHsrdo Decomposition Products: If subiecled!o turn- Emergency and First Aid Procedures: Wash skin with soap peratures above 2701 may give acid fumes of.bromine, li and on. chlorine and fluorocarbons. Skin: Wash with soap and water. Contaminated clothing and water after contact and handling. In the event of contact must be removed and washed before reuse. with eyes,flush eyes for 15 minutes with water and get medical Conditions Contributing to Hazardous Polymerization: attention. In case of Ingestion,induce vomiting and gel medical Will not occur. Inhalation: Remove to fresh air. attention. SECTION VII-SPILL OR LEAK PROCEDURES Ingestion;Wash out mouth with water and obtain medical at- SECTION VI-REACTIVITY DATA tion. Steps to be Taken If Material Is Released or Spilled: ten Stability: Stable Allow to evaporate with adequate ventilation. If necessary to SECTION VI-REACTIVITY DATA Conditions to Avoid: Heat,sparks,flame,metal contamina- enter area, use air-supplied breathing apparatus. Whore Conditions Contributing to Instability: Stable Ilan evaporation technique in are not feasible,soak up spill with an . Incompatibility: Unknown. Incompatibility(Materials to Avoid): Acids,oxidizing and re- absorbent such as dry sand or earth. Remove to sale area and Hazardous Decomposition Products: None ducing agents,accolorators,corrosves. allow to evaporate. Neutralizing Chemicals: None Conditions Contributing to Hazardous Polymerization: Hazardous Polymerization: Will not occur Will not occur. SECTION VII-SPILL OR LEAK PROCEDURES Waste Disposal Method:Incinerate,or allow to evaporate as SECTION VII.SPILL OR LEAK PROCEDURES above. Stops to be Taken In Case Material Is Released or Spilled: Steps to be Taken If Materiel Is Released or Spilled: Wet down the spilled material with water,mix with a noncom- Vlll-SPECIAL PROTECTION INFORMATION Sweep up and retain in suitable container for subsequent bustible material(i.e.Vermiculite). Deposit in a safe area using Ventilation Requirements:General mechanical exhaust sat- disposal. Avoid generation of excess dust. nonsparking equipment. Ignite with a torch from a safe drs- isfactory. Local exhaust preferred. tance. Neutralizing Chemicals: None Specific Personal Protective Equipment: Waste Disposal Method: Add Benzoyl Peroxide in small Respiratory: None during normal use;NIOSH-approved Waste Disposal Method: Incineration or controlled disposal portions to 10 times its weight of cold 10%sodium hydroxide organic vapor respirator for concentrations In excess of TLV. at approved landfill. solution. Supply agitation to break up lump formations. The Eye:Safety glasses or face mask. Vill-SPECIAL PROTECTION INFORMATION resulting slurry of sodium bonzoal,can then be disposed in the Ventilation Requirements:Local exhaust preferred.General same mannor as other waste chemicals. Gloves: Not required. mechanical exhaust satisfactory. SECTION Vlll-SPECIAL PROTECTION INFORMATION Other Ciothrng and Equipment:Eye wash and solely showor Specific Personal Protective Equipment: Protective Gloves: Rubber in areas whore bulk quantities of chemicals are routinely handled. Respiratory:In areas where dust is present,use respirators Eye Protection: Goggles,lace shield or equivalent IX-SPECIAL PRECAUTIONS carrying NIOSH-approval for protection against active chemical SECTION IX-SPECIAL PRECAUTIONS Ingredients,or supplied air respirators. Precautions to be Taken In Handling and Storing: Avoid Precautionary Statements: Do not Inhale vapors. Eye:Goggles when handling bulk chemicals. Other Handling and Storage Requirements:Store in cool Gloves: Impervious to dust. sources of heal,flames or sparks.Store away from combustible place In air-light containers. Protect from light. Other Clothing and Equipment: Protective outerwear. Eye and decomposition agents(see Section VI). Store in cool, wash and safety shower in areas whore bulk quantities of isolated area. chemicals are routinely handled. Other Precautions: Store in original containers. Avoid direct sunlight.Do not allow to dry out as it will become shock and fric- tion sensitive. - -- --- - - -- -- - -- -- - - - -- MATERIAL SAFETY DATA SLT -- --- - - ---- --- --------- Techamerica AGRI LABS ISOPROPYL ALCOHOL 70% IDENTIFIER NO.: 99632 ----------------------------------------------------------- DATE: 7/21/86 VII. ENVIRONMENTAL PROTECTION PROCEDURES ---------------------------------------------------------- ----------------------------------------------------------- I. GENERAL INFORMATION SPILL/LEAK RESPONSE: Eliminate all sources of ignition. ----------------------------------------------------------- Ventilate area. Remove with inert absorbent and non- PRODUCT DESCRIPTION: Isopropyl Alcohol 70W GL sparking tools. TRADE NAME & SYNONYMS: Agri Labe Isopropyl Alcohol 70% WASTE DISPOSAL METHOD: Dispose of in accordance with local CHEMICAL FAMILY: Alcohol pollution regulations. MANUFACTURER: TECHAMERICA GROUP, INC ----------------------------------------------------------- P.O. BOX 338 VIII. SPECIAL PROTECTION INFORMATION ELWOOD, KS 66024 ----------------------------------------------------------- PHONE NO: (913) 365-9076 BYE PROTECTION: Chemical safety goggles PROPER DOT SHIPPING NAME: Isopropanol SKIN PROTECTION: Rubber gloves DOT HAZARD CLASSIFICATION: Flammable liquid RESPIRATORY PROTECTION (SPECIFIC TYPE): Organic canister ----------------------------------------------------------- respirator for emergencies II. INGREDIENTS , VENTILATION RECOMMENDED: Local exhaust ---------------------------------------7------------------- OTHER PROTECTION: None PRINCIPAL HAZARDOUS ----------------------------------------------------------- COMPONENTS % PEL TLV IX. SPECIAL PRECAUTIONS ----------------------------------------------------------- ----------------------------------------------------------- Isopropyl alcohol 70% None estab 400ppm HANDLING & STORAGE: Do not store above 120 deg F. Use ----------------------------------------------------------- according to label directions. III. PHYSICAL DATA OTHER PRECAUTIONS: None ----------------------------------------------------------- ----------------------------------------------------------- BOILING POINT (deg. F) : 180 THE INFORMATION CONTAINED HEREIN IS BASED ON DATA VAPOR PRESSURE (mm Hg.): n/applicable CONSIDERED ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR VAPOR DENSITY (AIR = 1): n/applicable IMPLIED REGARDING THE ACCURACY OF THE DATA OR RESULTS TO BE SOLUBILITY IN WATER: Complete OBTAINED FROM THE USE THEREOF. SPECIFIC GRAVITY OF CONC (H20 = 1): .8770 ----------------------------------------------------------- PERCENT VOLATILE BY VOLUME (b): 704 DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: Although EVAPORATION RATE (BuAc = 1) : 1.7 reasonable care has been taken in the preparation of this PH: Not applicable document, we extend no warranties and make no APPEARANCE & ODOR: Clear, colorless liquid with representation as to the accuracy or completeness of the characteristic odor. information contained therein, and assume no responsibility ----------------------------------------------------------- regarding the suitability of this information for the IV. FIRE & EXPLOSION HAZARD DATA user's intended purposes or for the consequences of its -- ------------------------------------------------- use. Each individual should make a determination as to the FLASH POINT (METHOD) : 55 deg F suitability of the information for their particular FLAMMABLE LIMITS IN AIR BY % VOLUME: n/applicable purpoee(e). A request has been made to the manufacturer to EXTINGUISHING MEDIA: Carbon dioxide, dry chemical, alcohol approve the contents of this material safety data sheet. foam Upon receipt a new MSDS will be made available. SPECIAL FIGHTING PROCEDURES: Water may be ineffective, but ----------------------------------------------------------- may be used to cool containers. COMPAS Code: 74800040 NAC Approved Date: UNUSUAL FIRE & EXPLOSION HAZARDS: Keep away from heat, sparks, and open flame. ----------------------------------------------------------- V. HEALTH HAZARD --------------------------------------------------------- THRESHOLD LIMIT VALUE: 400ppm CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY: None SYMPTOMS OF EXPOSURE: Skin and eye irritation. Breathing of vapors can be irritating to nose and throat. Ingestion causes nausea, dizziness, headache, stupor. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: None known EMERGENCY FIRST AID PROCEDURES: SKIN: Wash with soap and water EYES: Flush with water for 15 minutes. Get medical attention. INHALATION: Remove to fresh air. INGESTION: Induce vomiting. Get medical attention immediately. ----------------------------------------------------------- VI. REACTIVITY DATA ----------------------------------------------------------- STABILITY: Stable CONDITIONS TO AVOID: Heat, sparks, open flame INCOMPATIBILITY: Strong oxidizers HAZARDOUS POLYMERIZATION: Will Not Occur HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide from burning. 3/14/95 -------------------------------------------------------------------------------------- MWI VETERINARY SUPPLY 1716731 NORTHWEST VET CLINIC/STANWOOD Page 1 of 1 W- 20 American Veterinary Distributors Association Specific Gravity(H.0-1):0 785 Other Handling&Storage Conditions:Corrode rubber use Iodine Vapor Density:2 0 Air-1 neoprene. Avoid ignition source and hot spots. Use UL Evaporation Rate(Ethyl Ether-1):7 70 approved explosion proof electrical systems,formal lank entry Confinued procedures. Appearance and Odor:Colorless/slight `} Percent Volatile:100% Extinguishing Media to be Used: Alcohol loam,CO2 Vapor Pressure(mm Hg):33 mm/Hg at 68 Special Firefighting Procedures:Cool exposed container. Solubility In Water:Complete PROPYLENE GL YCOL' Wear self contained breathing unit. AVDA MSDS No.:MS1589 Unusual Fire and Explosion Hazards:Flammable. Keep Melting Point:NA Item hoot,spark or ignition source. SECTION 111-HAZARDOUS INGREDIENTS Willard Products,P.O.Box 249,70 Chemical Way,Redwood NFPA Hazard Classification:Health- 1;Flammability-3; Exposure Llmlle In Air City,CA 94064..Emergency Telephone:415.365-3300. ' Reactivity0 Dale of MSDS:February 1,1987 ' Meterlel�Portent CASH ACGIH TLV OSHA PEL SECTION V-HEALTH HAZARD DATA Isopropyl Alcohol 67630 400 p/ma 980 mg/m3b SECTION I-IDENTIFICATION Route of Entry: Inhalation:mouth or nose. Ingestion:mouth. Isopropyl Alcohol 70%,Isopropanol 70%: Trade Name/Synonyms:Propylene Glycol Absorption: skin or eye contact, Less than 95% Chemical Name/Synonyms:Propylene Glycol Effects of Overexposure: Harmful if inhaled, Headache, SECTION IV-FIRE AND EXPLOSION HAZARD DATA Chemical Family:Glycol nausea.vomiting, eye and skin irritation,thinitis,coughing, CAS Number:57556 pulmonary edema,mahogany coloration. Ingestion:vomiting, Flesh Point 53 F(TOC)Cup burning and staining of mouth,necrosis. Auto Ignition Temp.:850 F Formula:CH3CHOHCH2OHSECTION ll-PHYSICAL DATA Health Effects or Risks from Exposure: Flammable Limits In Air,by Volume:Lower-2.0;Upper-12.0 physical Slate et STP:Liquid Acute: Headache, nausea and vomiting from prolonged Extinguishing Media to be Used: Alcohol foam,CO2,dry breauvng. Skin and eye irritation on contact. chemic4, Water may be ineffective. Bolling Point(°F):365.374 F Chronic:May cause rhinilis,pulmonary edema,and necrosis. Special Fire Fighting Procedures: Wear self contained Specific Gravity(H,0-1):1.035-1.036 Emergency and First Aid: breathing apparatus approved by the U.S.Bureau of Mines. Vapor Density:Heavier than air Skin Contact:Flush skin with water. Use water 10 cool neighboring containers. Evaporation Rate(BuAc-1):Slower than ether Eye Contact:Immediately flush eyes with plenty of water for at Unusual Fire and Explosion Hazards:Flammable. Danger. Appearance and Odor:Clear/glycol least 15 minutes. ous fire risk. Toxic by ingestion and inhalation. Vapors may percent Volatile:100 Iravol along ground to ignition source. May ignite. Never use Inhalation:Remove to fresh air. If not breathing,give artificial welding torch on or near drum. (Empty drum), Product reslduo Vapor Pressure(mm Hg):0.10 mm/Hg respiration. If breathing is difficult,give oxygen. can ignite. Solubility in Water:Slight If Swallowed:If conscious,immediately induce vomiting. In all NFPA Hazard Classification: Health-1;Flammability-3; Melting Point:Not available events seek medical attention. Reactivity•0 Suspected Cancer Agent:No. Not a carcinogen. SECTION V-HEALTH HAZARD DATA SECTION Ill-HAZARDOUS INGREDIENTS Exposure Limits In Air Medical lensConditions and Aggravated it Exposure:Can cause RouteAbsorption: of Entry:Inhalation:Mouth or nose.Ingestion:Mouth. Material CASH ACGIH TLV OSHA PEL heart problems and skin problems with prolonged contact. Absorption:Skin or eye contact. SECTION VI-REACTIVITY DATA Effects of Overexposure: Inhalation. Flushing of face,head- Propylene glycol 57556 0.05 ppm 0.3 mg/m3 Stability:Stable ache, dizziness, nausea, vomiting. Eyes: Irritant. Skin SECTION IV-FIRE AND EXPLOSION HAZARD DATA Conditions to Avoid:Heat,spark,ignition source. Absorbed through skin adding to effect of inhalation. Flash Point:225 F OC Incompatibility (Materials to Avoid): Hydrogen-palladium Health Effects or Risks from Exposure: Auto Ignition Temp.:780 F combination. Acute:Breathing will cause headache,dizziness,nausea and Flammable Limits in Air,by Volume:Lower-2.6;Upper- Hazardous Decomposition:Acetaldehyde;acetylene;alumi- vomiting if exposed for a prolonged period without proper None given hum;ammonia;a protection. ammonium hydroxide;chlorine;ethyl alcohol; ExUngubhing Media to be Used: Alcohol-loam,CO.,dry - Iluonne;mercunc oxide;potassium;phosphorus;silver azide; Chronic:Can be absorbed through skin adding to the effect of chemical sodium hydride;zirconium dicarbido. inhalation. Special Fire Fighting Procedures:May term CO,and carbon Hazardous Polymerization:Will not occur Emergency and First Aid: monoxide. SECTION VII-SPILL OR LEAK PROCEDURES Skin Contact:Remove soaked clothing. Wash with water for Unusual Fire and Explosion Hazards:Not applicable Steps to be Taken if Spill Occurs: Cover with vast volume of 15 minutes. NFPA Hazard Classification:Health-0;Flammability-1; concentrated solution of reducing agent(bisulfites or ferrous Eye Contact:Wash with water for 15 minutes. Reactivity-0 salts with 3m H2S94). Neutralize with soda ash or diluted Hot. Inhalation:Remove to fresh air. Keep warm and comfortable. SECTION V-HEALTH HAZARD DATA Waste Disposal Method:Dispose of waste in accordance with If breathing is labored,give artificial respiration. If conscious, ha give black coffee. Route of Entry: Inhalation:mouth or nose.Ingestion:mouth hauler . u state and local agencies. Use stale approved waste 9 Absorption: skin or eye contact. hauler If Swallowed:Keep warm and seek medical attention at once. Effects of Overexposure:Irritation to skin,eyes,and mucous SECTION Vill-SPECIAL PROTECTION INFORMATION Suspected Cancer Agent:No This product is not a carcino- membrane. Ingestion may,cause nausea,vomiting,and diar- Respiratory Protection:Self contained breathing apparatus, gen• rhea. or gas mask. Medical Conditions Aggravated by Exposure:Not available. Health Effects or Risks from Exposure: Eye Protection:Face shield Howuver alcohol can be absorbed into the skin. loves SECTION VI-REACTIVITY DATA Acute:Can irritate skin,eyes,and breathing. May rouse Protective Gloves:Rubber 9 nausea,vomiting,and diarrhea.Chronic:Not available Other Protective Equipment:Approved working clothes Stability:Stable Emergency and First Aid: SECTION IX-SPECIAL PRECAUTIONS Conditions to Avoid:Ignition source. Skin and Eye Contact:Wash skin and eyes with water for at Precautionary Labeling:Flammable Incompatibility (Materials to Avoid): Hydrogen-Palladium least/5 minutes.Inhalation:Remove to fresh air.If Swallowed: 01her Handling&Storage Conditions:Keep in tightly closed combination;nilroform;for alcohols in general. Give water. In any event seek medical attention. corrt:ainer Store at temperalwo between 15.30C(59.86F) Hazardous Decomposition:CO and CO2 and possibly aide- Suspected Cancer Agent:No. Not a earelnogen. hydos would be expected. Some strong oxidizing agents. Medical Conditions Aggravated by Exposure:Not available Hazardous Polymerization:Will not occur SECTION VI-REACTIVITYDATA SECTION Vll-SPILL OR LEAK PROCEDURES Stability:Stable ISOPROPYL ALCOHOL 70%r Steps to be Taken If Spill Occurs: Use personal protection Incompatibility(Materials to Avoid):Strong oxidizers ISOPROPANOL 70%. equipment. Keep away from ignition source and other chemi- cals. Call E.R.T.Team. Absorb with absorbent or flush area Hazardous Decomposition:May form CO.and Carbon Mon- ISOPROPYL ALCOHOL 99% with water. Place in D.O.T.waste container and call waste oxide. hauler. Hazardous Polymerization:Will not occur. AVDA MSDS No.:MS1587 Waste Disposal Method:All IPA waste must be treated as a SECTION Vll-SPILL OR LEAK PROCEDURES Willard Products,P.O.Box 249,70 Chorniral Way.Redwood dangerous flammable liquid. Even empty drums must be Steps to be Taken H Spill Occurs: Wear self contained City,CA 94064.Emergency Telephone:415.365.3300. treated as a Ilammable danger. All waste should be disposed breathing unit and protective clothes. Contain spill and cover Dale of MSDS:February 1,1987 of in accordance with federal,state,and local agencies. Waste with inert material. Place in D.O.T.drum': SECTION I-IDENTIFICATION haulers must be slate approved. Waste Disposal Method:Dispose of in accordance with local, Trade NametSynonyms:Isopropyl Alcohol 70%,Isopropanol SECTION Vill-SPECIAL PROTECTION INFORMATION state,and federal regulations. Call in state approved waste 70`<;Isopropyl Alcohol 99% Respiratory Protection:Air mask. Depends on size of spill. hauler. Chemical Name/Synonyms:2-Propanol; Isopropyl Alcohol Keep air pack near by. SECTION Vill-SPECIAL PROTECTION INFORMATION 99 i Eye Protection:Goggles Respiratory Protection: NIOSH approved respirator. Chemical Family:Aliphatic Alcohol, Protective Gloves:Neoprene Ventilation: Local,Mechanical CAS Number:67630 Other Protective Equipment: `Jol generally required but Eye Protection:Goggles Formula:CH3CHOHCH3;CH3CHOH safety clothes would be recommended. Protective Gloves:Polyethylene SECTION If-PHYSICAL DATA SECTION IX-SPECIAL PRECAUTIONS Other Protective Equipment:Work clothes. Physical Slate at STP:Liquid Precautionary Labeling:D.O.T.Classification. Flammable liquid. Boiling Point(°F):180E F-60 American Veterinary Distributors Association Medical Conditions Generally Aggravated by Exposure: Chemical Listed as Carcinogen or Potential Carcinogen:No Chlorasan Disinfectant Solution None Route(s)or Entry: Chemical Listed as Carcinogen or Potential Carcinogen:No Inhalation:hu Continued Route a or Ent �g " ( ) Entry: Eyas:Modera 11FI�etiwilff(Wal�('li a:ilat•,''q!,;.+. Inhalation:N/A Skin:Mild-Wash with soap and water Eyes:Possible irritation-flush with water. Ingestion:Contact a physician Signs and Symptoms of Exposure:None Skin:Possible irritation-wash with soap and water. SECTION Vll-SPECIAL PRECAUTIONS AND SPILULEAK Medical Conditions Generally Aggravated by Exposure: Ingestion:Harmful-gel medical attention. PROCEDURES Irn•utlion w uyas or mucous membranes, SECTION VII-SPECIAL PRECAUTIONS AND SPILULEAK Precautions to be Taken In Handling and Storage:For use in Chemical Listed as Carcinogen or Potential Carcinogen:No PROCEDURES dogs and cats only. Unopened vials may occasionally darken Route(s)or Entry: Precautions to be Taken In Handling and Storage:Keep out during storage. The change in color does not affect potency. Of each of children. Avoid contamination of lead and lead- Other Precautions:Keep out of reach of children.Federal law Inhalation:WA stuifs. Keep out of lakes,ponds,or streams. For cleaning, restricts this drug to use by or on the order of a licensed veteri- Eyes:Irritation-flush with water. disinfection,deodorizing. For veterinary use. It is a violation of narian, Sk/n:,lrrilation-wash with soap and water, federal law to use product In manner Inconsistent with labeling. to b0 Taken In Case Material Is Released or S Ingestion:May be harmful-get medical attention. Steps P pilled: SECTION Vll-SPECIAL PRECAUTIONS AND SPILULEAK Steps to be Taken In Casa Material Is Released or Spilled: Collect and place in suitable containor for future disposal. PROCEDURES Flush to drain with excess water. Wash contaminated surfaces and(lush to drain. Precautions to be Taken In Handling and Storage:Do not Waste Disposal Methods:Open dumping is prohibited. Do Waste Disposal Methods:Incinerate in accordance with local, not reuse empty container. May be disposed of on site. Rinse state and federal regulations contaminate water,food,or feud by storage or disposal, Keep empty containers and put in trash. out of roach of children. SECTION Vill-SPECIAL PROTECTIONINFORMATION/CON- Other Precautions:It is a violation of federal law to use this SfC r1QN Vlll - SPECIAL PROTECTION INFORMATION/ TROL MEASURES product in a manner inconsistent with its labeling. G)JNTROL MEASURES Respiratory Protection:Not needed F�esplratory Protection:Not required Protective Gloves:Recommended-latex or rubber Stops to a Taken Cs Material Is Released or Spilled: Ventilation:N/A Local exhaust-Recommended Flush to drain with excess water.water. Eye Protection:Recommended-safety glasses Waste Disposal Methods:Open durn ,n is prohibited Do Protective Gloves:Not required P9 Pe I 9 P Other Protective Clothing or Equipment:None not reuse empty container. Rinse containers with water and Eye Protection:Recommended-safety glasses. Work/Hyglenlc Practices:Follow label directions-see pack- discard in trash. Other Protective Clothing or Equipment:None age insert. SECTION Vlll - SPECIAL PROTECTION INFORMATION/ Work/Hygienic Practices:None-follow label directions. CONTROL MEASURES -- Respiratory Protection:Not needed Ventilation:WA Local exhaust-N/A;Mechanical-N/A; KETASET:(Kg,T,MI)Vg,t Ci.),NJ.).;: Protective Gloves:Not needed AVOA MSDS No.:MS1145 Eye Protection:Recommended KANTRIM AVDA MSDS No.;MS1 144 Fort Dodge Laboratories,Inc.,P.O.Box 518,800 5th St.N.W., Other Protective Clothing or Equipment:None Fort Dodge Laboratories,Inc.,P 0.Box 518,800 5th St.N.W., Fort Dodge,IA 50501.Emergency Phone: 515.955.4600. Fort Dodge,IA 50501.Emergency Phone: 515-955-4600. Date of MSDS:July 7,1988 Work/Hygienic Practices:None•follow label directions. Date of MSDS:July 19,1988 SECTION I-IDENTIFICATION SECTION/-IDENTIFICATION Product Name:Kelaset(Kelamine HCL-In).) Product Name:Kantrim SECTION 11-HAZARDOUS INGREDIENTS CHLORASAN SCENTED DISINFEC- SECTION 11-HAZARDOUS INGREDIENTS Ketamine Hydrochloride-Equivalent to 100mg.per ML.Ketam- TANT AVDA MSDS No.:MS2953 2 Sizes: ine. Not more than 0.1 mg/mL.phemerol(A)Benzathonium Kanam cn Sulfate 50 m /ml:Ea.ML contains: 200m chloride)added as a preservative. Fort Dodge Laboratories,Inc.,P.O.Box 518,800 5th St.N.W., i y g g/ml Vetalar may be used in cats for restraint or as the sole anes- Fort Dodge,IA 50501.Emergency Phone: 515.955-4600. Manamycin Activity as Sulfact 50.0mg 200 Omg thetic agent for diagnostic or minor,brief,surgical procedures Dale of MSDS:June 12,1986 Sodium Citrate 4.4mg 22.Omg that do not require skeletal muscle relaxation. For intiamuscu- SECTION I-IDENTIFICATION Melhylparaben 0.9mg 0.9mg let use. Product Name:Chlorasan Scented Disinfectant Propylparaben 0.1 mg 0.1 mg SECTION Ill-PHYSICAL&CHEMICAL CHARACTERISTICS SECTION If-HAZARDOUS INGREDIENTS Sodium bisullile 1.3mg 6.6mg Bolling Point: Not determined Sulfuric Acid used to adjust PH Specific Gravity(H20"): Not determined OSHA ACGIH This drug has been used successfully in the treatment of Vapor Pressure(mm Hg): Not determined Component PEL TLV OTHER % CAS# bacterial infections due to kanamycin-susceptible organisms in Vapor Density(AIR-1): Not determined 'Chlorhexidine N/A N/A N/A 2% N/A dogs and cats. Solubility In Water: Not applicable Diacetale SECTION It/-PHYSICAL B CHEMICAL CHARACTERISTICS Inert WA N/A N/A 98% N/A Reactivity In Water: N/A '1,1'-Hexamelh lenebis 5- Bolling Point:not determined y [ (p-chlorophenyl)biguanideJ discs- Appearance and Odor: Colorless to very slight yellow solu- tate Specific Gravity(Hz0=1):not determined lion Solution may darken(yellow)upon prolonged exposure to SECTION III-PHYSICAL&CHEMICAL CHARACTERISTICS Vapor Pressure(mm Hg):N/A light. This darkening does not affect potency. Do not use if Vapor Density ) Bolling Point:Not known P y(AIR=1 :N/A precipitate appears. Specific Gravity(1-1,00):0.98 Solubility In Water:Water soluble Melting Point: NrA Reactivity In Water:N/A SECTION IV-FlRE R kXPLOSION d%TA Vapor Pressure Hg):Not known y Flash Point: Not determined Method Used: WA Vapor Density(AIR-1):Not known Appearance and Odor:Clear liquid Melting Point:N/A Flammable Limits In Air(%by Volume):Let-N/A;Uel-WA Solubility In Water:Mixes well with water Reactivity In Water:Not reactive with water SECTION/V-FIRE B EXPLOSION DATA Auto-ignition Temperature: N/A Flash Point:not determined Method Used:WA Extinguisher Media: COz;dry them;foam;water spray. Appearance and Odor:Clear,blue,perfumed liquid Melling Point:WA Flammable Limits In Air(%by Volume):Lei-N/A;Uel-WA Special Fire Fighting Procedures: None Auto-I nation Temperature:WA Unusual Fire and Explosion Hazards:Toxic vapors or fumes SECTION IV FIRE B EXPLOSION DATA g P may be evolved,n afire. Flash Point:103.5 C Method Used:open cup Extinguisher Media:Water;waste mist;CO2;dry them;foam SECTION V-PHYSICAL HAZARDS(REACTIVITY DATA) Flammable Limits In Air(%by Volume):Let-Not determined; Special Fire Fighting Procedures:None Stability: Stable Uel-Not determined Unusual Fire and Explosion Hazards:None Conditions to Avoid: None Auto-Ignition Temperature:Not determined SECTION V-PHYSICAL HAZARDS(REACTIVITY DATA) Incompatibility(Materials to Avoid):'None known Extinguisher Media:Foam,CO,water mist Stability:Stable Hazardous Decomposition Products: None known Special Fire Fighting Procedures:None Conditions to Avoid:None known Hazardous Polymerization: Will not occur Unusual Fire and Explosion Hazards:None Incompatibility(Materials to Avoid):None known Conditions to Avoid: None SECTION V-PHYSICAL HAZARDS(REACTIVITY DATA) Hazardous Decomposition Products:None known SECTION VI-HEALTH HAZARDS Stability:Stable Hazardous Polymerization:Will not occur Acute: None Chronic: None Conditions to Avoid:None known Conditions to Avoid:None known Signs and symptoms of Exposure: None-non-toxic Incompatibility(Materials to Avoid):None known SECTION VI-HEALTH HAZARDS Medical Conditions Generally Aggravated by Exposure: Hazardous Decomposition Products:None known Acute: None Chronic: None None Hazardous Polymerization:Will not occur Signs and Symptoms of Exposure:None-product is non- Chemical Listed as Carcinogen or Potential Carcinogen: Conditions to Avoid:None known toxic antibiotic for the treatment of bacterial Infections due to No SECTION VI-HEALTH HAZARDS Kanamycin susceptible organisms in dogs and cats. Emergency and First Aid Procedures: Eyes: flush with Medical Conditions Generally Aggravated by Exposure: excess water. Skin-wash with soap and water. Ingestion- Acute:May be irritating to eyes Chronic:None None contact a physician. Signs and Symptoms of Exposure:Irritation to eyes or mu- cous membranes. Harmful if swallowed. F-61 y, Arll�dW Vebtinary Distributors Association Routes)or Entry: } Route(s)or Entry: Medical Conditions Generally Aggravated by Exposure: None Inhalation:WA Inhalation:Moderate.irritating with possible anaesthesia Eyes:Moderate-flush with water effect. Chemical Listed as Carcinogen or Potential Carcinogen:No Skin:Mild-Wash with soap and water Eyes:Moderate-irritating. Route(s)or Entry: Ingestion: Contact a physician Skin:Unknown Ingestion: N/A SECTION VII-SPECIAL PRECAUTIONS AND SPILULEAK Ingestion:High-toxic. Obtain medical help. Do not induce PROCEDURES i vomiting. Eyes:Possible irritation-flush with water Precautions to be Taken In Handling and Storage: Store at SECTION VII-SPECIAL PRECAUTIONS AND SPILULEAK Skin:Possible Irritation-wash with soap and water. controlled room temperature(59°-86°).Protect from light.Keep PROCEDURES Ingestion:Harmful-get medical attention. out of reach of children. Precautions to be Taken In Handling and Storage:Store in SECTION VII-SPECIAL PRECAUTIONS AND SPILULEAK Other Precautions: For use in cats and subhuman primates cool,dry place' Not for use on horses intended for food. PROCEDURES only. Federal law restricts this drug to use by or on the order of, Combustible mixture. Do not use near Itemos,sparks,or Precautions to be Taken In Handling and Storage:Keep out a fly. Fed r allaw restricts heaters.keep out of roach of children.Avoid breathing vapors. of reach of children. Avoid contamination of lead and food- Avoid contact with eyes. stuffs.Store at room lomperawo.It is a violation of federal law Steps to Taken In Casa Material Is Released or Spilled: Steps to be Taken In Case Material Is Rolessed or Spilled: to use this product in a manner Inconsistent with its labeling. Collect and place in a suitable container for future disposal. Absorb with filter aid or dry Inert powder.Scrape up and deposit Wash contaminated surfaces B flush to drain. In suitable container. Ventilate aroa. No neutralizing chemi- Other Precautions: Waste Disposal Methods: Incinerate in accordance with cats. Steps to be Taken In Case Material Is Released or Spilled: local,slate and federal regulations. Waste Disposal Methods: Incinerate. Do not incinerate Containment-absorbent. Alter absorbed.wrap and place in trash collection. SECTION Vill-SPECIAL PROTECTION INFORMATION/CON- closed containers TROL MEASURES Waste Disposal Methods: r i not reuse empty container SECTION Vlll - SPECIAL PROTECTION INFORMATION/ c Securely wrap original container several layers of newspaper Respiratory Protection: Not needed CONTROL MEASURES and discard in trash. Protective Gloves: Recommended-latex or rubber 2Respiratory Protection:With adequate ventilation-not re- SECTION Vlll - SPECIAL PROTECTION INFORMATION/ Eye Protection: Recommended-safety glasses quired. CONTROL MEASURES Other Protective Clothing or Equipment; None Ventilation:Local exhaust-Preferred ;Mechanical-Accept- Respiratory Protection:Not required. Work/Hygienic Practices: Follow label directions-see pack- able;Special-N/A; Protective Gloves:Recommended neoprene Ventilation:Local exhaust-WA;Mechanical-WA;Special- age insert N/A; Eye Protection:Recommended goggles or full fare shield. Other- WA. Other Protective Clothing or Equipment:Suitable coveralls Protective Gloves:Not required. to protect against skin contact. KOPERTOX AVDA MSDS No.:MS1217 Eye Protection:Recommended Work/Hygienic Practices:None-follow label directions. Other Protective Clothing or Equipment:None Fort Dodge Laboratories,Inc.,P.O.Box 518.800 5Ih St.N.W., _ Fort Dodge,IA 50501.Emergency Phone: 515.955.4600. — Work/Hyglor lc Practices:None-follow label directions. Date of MSDS:May 29.1986 SECTION I-IDENTIFICATION NOLVACIDE INSECTICIDE SHAMPOO Product Name: Kopertox MSDS No.:MS1218 NOLVASAN ANTISEPTIC OINTMENT SECTION It-HAZARDOUS INGREDIENTS Fort Dodge Laboratories,Inc.,P.O.Box 518,8005th St.N.W., AVDA MSDS No.:MS1147 OSHA ACGIH Fort Dodge,IA 50501.Emergency Phone: 515-955.4600. Fort Dodge Laboratories,Inc.,P.O.Box 518,80051h St.N.W., Component PEL TLV OTHER % CASN Dale of MSDS:June 11,1986 Fort Dodge,IA 50501.Emergency Phone: 516-955.4600. Copper Naph- not known 500 ppm WA 37.5% not known SECTION I-IDENTIFICATION Date of MSDS:June 12.1986 thenato(active:ngredianll Product Name:Nolvacide Insecticide Shampoo SECTION 1-IDENTIFICATION Butyl Alcohol not known 100 ppm N/A 0.2% not known SECTION II-HAZARDOUS INGREDIENTS Product Name:Nolvasan Antiseptic Ointment Mineral Spirits not known 100 ppm WA 62.3% not known SECTION III-PHYSICAL 8 CHEMICAL CHARACTERISTICS CASN SECTION ll-HAZARDOUS INGREDIENTS Component % •Chlorhexldine Dlacetale LD50 Mice 2 p/Kp 1 Bolling Point:150.204"C' Pyrethrin 0.045% N/A Specific Gravity(H2O-1):0.86 Inert base 99% Piparonyl Buloxldos Technical •1,1'-Hexamethylenebis[5-(p•chlorophenyq bipuanlde]diaca- Vapor Pressure(mm Hg):Not determined (equivalent to 0.090% late Vapor Density(AIR-1):3.9' (butylcarbityl)(6-propylpiperonyq ether and 0.018%related compounds Topical ointment for surface wounds in dogs,cats,and horses Solubility In Water:Negligible SECTION III-PHYSICAL 8 CHEMICAL CHARACTERISTICS Reactivity In Water:Not reactive with water PetrolN-acl l m Dioillate a dicarboximide 0 215 Petroleum Distillate 0.215% Boiling Paint:N/A-Ointment Appearance and Odor:Green liquid with petroleum solvent Specific S H 1 WA odor Inert Ingredients 99.500% Pe Gravity( :0- ) Melling Point:WA SECTION III-PHYSICAL B CHEMICAL CHARACTERISTICS Vapor Pressure(mm Hg):WA SECTION IV-FIRE S EXPLOSION DATA Boiling Point:Not determined Vapor Density(AIR-1):WA Flesh Point: 45-WC Method Used: Open Cup Specific Gravity(H.0-1):1.028 Solubility In Water:WA-ointment Flammable Limits In Mr(%by Volume): Let-Not determined; Vapor Pressure(mm Hg):Not determined Reactivity In Water:Not reactive in water Usl-Not determined Vapor Density(AIR-1):Not determined Appearance and Odor:Light blue ointment Auto-Ignition Temperature:Not determined halon or Solubility In Water:Mixes well with water to produce a lather. Melling Point:WA Extingulaher Madla:Foam,dry chemical,COz,water mist. Reactivity In Water:Not reactive with water. SECTION IV-FIRE d EXPLOSION DATA Spoelel Fire Fighting Proceduros:Do not use water hose Appearance and Odor:A green to blue clear mobile liquid with Flash Point: WA Method Used: WA duec:ly on fire. Uso self-coniaincd breathing apparaius a faint odor. Flammable Limits In Air(%by Volume):Lei-WA;Ual-WA Unusual Fire and Explosion Hazards:Storage in not areawid Melting Point:N)A Auto-Ignition Temperature:WA develop pressure in container only Use water as cooling mod a SECTION IV-FIRE B EXPLOSION DATA Extinguisher Media:Will not burn. around fire. SECTION V-PHYSICAL HAZARDS(REACTIVITY DATA) Flash Point: Not determined Method Used:N/A Special Fire Fighting Procedures:None-will not burn. SE CTIOStability:Stable Flammable Limits In Air(% by Volume): Let-Not Unusual Fire and Explosion Hazards:None-will not burn. determined;Uel•Not determined SECTION V-PHYSICAL HAZARDS(REACTIVITY DATA) Conditions to Avoid:None known Auto-Ignition Temperature:Not determined Incompatibility(Materials to Avoid): Peroxides and strong Con Stable Conditions Extinguisher Media:Foam-ABC extinguisher Condlllons to Avoid:None known oxidizing agents. Hazardous Decomposition Products:Thermal decomposi- Speclel Fire Flphting Procedures:None Incompatibility(Materials to Avoid):None known lion releases carbon dioxide and monoxide. Unusual Fire and Explosion Hazards:None-contains only Hazardous Decomposition Products:None known Hazardous Polymerization:WIII not occur 0.215%volatile by volume(petroleum distillate) Hazardous Polymerization:WIII not occur Conditions to Avoid:None known SECTION V-PHYSICAL HAZARDS(REACTIVITY DATA) Conditions to Avoid:None known SECTION VI-HEALTH HAZARDS Stability:Stable Conditions to Avoid:None known SECTION VI-HEALTH HAZARDS Acute:Inhalation of vapors could cause headache,anesthe• IncompatibilitycombostoAvoid: Nonials to Avoid):None known Acute:None Chronic: None sia,nauseaSigns and Symptoms of Exposure:None-product is non- Chronic:Unknown Hazardous Decomposition Products:None known toxic Signs and Symptoms of Exposure:Toxic it ingested. Liquid Hazardous Polymerization:will not occur Medical Conditions Generally Aggravated by Exposure: and vapor imfaiing to eyes. Inhalation of vapors could cause Conditions to Avoid:None known None headache,nausea,anesthesia. SECTION VI-HEALTH HAZARDS Chemical Listed as Carcinogen or Potential Carcinogen:No Medical Conditions Generally Aggravated by Exposure: Acute:None known Chronic: None known Route(s)or Entry: Possible Irritation to eyes,headache,nausea,anesthesia. Chemical Listed as Carcinogen or Potential Carcinogen: Signs and Symptoms Exposure:none-a shampoo to kill Inhalation: No Ileac,lice,and licks in hair coats of dogs and cats. Eyes:Moderate•Flush with water Skin:Mild-Wash with soap and water G-10 American Veterinary Distributors Association NIOSH has recommended a 10-hr Eye:5 ppm Use air-supplied or sell-contained'breathing apparatus when Isopropyl Alcohol TWA of 200 ppm with a ceiling of Primary irritation conc.Is above TLV,but less than 2,000 ppm. A full face piece 800 ppm dose Is required above 10.000 ppm, Cont/nued Prevent skip contact kh wearin rubbqf gloves. Protective (15 minute sample). Oral:LDLo 340 mg/kg aprons,hoofs anc(Ihu'etkhiokis s tl bo used where splashing and burning sensations, with possible eye damage. Skin Inhalation: may occur. Use safety glasses other areas of use. contact will cause a slinging and burning sensation with defat- TCLo 8600 mg/ml Eye wash stations and safety showers should be available in ling and possible Irritation from prolonged contact, Ingestion Toxic irritant areas of use. will cause burning sensations of the digestive tract along with effects(systemic) No smoking in areas of use. nausea,vomiting,bleeding and CNS depression. This alcohol is considered poison,with ingestion of 20 ml causing serious SECTION!ll-PHYSICAL DATA Provide suitable training to those working with methanol.illness. The single lethal oral dose for an adult is approximately Bolling Point at 1 aim,deg C:64.5 Monitor the work place Keep records. 250 ml. Vapor Pressure at 21.2°C,mm Hg:100 SECTION/X-SPECIAL PRECAUTIONS AND COMMENTS First Aid: Vapor Density(AIR-1):1.1 Store in a well-ventilated,lire proof area,away from sources of Eye Confect:Irrigate with water for 15 minutes,including under Water solubility:Totally miscible heat,open flame and ignition.Ground and electrically intercon- nect containers for transfer. Use spark proof tools. Use with Appearance and Odor:A clear,colorless liquid with a charac- adequate ventilation. No smoking in areas of storage or use. Skin Contact.,Remove contaminated clothing. Flush with leristic alcohol odor.The odor recognition threshold(100%of Avoid prolonged or repealed breathing of vapor or contact with water. lest panel)is 53.3 ppm. skin.Avoid contact with eyes.This material is poisonous when Inhalation:Remove to fresh air. Restore and/or support Specific Gravity(201/4°C:0.791 introduced into the body metabolism. Do not Ingestl breathing as needed. Give oxygen if breathing difficult. Molecular Weight:32.04 Provide preplacement medical exams for Industrially exposed Ingestion:Get prompt medical help. Give water to drink to Melting Point,dap C:-978 workers, periodic medical surveillance, with emphasis on , . dilute.If medical help not readily available,the amount ingested neurological and visual functions,liver and kidney systems. was large and the victim Is conscious and alert induce vomiting. Ovaporation Rate(n-SuAc.1):4.6 LABEL:Flammable liquid. SECTION Vll.SPILL,LEAK,AND DISPOSAL PROCEDURES Viscosity Q 20°C,cps:0.59 DOT Classification: Flammable liquid. Clean-up personnel need protection against liquid contact and SECTION IV-FIRE AND EXPLOSION DATA vapor inhalation. Flesh Point and Method:54°F(12°C)(closed cup) Absorb small spills with paper towels,evaporate flammable Autolgnlllon Temp.:867°F(465°C) PHENOL AVDA MSDS No.:MS2265 alcohol in exhaust hood and burn dry paper Contain large Flammablllty Limits In Air:%by Volume spills;collect liquid II feasible or absorb vnu, vurmiculite on General Electric,Corporate Research&Development,Sch- sand;then place into covered container(using non sparking Lower-6 enectady,NY 12305.Telephone:518.385.4085. tools)for disposal. Water spray can be used to dilute and flush UPPer-36.5 Date of MSDS:September 1980 spill If necessary,but do not flush to water course or to sewer or P enclosed area. Extinguishing media:CO,,dry chemical,alcohol foam,and SECTION 1-IDENTIFICATION water mist or log. Methyl alcohol fires are Class IB fires,use a Disposal: Burn waste liquid in an approved incinerator or blanketing effect to smother lire. Material Name:Phenol dispose of via licensed waste disposal company. Absorbed It is a moderate explosion hazard and dangerous fire hazard No.:355 liquid can be land filled. Follow Federal, State, and local when exposed to heat,sparks or flames and can react vigor- Other Designations:Carbolic acid,Hydroxybenzene,Phonic regulations. ously with oxidizing agents. acid,ASTM D2439,GE Material D5J6,CAS#000 108 952, AQUATIC TOXICITY TLm 96:1000-100 ppm. Fire lighters should use sell-contained breathing apparatus C.HsOH SECTION Vlll-SPECIAL PROTECTION INFORMATION with full lace piece operated in pressure-demand or other SECTION II-INGREDIENTS AND HAZARDS Provide general and exhaust ventilation(explosion-proof)to positive pressure mode. Weer full protective clothing. Hazardous Ingredients % Hazard Data meet TLV requirements. Exhaust hoods should maintain a 100 SECTION V.REACTIVITY DATA I Phenol ca 100 8•hr TWA 5 ppm Pr lice velocity. Methyl alcohol is a flammable material,but it is stable under (skin) Provide salt-contained or air-supplied breathing apparatus with normal storage and use conditions. It does not undergo hazard- 'Current OSHA and ACGIH(1980)TLV or lull lace piece for non-routine or emergency use above the TLV, ous polymerization. Action Level:One half of permissible 19 mg/ml Use neoprene gloves and aprons where necessary to avoid Avoid contact with strong oxidizing agents such as nitrates, exposure or 8 fir TWA. (Skin)notation Human,oral skin contact. perchlorates or sulfuric acid. Chemical goggles should be worn in areas where splashing or Indicates a potential contribution to LDLo 140 mgAg Oo90 R 0 Oxidation products In air Include oxides of carbon and nitrogen. misting may occur.An eyewash fountain and washing facilities SECTION V/•HEALTH HAZARD INFORMATION overall exposure via absorption through should be available near use areas. Where gross spills or the skin. Mouse,Skin splashing can occur,a drenching safety shower is needed. TLV:200 ppm(Skin)or 260 mg/ml Preplacemeni and periodic medical examinations should Methanol Is a poisonous,narcotic chemical that may exert its NIOSH recommends a 10•hr TWA TLDo/40 mg/kg emphasize skin,sinuses,and the respiratory system. Keep effects through Inhalation,skin absorption or ingestion. Body of 20 mg/m3wlth a ceiling of 60 mg/m3 records. Provide suitable training to those working with iso• elimination of methanol Is slow,and the toxic effects can be (15 minute sampling period) (Intermittent). propanol, compounded by repeated excessive exposures over several A bloassay of phenol for possible Carcinogenic Effects SECTION IX-SPECIAL PRECAUTIONS AND COMMENTS days. Toxic effects are exerted upon the CNS,especially the optic norvu. Ingestion can produce blindness. Symptoms of carcinogenicity was conducted by NCI who Store in a clean,cool,ventilated area away from sources of overexposure include dizziness, visual impairment, nausea, submitted tainted drinking water containing ignition and oxidizing agents. Handle and store In a manner respiratory failure,muscular Incoordination and narcosis. Pro- 2,500 or 5,000 ppm phenol to F344 rats and suitable for OSHA Class IB Flammable Liquid. Electrical longed or repeated skin contact will cause dermatitis,erythema, B6C services must meet code. Bond and ground containers for and scaling. Ingestion of 100-250 ml can be fatal. sF r mice for 103 weeks. Bioassay indicated transfers. Use non-sparking tools. First Aid: phenol was not carcinogenic. FIR Vol.45 9/19/80 62563 Use with adequate ventilation. Avoid inhalation of vapors and Eye Contact:Irrigate with running water for 15 minutes. Gel SECTION 111•PHYSICAL DATA repeated or prolonged contact of liquid with skin or clothing. Do medical help. Bolling Point el 1 elm,deg C:182 not lake Internally. Wash thoroughly after handling. Do not smoke or eat In areas of storage or use. Skin Contact:Remove contaminated clothing. Wash affected Vapor Pressure at 96C,mm Hg:0.35 DOT Classification:FLAMMABLE LIQUID DOT I.D.No UN area with soap and water;apply skin lotions. Vapor Density(AIR-1):3.24 1219 Inhalation:Remove victim to fresh air and prevent further Water solubility at 25 C,g/liter:Miscible exposure for 7 days. Obtain medical assistance It victim Is not At room temp.,g/100 H O:ca 6 fully normal with 10 minutes. 0 r Ingestion:Drink 3 glasses milk,water or 4%sodium bicarbon- Appearance and Odor:Colorless or reddish(with impurity) METHYL ALCOHOL ate. Gastric lavage by medical personnel. Repeat NeHCO crystalline solid; characteristic sharp medicinal sweet tarry treatment after lavage. 3 odor,which is delectable above 0.05 ppm. AVDA MSDS No.:MS2264 treatment recommends Inducing vomiting it victim is conscious). Specific Gravity(H30.1):1.07 General Electric,Corporate Research&Development,Sch• SECTION VII-SPILL,LEAK,AND DISPOSAL PROCEDURES Molecular Weight:94.11 enectady,NY 12305.Telephone:518-385-4085. Date of MSDS:September 1981 NollfY safety Personnel. Remove all sources of ignition;pro- Melting Point,deg C:>40.5 SECTION I-IDENTIFICATION vide adequate ventilation.Absorb on vermiculite,paper or other Viscosity,cps,at 80 C:1.51 absorbent. Burn in an approved Incinerator or open pit away 'Water solutions start to boil at lower temp;e.g.85%104 C; Material Name:Methyl Alcohol from buildings and people. 92%:112 C No.:354 Spills In sensitive areas may be diluted and flushed to ground SECTION IV-FIRE AND EXPLOSION DATA Description:Industrial solvent with a water spray. Do not flush to sower. Other Designations: Methanol, Wood alcohol, Carbinol, Disposal: Dispose of large quantities of waste via a licensed Flash Point and Method:175 F(79 C)CC Wood naphtha,GE Material D5B51,ASTM D1152, CH30H, waste solvent disposal company,or reclaim via filtration and Autoignitlon Tamp'.:1319 F(715 C) CAS 0000 067 561 distillation procedures. It can be incinerated. Flammability Limits In Air:%by volume SECTION I/-INGREDIENTS AND HAZARDS Follow federal,slate and local regulations. Lower-1.5 Hazardous Ingredients % Hazard Data Aquatic toxicity rating:TLm 96:over 1000 ppm. Upper-8.6 Methyl Alcohol ca 100 8-hr TWA 200 SECTION Vlll-SPECIAL PROTECTION INFORMATION Extinguishing Media:CO.,dry chemical,alcohol foam or water ppm*(Skin) Provide adequate ventilation to meet TLV requirements. Ex- spray. 'Current OSHA Standard;ACGIH or 260 mg/m3 haust ventilation with 100 1Im minimum should be used where Do not expose any skin surfaces to phenol,liquid or vapor. (1981)TLV vapor exposure is likely. Engineering controls shall be spark Explosion and lire hazard when phenol is healed;can react proof end explosion proof.adds(skin)notation Human. vigorously with oxidizing agents. Solid phenol burns, with Material Safety Data Sheet U.S. Dcpar-2rn•e,, •)oi Libor may tx used 10 coney with Occupational Safaty ...d P.sslrh Administration OvA's Hazard Communication Standard, (Non-Mandatory Form) i C1=R 1910.1200. Standard must be Form Approved •xsufted for spec fic requirements. OMB No. 1216-0072 C*NTTTy (As Used on Labor and List) Ncte: PJhnk spasm sry no(penrO ad. !any Rem is not appkabb, or no CSTER Disinfectant -Sorav raxrns on k aYmAabis. trw *ace nx-V r,o marred to hdcab men. Section 1 7-9761 TO 449-3602 EPA Rea. No. 498-97 fAarwterurer's Name Emer;ency Teiephcne Nuxr-b•r C ase Products Cortrany 865-1000 NFPA 10,4 -J.LI14 Address (TArnber, Srset, Cry, Sane. and ZIP Coda) Ta4e�trna Numer O kx •1AtARC AATIYL' A . E.i rTr l P.O. Box 70 - i 0 363-10003 . M,r Owe Prepared 2 • W+ a r•s r r l �vati^,cod, IL 60153 04/18/08 ' ' S"4"' 0• M.n.m.i Signature or Prikum (cpoor-so "r"�•'"'r' 1 Section 11 — Hazardous Ingredlents/ldentLy Information demon Umrts Hazardous Components (Speck G`emical Identity: CAS Req. :`30. OSHA PEL ACzr;H TL`.' Req-mended % (opaor* Scdiu- Nitrite 7632-00-0 NA 64-17-5 Scecially Denatured Ethvl 75-65-0 1000ctrm 1000=n NA Alcohol SDA-4GB 3734-33-6 N- lkorl (60"C14 , 30%Ci 1 5%C12,5%C1 ) Di_-eth•✓Lte_nz•;l r.^,SOrat: A=niLun Chloride 15197-80-8 NA 0.5�;l-.-1/'tic _ ZJ-Alkyl (68% C1 , 32% C ) DirrethvlethvLbermzvl Ar=niurm + LDr;nrat: Chloride I NA 'N A 0.55rt1/Kq NA Procarie /Isobutare Propellant 74-98-6/ I NA 1000 zrt ALA B1erlsd 75-28-5 Section III — Physical/Chemical Characteristics Bobng Pant Specific Gravity (HZO - t) dater 212 F G,;rcerttrate 0.92 Vapor Pressure (mm Hg) ktelfir+a Pant nct acolicable Vapor Density (AIR - t) Evaporation Rate i:;Ut,/l aster �.a.:.(Bur?. Aceu:e - 1) ?seta t Sok,alrty in Water :tiscible Appearance and Odor "Ater t•Ahite lic dd. Section IV — Fire and Exp1o•slon Hazard Data Flammaote Umd3 I LEL UEL r la--e nro i ection: 0 in. NA E.-t Vuisning 1.4edLa Foam, Carbon Dioxide, Dry Cr.emical. . Fire FVNing Procedures . rater spray rray be used to cool cars in t:-.e vicinity of Fire or excessi:•e heat. L*xA" Fire and EAd0.t+on Hazards n—.:eraturez obc,:e 120 F rav cau_-e curls to IDurst. Urnta� CorXIoorr to A+omd sue* x �e T--.. ratures above 1200F - r icWnp ]Vlrty (Marvrlxls to Avo;M Stronc o>-.idizino agents and oven flame io%a Deccmpoanron or Byproduou n, ermal decomposition rrav yield toxic oases such as Carbon monoxide and Carbon Dioxide. tazardova Wy oo.ur Corxinx)ss 110 Arad VrT wriw xt Will Not Occur . X` -Te--*,Deratures above 120oF. k.ct4on VI — Health Hazard Date ime(s) or Entry Inhaletron? Skin? Ingestwn? yes yes no ieallh Hazards (ACute and ChrDn+C) — Acute: Proloncled inhalation of vapor or pray mist may z G nausea. cause eye and skin iSrritation on prolonged and repeated contact. Chronic: Not known. ,a=nogenicrty NTP7 IARC Monographs'? OSHA Regulated? no no no 4,is and Symptoms of Exposure Proloneed inhalation of vapor or sorax, mist may cause headache dizzy^ s ,L�- Nav cause eve and skin irritation on prolonged and rer.)eated contact. Aedica! Conditions ienerally Aggravated by Exposure Not known. .mergencl and First Aid Procedures - P -mre victim to fresh air. Restore respiration when necessary flush skin aml eves LI, plemt- of eater. (Ingestion very unlikely_ to occur.) If accidentally incested, drink ;z ?ion VII — Precautions for Safe Handling and Use plenty of eater and call a physician. reps to Be Taxer, in Case Maier.a Is Released or Spilled Soak uo soills with chemically inert, absorbent material. Provide ade-urte ventilation to area bei.nc t-eated. S:.se Drsaosa: Me:noC Dispose car-, in non-incinerated trash only. tYaulrons to Be Taken in Handling and Slonng Ke-ec container closed and awav from heat or oo n flare. FIRE PROTECTiON LEVEL I (NFPA 306) Ine: P .✓Mons Avoid breatr.inc too much vapor. Avoid prolonged and repeated contact with skin and eves. Keen out of reach of children. iection VIII — Control Measures ',asppwralory Protection (Sp&--r), Type) None re—aired if used with adecuate ventilation. e.-%iitation Local Exhaust Spe"I Pref erm3 None Mechanical ( e) Other None CJnL Iona 1 -•oteCtrve Gloves Eye Protection L Chemically resistant gloves if needed. Conventional evealasses to Guard a ains� 'roteci've Clothing or Equipment unexoacte>d splashimg. Not re^,fired. v�rk/Fiy?enK Prc:trces lyt: •`ri.s .+tt r W! .1 r vfQ. s . usa•o rrW .�91-529;�57)5 P re"-.are6 By: Laura E. I4aOevski. 0%r111,R0I.PI. XA COLLAR DOGS VVETKEM Date Issued: January, 1996 Supersedes; Novarnbw, 1995 MATERIAL. SAFETY DATA SHEET - VET-KEM® OVITROL® PLUS COMPLETE FLEA CONTROL COLLAR for Dogs and Puppies Manufacturer: Sandoz Agra,Inc. Address: 1300 East Touhy Avenue, Des Plaines, Illinois 60018 Emergency Phone; 1.800-950.8385 Transportation Emergency Phone: CHEMTREC: 1-800.424.9300 I• Product Name; Vet-Kern® Ovitrol® Plus Cornplete Flea Control Collar for Dogs and Puppies Chernical Name/Synonyfi: Mixture of IeVechinnrinohos (2-Ch[OrO-1-(2,4.5-trichlurophenyl)vinyl dimelhyi phosphate) and I$l-MethQp�ene• (isopropyl(2E, 4E, 75)•11-mothoxy-3,7,11-lrimethyl-2,4-dodo-dodecadienoule) O dcal Family: Mixture of Organophosphate and Insect Growth Regulator (IGR). FOMIR., CIO H„Os •CIO Hs CI4 04 P EPA Registration No.: 2596-139.2724 RF rr: 9507.001 • • • c , �9 s!n mon nan AS _��R sure Limits Tatrachlorvinphos 22248.79-9 14.559E Na Established M-Methoprene 65733-16.6 1,02'Y° Not Established Inert Ingredients (non-hazardous and/or trade secret) 84.4396 N/A t1170-61100 • PRECAUTI ONARY S TATEMENT FC 1i --� '1 CAI Ti DO O,� LET CH DREN PLY WIT L R.. ICOL SIGNS AND SYMPTOMS OF OVEREXPOSURE Due to product form, mothod of use, and hiss not expected. However, depending u �' human intoxication is may produce symptoms consloont witri chol ne3 trasere einhibit onnphos PRIMARY ROUTE OF ENTRY DenmallEye: lies Oral: No Inhalation: No ACUTE TOXICITY Oral: LDs,(rat): >2.000 mg/kg bw(Twachlorvinphos): >5,000 fng/kg (hlghest dose tested) (Methoprene) Derntalo LDs, (rat): a10,000"V/kg bw(Tatrachlorvin hos • (rabbit)- >Z,000 mg/kg (hlghest dose tested) (Methop enej' rabbh Inhalation: N/A Provided as a "Value Added Service" Paste ' �� ' �a� by The Butler Company 3. HAZARD INFORMATION (eondnua4, OTHER TOXICOLOGICAL INFORMATION Skin Irritation: Non-irritant Eye Irritation: N/A Sensitizer: Non-sensitizer Eye: Flush with plenty of water, If Irritation appears, get medical attention. Skin; Wash with soap and wdLor. Pemove contaminated clothing and launder before reuse. If irritation appeare, get rmcilcel artent]on. Ingestion? Consuk a physician or veterinarian, Inhalation: Remove to fresh air. NFPA Rating; Neallh: 2 Fire: 7 Reactivity: 0 Flammability Class: Combustible solid Flash Point: N/A Explosive Limits(%of Volume): N/A Extinguishing Media: Foam%COS. Dry Chernicai, Water SPOCIal Protective Equipment: Firefighters should wear full protective clothing including self contained breathing apparatus, Fire Fighting Procedures: Toxic turns are released upon ti'teratel decomposition. Do not allow fire fighting water to escape into waterways or sewers, Combustion Products: Burning liberates HCL gas. Unusual fine/E:ploxlon Hazards: Burning liberates HCL gas. Steps to be Taken: Because or individual packaging, possibilltlos or a release are remove. However, should one occur, sweep up and Place In cntannw for proper o disposal, Do not allow to enter drainage systems, waterways, or sewers. Absorbents: If In liquid form, use clay granules, sawdust,dirt or equivalent lneompatibles: Strong oxidizing agents. s • 1 Handling: Wash hands, Rica, and arms thoroughly with soap and water arter handling this product, Storage: Store In original unopened container away from children, Do not rouse container or used collar. Wrap and put In trash. Exposure limits: Not Estsblishad Ventilation: General ventilation should be sufficient. Personal Promotive Equipment: N/A Vat•Keme Ovltrola Plus Cotapl.ta I"Control Collar for Dogs and Puppies Page 2 of 4 January 1906 • Appearance and Odor: Solid, gold plastic collar 6o111ng Point: N/A Malting Point: Not Determined Vapor Pressure 4nm Hg): Not Determined Vapor Density(Air— 1): Not Determined Specific Gravity: Not Determined Bulk Density: N/A Solubility: N/A Evaporation katel Not Detentrninea 7 pH: N/A s s Stability: Stable Reactivity: Non-reactive Incompatibility with Other Materials: Strong oxidizing agents Decomposition Products Low release of HCL gas when heated above 400eF Hazardous Polymerisation: will not occur e • e Z8RR0 IC TOXICITY [Speelfit to Active Ingredient(s)) Methoprene is not considered as an oncogenie compound. No evidence of compound related gross or histopathic lesions, organ wolghl variations or tumoriganic effects were observed at dietary levels up to and including S,000 ppm (HDT-highest dose tested)In a 2-year chronic toxicity/oncogenic study in rats, Tatrachlorvinphus. An NOEL of 6.25 mg/kg bw was observed in a two year rat study. C-cell hyperplasia/adenoma Of the thyroid, and adrenal cortical adenomas in lamules only, were observed at 42S mg/kq body weight in a two year rat study. DEVE[OPMENTAL/ R VE TOXICIly )Specific to Active Ingrodient(s)) Methoprene did not affect the reproductive porformence of rats when tasted at levels up to 2,500 ppm over a period or 3 generations. The NOEL for reproductive toxicity in rats was 5oo ppm. In rabbits, no leratogenic effects were nbserved at levels up to 2,000 mg/kg/day, the maximum lolarated dose for maternal toxicity. The NOEL in rats for tetrachlorvinphos was So mg/kg bw. I T GENICITY jSpelelfte to Active Ingredlent(s)) Methoprene is not a mutaganic compound. It has been found negative in the following tests. a) Arms Test (In vitro), b) Chromosom+tl aberraon In CHO calk (in vitro), and c) Dominant lethal assay(invitro test for chromosomal damage) lest. Tatraehlonliriphas was found to be non•mutaganie In gotta mutation assay and weakly positive In mieronuclaus test. OTH R,(S OW& to Active Ingredleht(s)) There was no evidence or delayed nourotoxiclty for tetrachlorvinphos, U.S. EPA has evaluated this product's toxicity as part of Uta U.S. registration procoss. EPA requires exlens(ve toxicity tests be porrorrrted btlfcre any pesticide chemical is approved for use. Based on their review of test results, they have determined that no significant risk to users, thN public, or lha environment ieIrexi when this product is used as Indicated on the product label, Vel•Kems Ovivcte Plus Complete Flea Control Color for Dogs and Puppies Page 3 of 4 January 1996 12. ECOLOGICAL INFORM-AlION ENYIRONMENTAL FATE Hydrolysis; T11/2 P 4 weeks ((S)-Methoprene) Photolysis: T1/2 c 10 hours ((S)-Methopnene) Son hall Ufa: — 10 days ((S)-Methoprena) Water solubility: c 2 ppm ((S)-Melhoprene): 15 ppm (tetrachlorvinphor) F,�CQ7OgfCITY (Active Ingredients Only) Acute Todehy: fish: LCs,(trout): 760 ppb, (blueglll): > 370 ppb ((S)•Methoprene) LC" (aom): 430 ppb, (blucglll): 530 ppb (tetrachlorvinphos) Acute foXioity: aquatic Invertabratar'e LC,,,(Daphnia): 360 ppb ((S)-Mathoprene) CONSIDILRAIIONS Do not reuse empty pouch and dispose In trash collection. Dispose In accordance with local, stale, and federal regulations as a consumer good containing a pesticide. YRANSPORI INFORMATION DOT49CFR Description: N/A Freight Classification: Collars, Animal, Insecticidal, In Individual retail containers. NMFC 1.49998 Sub 1 15. REGILILATORY INFORMATION CERCLA(Superlund): No RCRA: No SARA 311/312 HAZARD CATEGORIES Immediate Health: Yes Delayed Health: No Fire: (yo Sudden Pressure: No Reactivity: No The information presented horaln, while not guaranteed, was prepared by technically knowledgeable personnel and to the bast of our knowledge is true and accurate. It Is not intended to be all Inclusive rind the manner and conditions of ma and handling may InvolAw other or additional considerations. Yet-Kemp Ovftrol®Pius Complete Fits Control Collar for Dogs and Puppies Is a registered trademark of Sandoz Ltd. Vat•Itemed Orltrola plus Complete rtea convol Geller for Dope and Puppies Pape 4 of 4 January 1996 it 1069 PHYSICAL AND CHEMICAL PROPERTIES COM rION/INFORMATION ON INGREDIENTS Vet-Kam Ovitral Plus Flea Spray(Spi—I physical and Chemical Characteristics Harardoue/Non-Haturdow Ingredients MSDS No:MS11456.N March 1992 Bolling Point 200E COMPONENTS OSHA ACGIH Spetdlic Gravity(H2O=1);0.88 (Ch"Cal and Convivial llirua)I PEL TLv CHEMICAL PRODUCT IDENTIFICATION CHEMICAL Identification Vapor Protestant,(mm Hg):27 Placental N{Meraptomelhyl)phylhaUmide HE HE isroducVapor Dismally(Alr=1):less than 1 S-(0,04methyl-phosphorodlalaloate) oduet Harm:Vet-Kem Ovitrol Plus Flea Spray(Sprilz) Soiubluly In Water.Apprecubk Aromatic solvent(contains nap0u) NE NE -FIFA Reg.No.:2724-403•11785 RF No..721 Evaporation Role:>1(via.Butyl Acetate) Allrylruphthaknes HE NE , %Volatile(Volume):61 Xylem: 100 ppm 100 ppm COMPOSITION/INFORMATION ON INGREDIENTS Appearance end Odor.Clear yellow liquid with an alcohol odor. 435 mym3 435 mg/m3 Hazardous Irlgriedierils/Iderdlty Napthalene 10 ppm 10 ppm Hazardous STABILITY AND REACTIVITY 50 mym3 50 mym3 ICPhysical Hazards(Reactivity Data) Biphenyl 02 ppm 0.2 ppm rwnlcAi and Comnwn other Expo• Stability:Stable I mym2 1.5 mym2 Name) OSHA PEL ACGIH TLV sun Ladle CAS No. Conditions to Avoid:Open game,heat Iso rc I alcohol 400 m 400 COMPONENTS P PY pp ppm 616]-0 Incompatibility(Materiau to Avoid):Strong oxidisers (Chemical end Common OTHER EXPOSURE 980 mg%m3 980 mym3 rtazsrdous DseompoJuon Products:Ncne Name) LIMITS CAS No. STEL•' Hazardous Polymerisation:Will not occur Phosmet N{Meraplomelhyl)Zoecon recommended 0.9 732.116 500 ppm a phytha imide S-(0,0-0imcthyl-mym3 8 hour unsure limit 1225 mym3 DISPOSAL CONSIDERATIONS phosphorodithloxte) Wash Disposal Method(Consult federal,state,and local regulations): Aromatic solvent(contains 10 ppm recommended by 64742.94.5 HAZARD IDENTIFICATION If household waste,empty,containers an be thrown in trash. larger naplha) vendor Health Hazards quantities should be disposed of at an approved disposal site. Alkylnaphthalenes 10 ppm recommended by NE Signs and Symptoms of Exposure.Those associated with aileron, vendor hay fever,i.e.,itchy,runny eyes,sluffylrunny nose,chest discomfort, TRANSPORT INFORMATION Xylene OSHA&ACGIH 150 ppm 1330.20-7 possible hives.In addition,alcohol may cause ataxia,dizziness. Acute;In large doses,may see ataxia,convulsions,cramps,G.l.irritation. Material Shlpping Information 6551nem3 Symptoms similar to dmokenness. Napthalene OSHA&ACHIB MU 15 91-20.3 Department of Transportation Regulations(Air md'Ruck) Chronic:Chronic symptoms not known/reported. ppm Duane or Use Greater Than a Quart Primary Routes of Entry:Oral,dermal 75 mym3 Chemical Usb d as Carcinogen or Potentim Carcinogen:Not used. Article Name: Consumer commodity Insecticide liquid, Biphenyl NE 92-524 N.O.S.(Isopropanol) FIRST AID MEASURES Hzzard Class: Flammable liquid Emergency and First Aid Procedures:If in eyes,gush immediately Packaging: Exempt DOT-12B65 HAZARD IDENTIFICATION with water. If irritation persists,get medical attention. If swallowed Fiberboard Box Health Hazards in quantity,give I to 2 glasses of water,and induce vomiting. Call a Max.Net Qty.Per Passenger&Cargo:30 Passenger:forbidden. Signs and Symptoms of Over Exposure: physician.If on skin,wash with plenty of soap and hot water. Pkg,by Air. its gross Aeuts:Over exposure an am choltowerise inhibition.7bzic signs Cargo:10 gallons may include nausea,vomiting,diardw,headache,tightness in chat, 'IRE FIGHTING MEASURES ataxia,anorexia,twin&salivation,pinpoint pupils,Pulmonary edema, Big of Lading Consumer commodity, Insecticide Liquid, cyanosis,convulsions,sweating,eta. e and Explosion Data Description ORM-D N.O.S.(Isoprepanol) Oral I.Dyo(Rat):399 mgft Dermal LD3a(Rabbit): >2,100 mgft -rash Point:53 F Flammable liquid,NA Dermal irritation(Rabbit):Moderate;Eye irritation(Rabbit):Modes. Mehod Used:TCC Flammable Llmgs In Air(%by Volume):LEL-2%;UEL upper-12% 1993 Chronic:Unknown (guinea pig):Negative Chronic:Unknown Auto Ignition Temperature:Not known International Ale Transport Association(IATA): Primary Rotas of Entry.Dermal,oral Extinguisher Media:Dry chemical,CO2 or Alcohol Foam(water may Article Name:Flammable liquids,N.O.S.(Isopropanol) Chemical Listed as Carcinogen or PolerNal Carcinogen:NTP-No; be ineffective) Hazard Class:Class 3(Flammable liquid) IARC Monographs•No;OSHA-No Special Fire Fighting Procedures:Firefighlers should wear protective Packaging:UN 4G Combination package clothing and self contained breathing apparatus.Do not allow runoff to enter waterways or drainage t)vtem_ FIRST AID MEASURES Unusual Fire and Explosion Hazards:None Max.Nei Oty. Passenger. 5 liters Pkg.]mt.305 Emergency and First Aid Procedures:Product Is a cholhtesterase in- Per Pkg: Cargo Only: 60 Liters Pkg.[mi.307 Whiter.Atropine ls antidotal.In ace of toxic signs,I.V.administration of ACCIDENTAL RELEASE MEASURES atropine sulfate,to effect may be preferable.If swallowed,all a physician Steps to be Taken In Came Material a"hu sed/Sp111ad:Absorb Bill of lading Description:Flammable liquids,N O.S.(Iwpropanol), immediately.Do not induce vomiting.May present an aspiration haw& spill.Place all wastes in container for disposal.Do not allow product to Class 3,UN 199J,Pkg II If on skin,wash with soap and water. Remove coolemieared clothing enter drainage system or waaemays. Imemstlonal MorMms Organization(IMO)(Via ocean): and clean before reuse.If in eyes,immediately Bush with gently gearing Article Name:Flammable liquids,N.O.S.(Isopropanol) water to effect.If irritation persists,get medical attention. HANDLING AND STORAGE Hazard qua Clan 3.2 FIRE FIGHTING MEASURES General Precautions for Safe Handling and Use packaging:UN 40 Combination Package Work/Hyglenic Practices:Wash hands,emu and face thoroughly with B81 of Lading Description:Flammable liquids,N.O.S.(Isopropanol), Fire and Explosion Data soap and water after handling product. Clan 3.2.UN 1993.PG 11, Flash Point:130'F Precautions to be Taken In Handling and Storage:Avoid inhalation Method Used:TCC and roan with skin,cya and clothing.Stove in original container away Flammable Linda W Air(%by Volume):UEL Unknown;UEL Uu• from thixdten-Keep sissy from heat,sparks and game. known Extinguisher Media:Dry chemical,water,fog,CO2,fans EXPOSURE CONTROLS/PERSONAL Vet Kam Peremlte Sponge-On or DI f : 'r^e lgnivah T.mp.rsh rr unknown PROTECTIONPOr Special Fire Fighting Procedures:Firefighters should wear protective General Control Measures Dogs; clothing,eye protection,and MSIWNIOSH approved positive prenae Ventilation:Required self-contained breathing apparatus. q MSDS No:MS1031R Mach 1S192 Unit"Fla and Explosion Hazards;Produce my decompose under Respiratory Protection:None for ordinary use.If prolonged nposurc n apcoed,wear a hISMINIOSH sppnmcd organicvsporlpcuicidc tea- fire conditions to give off toxic Irritant. pastor. CHEMICAL PRODUCT IDENTIFICATION Protective Gloves None for ordinary use. If prolonged exposure or Product IdengNcaUon ACCIDENTAL RELEASE MEASURES e 1:[wst contact u expensed.wear Impervious gloves. product hem:Vial-Kern Panmite Sponge-On or Dip for Dogs Steps to be Taken In Caw Material Is Rstessed(Spllled:Wear pro- Eye Protection:None for ordinary use. If eye contact from spray is EPA Reg.No.:2724.169.1171U lective clothing while handling split Pmvlde veadhadoo,cover with& �ssible,rear goggles or (try glasses with side shields wtecnn alcruL plan xitspxiaem sad uuxc cootamu:mi:d matutab in ar Protective Cle ZtorllEgtalpmsm:West appropriate clothing FDA No.:N/A tontainct which on be herded sod removed to dupoul aura.Do nor prevent skin contact. RF No.;243 allow spill to reach drains or Waterways. Article Name:Organophosphonss pesticides,liquid,toxic,N.O.S.(Phos. HANDL. `ND STORAGE In 1) General Precautions for Sale Handling end Use Zoeeon Industries continued Hazard pass:Class 6.1 Wort/Nyp4nk Pratticea•.Avod wntau with eyes,skin and cklhiny Packaging:Combination packages:UN 40;Steel Drum:UN IAI Avoid mulanon of ma o...pan.,%sah thoroughy with rep and wamr Bill of Lading Description:Organophosphorus pesticides,liquid,toxic, .Oat handing. 1 •tat-Kam Para mite Sponge-On or Dip,f#r N.O.S.(contains Phosmel),Class 6.1.ON 3018.PG III Precautions to be Taken In Handting end Storage Contents unict s t pneuure.Do not uae or dote onr'beat or open fisme Do not puncture. ep gS C9111iII14Cd Exposure to temperatures above 130 degrees F my cause bursting. HANDLING AND STORAGE Vet-Kem Pet Spray EXPOSURE CONTROLS/PERSONAL General Precautions for Safe Handling and Use PROTECTION Work/Hyglenk Practices:Avoid inhalation of vapors and contact with MSDS No:MS3399R March 1992 eyes and skin.Wash hands,arms and face thoroughly with soap and water General Control Measures after handling. CHEMICAL PRODUCT IDENTIFICATION Ventilation:heal exhaust.Ventilate to keep airborne exposures below Preuuaone to be Taken In Handling and Storage:May be harmful if Product IdenUfiealion recommended limits. swallowed,inhaled,or absorbed through skin Do not contaminate feed Product Name:Vet Pet Spray Raaptralory Proteetlod:Avg d inbatatson of mot or vapor.If exposures or foodstuffs.Do not breath fumes or vapors.Do not get an skin or eyes above recommended limits is anticipated wear a MSHMNIOSH approved Do nor use or store near open heat or flame. EPA Reg.No.:11715-41-11785 organic vapor/pesticide respirator. Protective Gloves:Avoid contact with skin.If exposure is anticipated, EXPOSURE CONTROLS/PERSONAL COMPOSITION/INFORMATION ON INGREDIENTS wear impervious gloves. PROTECTION HazardouVNonhazardous Ingredient Eye Proleclik n:Avoid eye contact. If exposure is anticipated,wear General Control Measures yoggies of glasses with side shields Ventilation:Mechanical(generel) (Chemical OTHER ONar Protective Eq ar ulpmanl:Weappropriale clothing to prevent skin Rsepinlory Proleetlon:Avoid inhalation of vapors. If exposures ls end Coo- EXPOSURE contact. v expected,wear a MSHAINIOSH approved/organic vapor pesticide respi- raps Name) OSHA PEL ACGIH TLV LIMITS CAS NO raver. Protective Gloves:Avoid skin contact by wearing impervious gloves. Propoxur. 0.5 mg/ms 0.5 mg/ms HE 114.2&1 PHYSICAL AND CHEMICAL PROPERTIES Eye Proleaton:If splashing into eyes is possible,wear chemical goggles. (e2h(1-methyl Physical and Chemical Characteristics Other Proleglve Equlpment:Wear appropriate clothing to prevent skin phenol melhyl Boiling Point:N/A contact. carbonate Specific Gravity(11;0=1):or Corse.1.1900 PHYSICAL AND CHEMICAL PROPERTIES 1,1,1 trichlor. 350 ppm;1900 350 ppm; OSHA& 71.55-6 Vapor Prassun(mm Hit):24 PSI at 70 deg.F .' Physical and Chemical Characteristics etnene mgimx 19DO mg/ms SA��H Vapor Density(Air=1):Not estimated Boiling Print:440'F Solubllny In Water:Not w:ublc /50 ppm 2450 Evaporation Rate:Not estimated. Specific Gravity:(Hr0=1)1.036ure a Par° Vapor Press (mm Hg):Unknown mg/m %Volatile(Volume):99.+% Vapor Density(Air=1):Unknown Isopropyl 4W ppm;990 400 ppm;980 OSHA& 67-63-0 Appearance and Odor;Concentrate:Odor of chlorinated solvent. Solubunry In Watar:Emulsion alcohol mg/ma mg/ms SAOOIH Evaporation Rats•.Unknown %Volatile(Volume):App.70% 500 ppm 1225 STABILITY AND REACTIVITY Appearance and Ociccp Light amber to medium brown,solvent odor. mg/mz Stability:Stable. Propane 1000 ppm; Asphyxiant NE 74.98-6 Incompatibility(Materials to Avoid):High heal: Do not store above "ABILITY AND REACTIVITY IBW mg/ma 130 degrees F.Do nol store near open game. °slal Hazards(Reactivity Data) Hezardoes Docc mpoohlon Products:Carbon monoxide,carbon diox- :.ybillry:Stable ide. Incompatibility(Materials to Avoid):Strong axidium HAZARD IDENTIFICATION Hazardous Polymerization:Will not Dour. Hazardous Decomposition Products:CO,COz,NO Health Hazards Condruons to Avoid:High rant;open name Hazardous Polynenlratkn:Writ not occur Signs and Symptoms of Exposure:Eyes:May cause temporary dis- comfort,redness,etc.Skin:May Cause skin irritation in ore cases.In. DISPOSAL CONSIDERATIONS DISPOSAL CONSIDERATIONS halation:May be irritant to respiratory mucus membrane.Oral:Amount transferred to mouth by contact with fingers,ere.during normal oiler- Waste Disposal Method(Consult federal,state&local regulations): WastesOlepo°el Method(Consuk ledaral,allte a local regulations): ations should not cause injury.Systemic:large quantities may cause Entire contents must be used according to label directions.Unused prod. Material is a hazardous wale under current Federal RCRA regulations, drowsiness,nausea,or dimness.Acute:None available Chronic:None uct,as a waste,may be classified as a hazardous waste due to ignitabiliry. Do not reuse container.If household waste,wrap empty container and available Recommended disposal of quantities is by an approved hazardous waste put in trash.For larger amounts,consult state and local regulations for Primary Roulu of Entry:Oral,dermal management. proper disposal procedures. Grelreganle Steals(NTT;IARC,OSHA):No components listed. TRANSPORT INFORMATION TRANSPORT INFORMATION Material Shipping Information FIRST AID MEASURES Material Shipping Information DeparlsnaM of Transportation Regulations(Air and Truck): Emergency and First AW Procedures:If in eyes:Wash with gently Department of Transportation Regulations(Air and Truck) Article Name:N/A flowing lukewarm water,if imsation persists,consult a physician,If on Article Name:Consumer Commodity,ORM•D Hazard Class:NIA skin:wash thoroughly with plenty of soap and water.Inhalation:Remove to fresh air and provide supportive are.Oral:Do not induce vomiting in Hazard Cis":N/A Packaging:N/A depressed or unconscious individuals.May Qum aspiration pneumonia, Packaging;Exempt CFR 49 173.12W Max.Net Ory•Per Pkg by Air.Passenger:NIA;Cargo only:N/A consult a h iciaa Bill of lading Description: Insecticides,N.0.1.,other than poison,in P n Max.Not Oty.Per Pkg.by Air Passenger:651bs gross weighs;Cargo boxes or drums.NMFC 111102120 only:65 Ile.grass weight Canadian Dangerous Goode Regulations: FIRE FIGHTING MEASURES BIII of lading Description:Consumer Commodity,ORM•D.Iruecd- Article Name:Organophosphorus pesticides,liquid,toxic,N.O.S.(Phos- Fife&Explosion Data tides,other than poison,N.O.S.,NMFC 102120 MCI) Flash Point Not est. Intsmatlonal Air Transport AssoelaUon(late); Hazard C1us:Class 6.1 Meted Used:NIA Article Nees:Aerosols,flammable,N.O.S. Packaging:Combination Package 21 ex.or less: RAC 6000,Rule 40. Flammable Limits In Air(%by Volume):LEL-Not est.;UEL-Not Hazard Class:Class 2,sulesidury risk 3 Fiberboard Box. est. Packaging:UN 4G combination package Combination Package greater than 21 oz:UN 4G Combination Pkg Extinguisher Media:Dry chemical,carbon dioxide and foam extin. Max.Not ay.Par Pkg.by Air:Passenger.75k Pkg.Inst:203;Cargo Steel Drum:UN IAI drum. guisher. only:150 kg.Pkg.Incl.:203 Imemdonal Alt Transport Association(IATA): Auto Ignition Temperature:NIA BIII of lading Description:Aerosols,flammable,N.O.S.Class 2,sub- Article Name:Orgenophosphonu pesticides,liquid,toxic,N.0 S.(PhDs- Special Fin Fighting Procedures:Firefighters should wear protective sidiary risk 3.UN 1950. Hazard clothing,and eye protection,self-contained breathing apparatus. International MmrM=Organization Imo Via ocean): Hazard Class:class 6.1 8 y P 8 PP g ( )( ) Packaging:Combination packages:UN 40;Steel Drum:UN[At Unusual Fire wW Explosion Huaree None brown Article Name:Acrowb Max.Net Qty.Per Pity:Passenger.60 liters Huard Class:N/A " f lading Description:Org.nophosphorm pcsNrtdcs,liquid,toxic, ACCIDENTAL RELEASE MEASURES Packaging:UN 40 combination package ps.(Phosmct),Class 6,I,UN 3018.Pkg Group III Steps to be Taken In Cass Matedal la ReleaaadlSpllled:Soak up gill of lading Dsacrlpton:Aerosols,Class 9,UN 1950,IMDO Page ...wsnrrauo W Mamma OrganlnUon(IMO)(Via ocean): with absorbent material.Place in container for disposal. 9022 H-64 American Veterinary Distributors Association RUBBING ALCOHOL U.S.P.70% SECTIONVill-REACTIVITY DATA SECTIOA HAZARDOUS INGREDIENTS ETHYL Stability;Generally stable Hazardous Ingredients CAS 0 % TLV(Units) Ha rdous Polyinwizallon:Not I:xuy DWocyl dlmelhyl 7173.51.5 9.22 NA nvnA MSDS No PAS 1677 Conditions Materials to Avoid:Contact with acetyl chloride ammonium chloride. Humco Labora(bry, nil.,P! . BOA 2550, Tezahana,TX and a wide range of oxidizing agents may react violently. n•Antyl(C„50%C,r 8001.54.5 6.14 NA 75504.Emergency telephone 214.739.3174. Hazardous Decomposition Products:Carbon monoxide can 40%C„10s:)dlmelhyl SECTION I-IDENTIFICATION form an Incomplete combustion. bonzyt ifptmondum chloride. Product:Rubbing Alcohol USP 70%EtnyI Oclyl dlmelhyl amine oxide 2605.78.9 320 NA Chemical Nome/Synonyms:Denatured Alcohol;Denatured SECTIONIX•EMPLOYEEPROTECTION Elhylenedlamine 60.00.4 300 NA Ethanol lelreacellc add. Chemical Family:Alcohol Control Missures:Handle In the presence of adequate ventl- S odium hydroxide 1310-73-2 1.35 2 mg/mr lalfon. Delonized water 7732-18-5 77.09 NA Respiratory Protection:Where exposure is likely to exceed SECTION SECTION It-INGREDIENTS accoptsbte corona use NIOSWMSHA approvod resixis ory SECTION III-PHYSICAL DATA Composition PELITLV HAZARD protection equipment. Respirators should be solecled bused Bolting Paint ff):212 /CAS RN. on the form and concentration of containment In air and In Vapor Pressure(mm Hg):17.5 Ethyl Alcohol 1000 accordance with OSHA(29 CFR 1910A34). y ppm System Depressant Vapor Density(AIR-1):<1 64.17.5 System Depressant which e i paMo s Wear gtovss and prolecwe f @riling Solubility In Water:100% which we ImpoMow to INS product for Inc duration of entkl• ry Acetone PEL 1000 ppm paled exposure It more Is potential lot Skin contact. Appearance and Odor:light amber'Ilquid,mild odor 67.64.1 1 Flammable/InIlanl Eye Protection:Wear safety Blesses,meeting the epeclllca•- Specific Gravity(H.0-1):1.0 TLV-STEL 1 0750 ppm Narcotic Clone 1 ANSI Standard Z87.1 where no contacl with the eye la STEL 1000 ppm y Percent,Volatile by Volume(%):77 Water 7732.16-5 NONE Vans of AN Chemical safety7.1poldbe mooting oher therecs-Is Evaporation Rate:1 Dona of ANSI Standard Z67.1 should be worn whenever there le Methyl Isobutyl a possibility of splashing or other contact with the eyes. Reactivity In Water:None Ketone PEL-TWA 100 ppm Flammebletinlient PH:7.6.8.0 108.10.1 TLV-TWA 50 ppm Narcotic SECTION X•ENVIRONMENTAL PROTECTION SECTION IV-FIRE AND EXPLOSION HAZARD DATA STEL 75 ppm Bilrex(TM) NONE None Noted Environmental Precautions:Avoid uncontrolled releases of Flesh Point(Method Used):None (Donalonrum Senzoale) this material.Where spills are possible,a comprehensive split Flammable Limits:Lei-None;Uel•None 3734.33-6 response plan should be developed and Implemented. Extinguishing Media:NA SECTION 11I-HEALTH INFORMATION Spill or Leak Procedures:Weer appropriate resplralory pro-I Alcohol lecdon and protective clothing as described In Section IV. Special Fire Fighting Procedural:None For Pure Ethyl Contain spilled malarial.Transtet to secure containers.Where Unusual Fire and Explosion Hazards:Nzno Inhalation:Exposure to over 1000 ppm may cause headache, necessary.collect using absorbent modia. in the event of an SECTION V-HEALTH HAZARD DATA drowsiness and Iasciodo.loss of appoblo and Inability to don• uncontrolled release of this material,the user should determine Threshold Limit Value:NA contrale. Irritation of the throat. It the release Is reportable under applleable laws and regula- tions. Effects of Overexposure:Inhalation:NA;Eyes:Causes eye nausea,vomiting,Owrhoa. Waste Disposal:All recovered material should be packaged, damage;Sion:Causes severe akin Irritation;Ingestion:Harm. labeled,vansponod,and disposed er roc:lii rod In confor- mance fUI or Isla]if swallowed. Eye Contract:Liquid or vegan may cause Irritation. manse with apo"No laws and regulations and In confor• Emergency and First Aid Procedures:Inhalation-.WA Skin Contact:May cause krllallon and detailing of skin on pro- mance with good engineering practices. Eyes-Immediately Ilush with flawing water for 15 minutes.Call longed contact. physician Immediately. Skin•Rinse with Ilowlnp water for 15 SECTION IV•OCCUPATIONAL EXPOSURE LIMITS minutes,than soap andwstw.lnposbon•Odlnk prompdy @!ergo SECTION XI-REGULATORY CONTROLS quantity of mxk, whiles,gelatin Solution,or water.AvoW PEL-(OSHA Parmlulble Exposure Limit):Mixture Sae q y DEPARTMENT OF TRANSPORTATION: " Section II akohel.Get maacsl attention. TLV-(ACGIH Threshold Limit Value):Mixture See Section II DOT Classification:Flammable liquid SECTION V1•REACTIVITY DATA SECTION V-EMERGENCY FIRSTAID PROCEDURE' DOT Proper Shipping Name:Denatured Alcohol Stability:Stable FOR OVER EXP04URE BY: SECTIONXII-PRECAUTIONS.,HANDLING,STORAGEAND Incompatibility(Materials to Avoid):Adds USAGE Hazardous Polymerization:Will not Occur SWALLOWING:If victim Is conscious and able to swallow, Protect container against physical damage.Detached Storage nave it tmM water s milk to d having convulsions, give CAq by mouth fl IAN Is tin OISONus w having ENTERCALLA b Preferred.All Ignition i sources should be eliminated.do Smoking PHYSICIAN OR POISON CONTROL CENTER IMMEDI• should be prohlbltod N slerage areas. Electrical lnslr¢,ruons SECTION Vll-SPILL OR LEAK PROCEDURES should be In accordance with Article 501 of the National Elocur Steps to be Taken In Case Material la Released or Spilled: ATELY.Induce vomiting only if advised by physician or Pelson col Code.NFPA 30,Flammable and Combustible Liquid Code, P p Control Center, should be followed for all storage and handling. Frequent Contain spill. Avoid contamination of food,water,or lead. INHALATION:Immediately remove victim to Irish air.If victim careful leakage Inspection should be done.Automatic sprinkler Waste Disposal Method:Open dumping Is prohibited. Dis- has slopped breathing give artificial respiration, preferably system should be provided. Isolate from oxidizers,chemicals pose of in accordance with local,stele and federal regulations mouth-to-mouth.GET MEDICAL ATTENTION IMMEDIATELY. capable of Spontaneous heating,materials reacting with air or SECTION Vlll-SPECIAL PROTECTION INFORMATION CONTACT WITH EYES OR SKIN:Immediately Ilush atieded moisture to liberate heat,Ignition sources and explosives. Respiratory Protection:None area with pianty of coal water. Eyes should be flushed for at Consult local fire codes for additional storage information. least 15 minutes. Remove and wash contaminated clothing Containers hazardous when emptied. Since emptied contain- Ventilation:Local exhaust before reuse.GET MEDICAL ATTENTION IMMEDIATELY, are retain residue product(vapor w liquid),all precautions Protective Gloves:Rubber gicves SECTION VI-PHYSICAL DATA described on this MSDS must be observed. Eye Protection:Goggles or lace shield. Bolling PW6183-F Other Protective Equipment;None Melling Point:•173'F' SECTION IX•SPECIAL PRECAUTIONS Vapor Prossurei 44.6mm Ha®e8'F' Manufacturer Precaution@ to be Taken In Handling and Storing:Keep Spaclflc Gravity:0.872 a 60-F away from children. Vapor Density(AIR.1):1.58' Huntington H&S Other Preca utions:Triple rinse ompy containers thoroughly g with water before disposal.'Remove contaminated clothing and Solubility In Water:Complete wash before reuse. Appearance and Color:Clear and colorless Chemicals Division 970 East Tipton Street SECTION VII•FIRE AND EXPLOSION HAZARDS Huntington,IN 46750 PARVOSOL AVDA MSDS No.:MS1678 Flash Point:61"F ASTM D-56(fag Closed Cup) Auto-Ignition Temperature:6B5°F' Emergency Phone:'(219)356-7073 H&S Chemicals Division,970 East Tipton Street,Huntington, Indiana 46750.Emergency Telephone No.:219-356.7073. Flammable Limits In Air,%by Vol.Lower.,3.3' Upper;19' SECTION I-IDENTIFICATION 'For Poo Ethyl Alwhbl Fire Fighting Procedures:(Nolo: Individuals should perform Troda NamwSynonyms:Parvosol Formulaton HWS-64 only those toe aphdng ptococuros for which they have been FORMULATION HWS-256 Chemical Family:Germicidal Detergent&Deodorant Veined)Use dry chemical,"Alcohol"loam,or carbon dioxide; AVDA MSDS No.:MS2745 Formula:NA water may be Ineffective,but water should be used to keep fire- SECTION If-HAZARDOUS INGREDIENTS exposed containers cod. 0 a leak or spill tins not lgni:od,use H&S Chemicals Division,970 East Tipton Street,Huntington, walor spray to disperse the vapors and to protect man attempt., Indiana 46760.Emergency telephone:219-356.7073. Hazardous Ingredients % TLV(Unite) ing to stop a leak.Water spray may be used to gush spills away - Date of MSDS:10-17.88 Oldecyl dlmelhyl ammonium from exposures-and to dilute spills to nonflammable mixtures SECTION I-IDENTIFICATION chloride(CAS 7173.51.5) 2.31 NA (NFPA 49.Ig75). Trade Name/Synonyma:Formulation HWS-256 n-Alkyl dlmelhyl benzyl Unusual Fire&Explosion Hazards:Firefighters should wear ammonium chloride selt•contalned breathing apparatus In the positive pressure Chemical NamalSynonyms:NA (CAS 68424.85-1) 1.54 NA mode with a full faceptece when there Is a possibility of expo- Chemical Family:Germicidal Detergent Sodium hydroxide a0re to smoke,fumes or hazardous decomposition products. Formula:NA (CAS 1310-73-2) 0.33 2mgrms PAGE 1 OF 5 CMSCurtin Matheson Scientific, Inc. )MATERIAL SAFETY 9999 VETERANS MEMORIAL DOCK A F�SONS DATA SHEET HOUSTON, TX 77038 MAIL TO: PHOENIX CENTRAL LAS ATTN: ANDY VERDAN/LAB • Ll FOR VETERINARIANS INC 18506 142ND NE WOODINVILLE, WA 98072 SECTION 1 NAME AND PRODUCT MANUFACTURER NAME AND ADDRESS CHEMICAL NUMBER: BIOCHEMICAL SCIENCES ITEM NUMBER: 0245685 PVT LABEL VNDR CATLG NBR: 57011-5G P.O.Q,BOX opA518 ENTRY DATE: 12-04-89 i:RICRMN PHONEN 609'467-1813 SPECIAL4 CHANGED ATE REQUEST-30-90 COMMON NAME (ON LABEL) CHEMICAL FAMILY FORMALIN, 10% BUFFERED ALDEHYDE TRADE NAME 3 SYNONYMS CHEMICAL FORMULA FORMALDEHYDE SOLUTION (4% IN WATER) CH2O FORMALIN SECTION 2 HAZARDOUS INGREDIENTS HAZARDOUS COMPONENT CAS % (WT) TLV PEL FORMALDEHYDE 1100 ML/LT) 50-00-0 .00 NOT GIVEN NOT GIVEN PEL: Permissible Exposure Limit established by the Occupational Safety and Health Administration (OSHA). TLV: Threshold Limit Value established by the American Conference of Governmental Industrial Hygienists, 1986-87, OTHER INGREDIENT INFORMATION FORMALIN, 10% BUFFERED IA A FORMALDEHYDE SOLUTION, METHANAL (CAS# 50-00-0). SECTION 3 PHYSICAL DATA BOILING POINT VOLATILE BY VOLUME (%) VAPOR PRESSURE 100 DEG C N/A 17 TO 20 MMHG MELTING POINT VAPOR DENSITY SOLUBILITY IN WATER N/A APPRO. 1 100 51 EVAPORATION RATE ( = 1) SPECIFIC GRAVITY N/A 1 .03 APPEARANCE AND ODOR COLORLESS LIQUID OTHER PHYSICAL DATA FOAM MSD:((nun' Continued on Reverse Side 1639 a Building Dept Project Tracking Form Contractor.'Name_&address- OwPermit No::`. c 7 zo Sn&11 FT Date Received: More info required: Information received: Sent.#o: `Td;ti4 't-3":.: : duezb� , ceived M ab.AAAJ,tfd _Q Comments U tracking ' r i :_ } CITY OF ARLING"--)N DEPARTMENT OF COMMUNITY D..-cLOPMENT 238 N. Olympic, Arlington, WA 98223 BATE JOB NO ATTENTION . ullding ❑ Engineering ❑ Planning Phone (206) 435-0724 FAX (206) 435-3906 TO Rlcy,- wjc� RE k) e_ � TIn i C-, -1-6 S, 6LL fT BA-V > WE ARE SENDING YOU ❑ Attached ❑ Under separate cover via the following items: ❑ Shop drawings ❑ Prints ❑ Plans ❑ Samples ❑ Specifications ❑ Copy of letter ❑ Change order ❑ A�' ` COPIES DATE NO. DESCRIPTION full eity HEce1V -. Lf O0 •STY OF A ; . THESE ARE TRANSMITTED as checked below: ❑ For approval ❑ Approved as submitted ❑ Resubmit copies for approval ❑ For your use ❑ Approved as noted ❑ Submit copies for distribution > ❑ As requested ❑ Returned for corrections ❑ Return corrected prints XFor review and comment ❑ ❑ FOR BIDS DUE 19 ❑ PRINTS RETURNED AFTER LOAN TO US RIEMARKS A/> (=LDS A/DP I A,7'_k -5P1g C_4:L Z « -4, a'-7- l- -c �i�,� • r COPY TO 4 40%Pro-Consumer Content•10%Post-Consumer Content SIGNED: PRODGGT240 Inc.,Gmbn,M=01471 If enclosures are not as noted, kindly notify us at once. `1 ;ac t r• r.: I, -To Y'i o -'.�'.�.1, _ .�{� r'!l�- III •..r�� �, �• i4�3?M�iI�.�:..1+� YY�111A�htAtcY.� 'It 1'1l�tkl'�1?t�43t1 .011'"dill �1�'a r"! ir04 Elk ' c tia rg7 ! ? Imo„. �. a• - • - y•, c, ., I I • 'GI;•171 Ifl _/n II L. II U . 111 II IIRI -J1llitr.11 1 16 J 1_- L, Ui I I III I►; /%% All- - fie+� - .- - - — - — -� •- - �'. - — � 1 - � - , �-_I � - 1 flRlfj&r"IIri. luj fndrlUr (1fRl.:. is 1 tc.h:rt 11. tmiIt;r7TQ1M U yatf i1►a� Il.f r I _ • N-1~Ir LC' y�� n,,l .t' . ��+iT-•► - 74� !� M Hr� J '•It,.'+ yS ��' 1 r1 Wt%4. 141 f.1'iJe 1 ��I" �-.l i f.... 1 i 1, - f - - 1 r•i!� �I 1cI -I _ r s to l S � — } _W1 f �� - I r I CITY OF ARLINGTON CONSTRUCTION PERMIT ❑ COMBINATION ❑ BUILDING ❑ MECHANICAL ❑ PLUMBING ❑ SIGN PERMIT NO. a OWNER 1T1Tfqoiico,,-t u MAIL ADDRESS City ZIP PHONE ARCHITLCOOR DESIGNER MAIL ADDRE S CItY ZIP PHONE \ 5�-}Aoo \5oe, \c1TK- C.��s�� s'� Igo I cr�J�r� g$zz-g--3 GENE RAIL CON IRAC TOR MAIL ADORE SS CITY ZIP PHONE LICENSE I S I O Gt 88 ST 'r MECIIANICAL CONTRACTOR MAIL ADDRESS CITY ZIP PHONE LICENSE I PLUMBING CONTRACTOR MAIL ADDRESS CITY ZIP PHONE LICENSE 0 CLASS OF WORK ❑NLW ❑ADDITION ®ALTERATION ❑REPAIR ❑DEMOLI LION ❑BUILDING RELOCATION '= VALJNTIO(NN O-F WORK - Q Z l D 5 J 1 f W OLSCRIBE WU m PRUPUit U USE OF BUILDING I HEREBY CERTIFY THAT I HAVE READ AND EXAMINED THIS APPLICA- Lu 4 I I C TION AND KNOW THE SAME TO BE TRUE AND CORRECT ALL PROVI- Z LLGAL OtS(RIP I ION 01 PROPk R T Y(SHOWN BEL OW OR ATTACH FOUR COPIF S) SIONS OF LAWS AND ORDINANCES GOVERNING THIS TYPE OF WORK LDI BL(X 1( OF WILL BE COMPLIED WITH WHETHER SPECIFIED HERIN OR NOT.THE a ,/� �� / �� GRANTING OF A PERMIT DOES NOT PRESUME TO GIVE AUTHORITY TO w L/{- VIOLATE OR CANCEL THE PROVISIONS OF ANY OTHER STATE OR J TAX ID NUMBER FROM PROPERTY TAX STATEMENT I-OCAL LAW REGULATING CON STRUCT ION OFTHEPERFORMANCEOF a CONSTRUCTION.PERMIT EXPIRES 1 YEAR FROM DATE OF ISSUANCE. f SIGNATURE OF(,ONTRNCTOR OR AU H RIZED AGENT DATE O 108 AOURI SS t ?.cam S c �Y two ►,I-r � x-'�- 6.�v�.o0 (OPFICE USE ONLY) PLUMBING UCHANICAL NO. TYPE OF PIXTURE FEE :s PIXTURES NO. TYPE OP EQUIPMENT PEE :'s FIXTURES HATER CLOSEC ILET \IR COND.UNITS—H.P. EA. a u .Ilt•' IATHTUB LEFRIGERATION UNITS—H.P.EA ti .list— VATORY ASH BASIN I0ILERS—II.P.EA. 7 ti .lit•• iF10WER 3AS FIRED A.C.UNITS—TONNAGE EA. Igtip.list*' 1TCHEN SINK&DISPOSAL TORCED AIR SYSTEMS—H.T.U. MEA ISHWASHER WALL HEATERS—B.T.U. M -AUNDRY TRAY UNIT HEATERS—B.T.U. M :LOTH ES WASHER WAPORATIVE COOLERS ATER II PAT ER :LOTH ES DkYERS RINAL lENTILATION PAN ILiNRING FOUNTAIN LdLANCIS HOOD COMMERCIAL *LOOR DRAIN kIR HANDLING UNIT— CPM VACUUM BREAKERS ifOVE OOP DRAINS—RAl N LFA D ERS METAL F1 REPLACE dt CH I MNEY INK SERVICE—BAR.trIC. iNATER HEATER 3AS PIPING *(up to S-13.00.addnl. S.TS •P ui ment Ibtmut be proAdcd SUIT TOTAL i SUB TOTAL PERMIT i PERMIT TOTAL 1'I?L' TOTAL FEE i SIUI_YARU SL IBACK StRELI SLIBACK REAR YARD SET PLA CK NUM E PLAN CHECK FEE I Lp_ ©O EE L RECEIPT NO. , L� F � USF /ONI LOT AREA VACANT SITE ❑YES El FFrc VALUATION FEE IYPL OF CONSI OCCUPANCY GROUP NO.OF DWELLINI"HITS CI ING BUILDING S SIZE 01 BLDG NO Of SIORILS MAX.OCC.LOAD DEPARTMENT OF COMMUNITY ®kr..LOPMENT 236 N. Olympic, Arlington, YiIA 98223 DATE JOB NO � . ullding ❑ Engineering Cl Plannir� _ �'' 7 ATTENTION Phone (206) 435-0724 FAX (206) 435-3 TO RE: ' 1c L4-LA 01 In ' " ()60() 1 > WE ARE SENDING YOU ❑ Attached ❑ Under separate cover via the following items: ❑ Shop drawings ❑ Prints ❑ Plans ❑ Samples ❑ Specifications ❑ Copy of letter ❑ Change order i_l COPIES DATE NO. n DESCRIPTION THESE ARE TRANSMITTED as checked below: ❑ For approval ❑ Approved as submitted ❑ Resubmit copies for approval ❑ For your use ❑ Approved as noted ❑ Submit copies for distribution > ❑ As requested ❑ Returned for corrections ❑ Return corrected prints "Ii�For review and comment ❑ ❑ FOR BIDS DUE 19 ❑ PRINTS RETURNED AFTER LOAN TO US REMARKS COPY TO 40/Pre-Consumer Content•10/Post-Consumer Content SIGNED: PRODUCT240 �Inc,Cmtw,Mm DI471 If enclosures are not as noted, kindly notify us at once. I rI 3m :. z 1- ■-(wm u 1 r rm 1 1 I 1 I J7 A 1`1 m 16n ' I I I � �a :.:� _ I - -I , � � .J)■1� -a K �I/T Kll�tl• I � t!�■ �� VU1 I ~10 17 I r �Y V�— ►ter I I�{ 5 J 1 1 _ I , • ,� i Ala _1 ■ _ Auk- j 1 _ 1 C 1 1 VI)1] n1 j! A ]K ■ 1_ 1 _ I _ I I I I in TY 1 C1 IT I I - - - - II _ I f� �fl�l ICJ•_ _ 'J!�] I a 1 ` fib I 4 •� _ { li J I —1 I 1 I II .►� I I 1 t _ T- r J I LI I mV L _ I 11 - 1 �tai I _ IJI _ IIJ AI Ill LP 1 City of Arlington Building Dept F'\\ PUBLIC WORKS CHECKLIST PERMIT # — 77 DATE - ' O 00 LEGAL �' LOO 10 Plat Lot Tax ID# NAMEVe-LLb1 - ADDRESS ! O Q ,/> ,t-� VF 9t_V BUILDING USE �� l i n I C' # of BUILDING UNITS Existing Required Signature Date Water Meter Fire Hydrant Side Sewer Permit Monitoring Manhole Cross-Connection Control Sewer: Off site On site Water: Off site On site Pretreatment Discharge Permit Water/Sewer Fees Date received Date Yellow returned Date Pink returned m Ij 1 1■ _ 1 ILI 11 1 5� 7 ■ -� fir. _' I I II r i i i Uri yi■ � _ in v 1 Ti W I L-. '-b ■' I I ro►mil`fi'►4�T ; •�u t� �j C�� Y CITY OF ARLINGTON I CONSTRUCTION PERMIT ❑ COMBINATION ❑ BUILDING ❑ MECHANICAL ❑ PLUMBING ❑ SIGN PERMIT NO. q. ! 'J j OWNERI,Tf??pjj[,a, ', MAIL ADDRESS CITY ZIP PHONE h l C4—% J 1C. 4 C_ o ARCHITLC OR DESIGNER MAIL ADDRE S CITY ' ZIP �— PHONE Skeutil 11 `6�eAe gY "i50l; 1r1TK- AHD Ste, s-� 110 , ZNlc.P_ I GENERAL CONI RAC TOR MAIL ADDRESS l 1�IYrr1 S'r ZIP PHON �LICENSE O N MECHANICAL CONTRACTOR MAIL ADDRESS C.ITY�111-j1 ZIP PHONE LICENSE IT 2�n) -2--a 1-19 PLUMBING CONTRACTOR MAIL ADDRESS CITY ZIP PHONE 'l LICENSE N 3 CLASS OF WORK a❑NEW ❑AUDITION ®ALTERATION ❑REPAIR ❑DEMOLI LION ❑BUILDING RELOCATION VALUATION OF WORK a � �"'� �c�/'� /� Z S�o s-r l ,( ,n' "�--- W UES(RIBS WO 3 -Tr 1r�1 �y �1� - m PROPOSE U USE OF BUILDING I HEREBY CERTIFY THAT I HAVE READ AND EXAMINED THIS APPLICA- w T 4 G TION AND KNOW THE SAME TO BE TRUE AND CORRECT ALL PROVI- J uGnL Ot S(R iPl ION of PRVPI R T Y(SHOWN BE I OW OR n 17 n(H rvuR coPIF so SIONS OF LAWS AND ORDINANCES GOVERNING THIS TYPE OF WORK J LUI BLOCK _ OF WILL BE COMPLIED WITH WHETHER SPECIFIED HERIN OR NOT.THE a GRANTING OF A PERMIT DOES NOT PRESUME TO GIVE AUTHORITYTO VIOLATE OR CANCEL THE PROVISIONS OF ANY OTHER STATE OR J TAX ID NUMBER FROM PROPERTY TAX STATEMENT LOCAL LAW REGULATING CONSTRUCTION OF THE PERFORMANCE OF :2 CONSTRUCTION.PERMIT EXPIRES 1 YEAR FROM DATE OF ISSUANCE. SIGNATURE OF CONTRACTOR OR A RIZED AGENT DATE � I08/AUDRI CS E)A' �O (OFFICE USE ONLY) PLUMBING MECHANICAL NO. TYPE OF FIXTURE FEE :'s FIXTURES NO. TYPED EQUIPMENT FEE_ :'s FIXTURES WATER CLOSET'(TOILET) %IRCOND.UNITS-H.P. EA. u .liat•" AT`HTUB EFRIGFRATION UNITS-H.P.EA. 7 ti .list" VATORY(WASH BASIN 01LERS-H.P.EA. Li .list•" HOWER AS FBZED A.C.UNITS-TONNAGE EA. u .list•• TCHEN SINK&DISPOSAL ORCED AIR SYSTEMS-B.T.U. MEA ISHWASHER ALL HEATERS-B.T.U. M AUNDRY TRAY )NIT HEATERS-B.T.U. M LOTHES WASHER :VAPORATIVECOOLERS WATER HEATER LOTH ES DRYERS RINAL ENTILATION FAN )RINKINGFOUNTAIN KANGE HOOD COMMERCIAL LOOR DRAIN INIR HANDLING UNIT- CPM VACUUM BREAKERS OVE OOF DRAINS-RAINLEADERS ETAL FIREPLACE&CHIMNEY INK SERVICE-BAR,ElC. WATER HEATER AS PIPING *(up to 5=$3.00,addnl.=$35 ' -Equipment list must be provided SUB TOTAL SUB TOTAL PERMIT PE mFT TOTALFEE TOTALFEE SIULYARD'd IHA(-F. STREET SLIBACK REAR YARD SETI PLA CKNUM E PLAN CHECK FEE � I LIP_ ©O EE RECEIPT NO. �I I LOT ARF A VACANT SITE ❑YES ❑ 14 VALUATION FEE TYPL OF CONS) OCCUPANCY GROUP NO.OF DWELLIN ITS kxr7NrxINr. BUILDING s SUL 01 BLDG NO.Or STORILS MAX.000 LOAD PLUMBING I IRE SPRINKLERS REQUIRE[) — --- ❑YES ❑NO MECHANICAL / STATE BLDG.CODE COMMENTS — ENERGY CODE SURCHARGE PENALTY U.B.C. SEC.303(a) WATER/SEWER FEES TOTAL t PERMIT VALIDATION WHEN PROPERLY VALIDATED TIN THIS SPACE)THIS IS YOUR PERMIT 6 RECEIPT PAID CR# BY_ cc: ASSESSOR,APPLICANT,TREASURER, BLDG. DEPT. al�nn»,cOFFICIAL DATE RECORDS COPY KESMEL 84UEpAlAa IAC.[183181.- ," - ` apt w ULM v,r�{1E �hr 8x a 1, In a ` ED J M! 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MI:TFD FOR BUILDING PERMITENANT APPF11 ROVAL,. ^%'I�I`1 SMIdKJEY 01NT RETAIL BUILDING a t 1 y P�RT n E R'S L I P SUBM ED f OR BID R. ` �,i S BMi�TENANT/BIO CORRFC70NS "I o- s �1G PERMIT CORRECAONS i Douginai /q� e�:� 1 NC�Ma�'H.:GOCINTY,<IA�A a� v'awrn ree+•, 'shrc �. - --- 'Mitchell, ! �P � CONSTRUCTION DRAWINGS 11820Wrthu�W ``#E3(3n ?�et4evu ,:WA98'9f� g, r --6-II DRAWINGS (206r822 94 - r�f6}8r.<.€11l f AS B1 _ is s I ' M { tb. L , L'.liwo"I"T INC.I 1tv. 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Smilh CONSTRUCTION DRAWINGS QUINNLfk STATE Of WASHISHIl _-•_., AS-BUILD DRAWINGS 300 (206)i8-1.7600 (206)86y-2563 mmmmmmw — •, ,. I ' .. .,..,n...art .bus.J. •h.. .:v.: --------- 0 F ❑ � � U D ❑N - Q � NIA J I (2)11 „ Type X GWB f I�t oi this wall a)' cages D 3 6'0" N c C7 D 9 o o D 7 - > O DO c„ 068BFe m O- F n A 3 D 3 o C, z z Co N o a� rn 7- > m rn C M. 2868 2868 2868 2868 x x x x x Dsolid 2-sided glass _ retail case - �j ca es counter Vni� i� m ref. n D n _ 0 0 m (� om 0 DO 3 I' w fTl I- X ? o -D t D to pl, N wlc_n (D - 0O wet tables;- z �I, < N rn f'1 w counter 2868 c) N counter Z (D x D D n o U] I- owet tabl o D rn % bo ks aC, N N I ' 00 0. oa a m ❑ IT/ 3068 W� scru 110v (� (A N o g m threshold ew-box n 0�P N o a ^Otter 68 c ° ` (n o OJ rn 3068 OC 26688E oo a A -1 Z n closet � �" a 0 N l+ ;U o D M Di � c a s F U1 N a C 0z m rn o 0 o _ n- O n D m ° o S cages file cab. m 11 v ew-6aJ. c0 W c0 rn ? U! 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F V7 d N O < G CD < A l\ O O ❑ Ncn N F V F - p cn m r. -o F V n \ o co m m G v o `❑m-o a< GO c< - o< a 0 F C:l L? p� N Z o v O W c � VI f.�o D n� � �❑ . ,�.m 3 9 m FFm c N I-Tl 0 Dm--ono s q rn —a3 = X 4-8gip' O d(D m � a' N r~ O 0 � W. m o o F o C_— o 1. � y ❑ of ��' a — �< D o- ❑ C_Q — O y p N_ d❑ x \O O Op O F rt < V/ O O m O O ❑ 0 3 l � A Q NORTHWEST VE EAII\iAKY CLINIC Dz m " EMOKEY POINTS' 0� 0 16820 Smokey Point BLVD, Arlington, WA 98223